A Molecular Theory of the Solid-liquid Interface and Other Properties of the Liquid State

A Molecular Theory of the Solid-liquid Interface and Other Properties of the Liquid State PDF Author: Anthony Douglas John Haymet
Publisher:
ISBN:
Category : Liquids
Languages : en
Pages : 328

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Book Description

A Molecular Theory of the Solid-liquid Interface and Other Properties of the Liquid State

A Molecular Theory of the Solid-liquid Interface and Other Properties of the Liquid State PDF Author: Anthony Douglas John Haymet
Publisher:
ISBN:
Category : Liquids
Languages : en
Pages : 328

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Book Description


Structure of Liquids / Struktur der Flüssigkeiten

Structure of Liquids / Struktur der Flüssigkeiten PDF Author: H. S. Green
Publisher: Springer Science & Business Media
ISBN: 3642459471
Category : Science
Languages : en
Pages : 326

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Book Description
135 We first describe the thermodynamic theory of surface tension and adsorption, by the method of the dividing surface of GIBBS. The use of a dividing surface or its equivalent is indispensable for the treatment of a curved interface, as otherwise the concepts of the area and curvature of the interface, cannot be pre cisely defined. In the case of a plane interface, however, the concept of the dividing surface is not necessary and a valid alternative exposition has been proposed by GUGGEN HEIM [3J, [4J in treating the interface zone as a separate entity of some definite thickness bounded by two mathematical planes. We make, however, little mention of this method, since it seems to be of only minor importance in connec tion with the statistical treatment of an interface. To avoid any ambiguity, the treatment of a spherical interface given in this article is based not on the original method of GIBBS but on the method modified by HILL [8J and KONDO [9]. This method, however, is not applicable to non spherical interfaces, which will not be dealt with in this article. Although all the relations for a plane interface can be deduced from the cor responding ones for a spherical interface by putting the curvature equal to zero, the planar and the spherical cases are considered separately because of the prac tical importance and easy physical visualization of a plane interface.

Molecular Theory of Capillarity

Molecular Theory of Capillarity PDF Author: J. S. Rowlinson
Publisher: Courier Corporation
ISBN: 0486317099
Category : Science
Languages : en
Pages : 354

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Book Description
History of surface phenomena offers critical and detailed examination and assessment of modern theories, focusing on statistical mechanics and application of results in mean-field approximation to model systems. 1989 edition.

Solid-liquid Interface Theory

Solid-liquid Interface Theory PDF Author: James Woods Halley
Publisher:
ISBN:
Category : Science
Languages : en
Pages : 260

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Book Description
Solid-Liquid Interface Theory examines electronic properties of the metal-solvent interface, the modelling of reaction rates, oxides at liquid solid interfaces and organic liquid-solid interfaces.

Theory of Molecular Fluids

Theory of Molecular Fluids PDF Author: Christopher G. Gray
Publisher: Oxford University Press
ISBN: 0191004871
Category : Science
Languages : en
Pages : 785

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Book Description
Existing texts on the statistical mechanics of liquids treat only spherical molecules. However, nearly all fluids of practical interest are composed of non-spherical molecules that are often dipolar or exhibit other kinds of electrostatic forces. This book describes the statistical mechanical theory of fluids of non-spherical molecules and its application to the calculation of physical properties, and is a sequel to Theory of Molecular Fluids. Volume 1: Fundamentals by C.G. Gray and K.E. Gubbins. The emphasis is on the new phenomena that arise due to the non-spherical nature of the intermolecular forces, such as new phase transitions, structural features and dielectric effects. It contains chapters on the thermodynamic properties of pure and mixed fluids, surface properties, X-ray and neutron diffraction structure factors, dielectric properties and spectroscopic properties. The book is aimed at beginning graduate students and research workers in chemistry, physics, materials science and engineering.

An Introduction to the Liquid State

An Introduction to the Liquid State PDF Author: P Egelstaff
Publisher: Elsevier
ISBN: 0323159036
Category : Science
Languages : en
Pages : 253

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Book Description
An Introduction to the Liquid State focuses on the atomic motions and positions of liquids. Particularly given importance in this book are internal motion of molecules as a whole and the motion of atoms in a monatomic liquid. Divided into 16 chapters, the book opens by outlining the general properties of liquids, including a comparison of liquid argon and liquid sodium, discussions on theories and methods of studying the liquid state, and thermodynamic relationships. The book proceeds by defining the molecular distribution functions and equation of state, the potential function for non-conducting liquids and metals, and measurement of pair distribution function. Numerical analyses and representations are provided to simplify the functions of equations. The book discusses equilibrium properties wherein calculations on the state of gases and fluids are presented. The text also underlines space and time dependent correlation functions. Given emphasis in this part are neutron scattering, electromagnetic radiation, and various radiation scattering techniques. Other concerns discussed are diffusion and single particle motion, velocity of correlation function, diffusion and viscosity coefficients, liquid-gas critical point, and a comparison of classical and quantum liquids. The selection is a valuable source of information for readers wanting to study the composition and reactions of liquids.

Water and Aqueous Solutions

Water and Aqueous Solutions PDF Author: Arieh Ben-Naim
Publisher: Springer Science & Business Media
ISBN: 1461587026
Category : Science
Languages : en
Pages : 481

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Book Description
The molecular theory of water and aqueous solutions has only recently emerged as a new entity of research, although its roots may be found in age-old works. The purpose of this book is to present the molecular theory of aqueous fluids based on the framework of the general theory of liquids. The style of the book is introductory in character, but the reader is presumed to be familiar with the basic properties of water [for instance, the topics reviewed by Eisenberg and Kauzmann (1969)] and the elements of classical thermodynamics and statistical mechanics [e.g., Denbigh (1966), Hill (1960)] and to have some elementary knowledge of probability [e.g., Feller (1960), Papoulis (1965)]. No other familiarity with the molecular theory of liquids is presumed. For the convenience of the reader, we present in Chapter 1 the rudi ments of statistical mechanics that are required as prerequisites to an under standing of subsequent chapters. This chapter contains a brief and concise survey of topics which may be adopted by the reader as the fundamental "rules of the game," and from here on, the development is very slow and detailed.

Theory of Simple Liquids

Theory of Simple Liquids PDF Author: Jean-Pierre Hansen
Publisher: Elsevier
ISBN: 0080455077
Category : Science
Languages : en
Pages : 430

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Book Description
The third edition of Theory of Simple Liquids is an updated, advanced, but self-contained introduction to the principles of liquid-state theory. It presents the modern, molecular theory of the structural, thermodynamic interfacial and dynamical properties of the liquid phase of materials constituted of atoms, small molecules or ions. This book leans on concepts and methods form classical Statistical Mechanics in which theoretical predictions are systematically compared with experimental data and results from numerical simulations. The overall layout of the book is similar to that of the previous two editions however, there are considerable changes in emphasis and several key additions including:•up-to-date presentation of modern theories of liquid-vapour coexistence and criticality•areas of considerable present and future interest such as super-cooled liquids and the glass transition•the area of liquid metals, which has grown into a mature subject area, now presented as part of the chapter ionic liquids•Provides cutting-edge research in the principles of liquid-state theory•Includes frequent comparisons of theoretical predictions with experimental and simulation data•Suitable for researchers and post-graduates in the field of condensed matter science (Physics, Chemistry, Material Science), biophysics as well as those in the oil industry

Liquids

Liquids PDF Author: Thomas J. Hughel
Publisher:
ISBN:
Category : Liquids
Languages : en
Pages : 404

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Book Description
Introductory remarks / R.L. Smith -- Free volume model of the liquid state / David Turnbull -- The geometry of the structure of liquids / J.D. Bernal -- A brief review of some aspects of the molecular theory of liquids / Stuart A. Rice -- Transport processes, correlation functions, and reciprocity relations in dense media / I. Prigogine -- An outline of the theory of transport properties / N.F. Mott -- X-ray and neutron diffraction studies of liquid structure / Newell S. Gingrich -- Inelastic neutron scattering by liquids / H. Palevsky -- Proton magnetic resonance studies of compounds with the structure (CH3)4X / George W. Smith -- Viscosity anomalies and other pre-freezing pheonomena / A.R. Ubbelohde -- Surface tension of liquid metals and oxide melts / Paul Kozakevitch -- Importance of the surface tension of metals in some engineering problems / D.J. Harvey -- Dynamic nucleation / Bruce Chalmers -- Eutectic solidification / G.A. Chadwick -- Deviation from the normal fusion curve / Donald L. Ball.

Liquid-Liquid InterfacesTheory and Methods

Liquid-Liquid InterfacesTheory and Methods PDF Author: Alexander G. Volkov
Publisher: CRC Press
ISBN: 9780849376948
Category : Science
Languages : en
Pages : 446

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Book Description
Update your knowledge of the chemical, biological, and physical properties of liquid-liquid interfaces with Liquid-Liquid Interfaces: Theory and Methods. This valuable reference presents a broadly based account of current research in liquid-liquid interfaces and is ideal for researchers, teachers, and students. Internationally recognized investigators of electrochemical, biological, and photochemical effects in interfacial phenomena share their own research results and extensively review the results of others working in their area. Because of its unusually wide breadth, this book has something for everyone interested in liquid-liquid interfaces. Topics include interfacial and phase transfer catalysis, electrochemistry and colloidal chemistry, ion and electron transport processes, molecular dynamics, electroanalysis, liquid membranes, emulsions, pharmacology, and artificial photosynthesis. Enlightening discussions explore biotechnological applications, such as drug delivery, separation and purification of nuclear waste, catalysis, mineral extraction processes, and the manufacturing of biosensors and ion-selective electrodes. Liquid-Liquid Interfaces: Theory and Methods is a well-written, informative, one-stop resource that will save you time and energy in your search for the latest information on liquid-liquid interfaces.