A Model for the Charge-transfer Photochemistry of Transition Metal Nitrosyl Complexes PDF Download
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Author: Wayne E. Evans
Publisher:
ISBN:
Category : Change transfer
Languages : en
Pages : 492
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Book Description
Author: Wayne E. Evans
Publisher:
ISBN:
Category : Change transfer
Languages : en
Pages : 492
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Book Description
Author:
Publisher: Elsevier
ISBN: 0443237468
Category : Science
Languages : en
Pages : 330
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Book Description
Photochemistry and Photophysics of Earth-Abundant Transition Metal Complexes, Volume 83 in the Advances in Inorganic Chemistry series, highlights new advances in the field, with this new volume presenting interesting chapters on topics such as Radioluminescence of Copper(I) Clusters, Photophysics and Photochemistry of Chromium(III) Complexes (Molecular Rubies), Chromic behaviors of luminescent copper(I) complexes, Long-lived photoluminescence in group 4 metal complexes enabled by ligand-to-metal charge transfer, Photoactive MOFs for CO2 Activation utilizing Earth Abundant Metals, and more. Other sections cover Earth Abundant Metal Complexes for Optoelectronic Applications, Photoactive metal to ligand charge transfer excited states in 3d6 and 3d8 complexes, Ligand-to-metal charge-transfer excited states in d0 transition-metal complexes: Investigations into the photochemistry and photophysics of emissive titanocenes, Ultrafast dynamics in photoactive copper complexes from optical and Xray methods, and Photophysical properties of Ni(II) complexes and some copper(I) and zinc(II) complexes.
Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 141
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Author: Hans Klaas van Dijk
Publisher:
ISBN:
Category :
Languages : en
Pages : 141
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Book Description
Author: Ghulam Mohammad Malik
Publisher:
ISBN:
Category : Complex compounds
Languages : en
Pages : 566
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Author:
Publisher:
ISBN:
Category :
Languages : en
Pages :
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Author:
Publisher:
ISBN:
Category : Dissertations, Academic
Languages : en
Pages : 868
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Author: Mandeep Dalal
Publisher: Dalal Institute
ISBN: 8193872002
Category : Science
Languages : en
Pages : 480
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Book Description
An advanced-level textbook of inorganic chemistry for the graduate (B.Sc) and postgraduate (M.Sc) students of Indian and foreign universities. This book is a part of four volume series, entitled "A Textbook of Inorganic Chemistry – Volume I, II, III, IV". CONTENTS: Chapter 1. Stereochemistry and Bonding in Main Group Compounds: VSEPR theory, dπ -pπ bonds, Bent rule and energetic of hybridization. Chapter 2. Metal-Ligand Equilibria in Solution: Stepwise and overall formation constants and their interactions, Trends in stepwise constants, Factors affecting stability of metal complexes with reference to the nature of metal ion and ligand, Chelate effect and its thermodynamic origin, Determination of binary formation constants by pH-metry and spectrophotometry. Chapter 3. Reaction Mechanism of Transition Metal Complexes – I: Inert and labile complexes, Mechanisms for ligand replacement reactions, Formation of complexes from aquo ions, Ligand displacement reactions in octahedral complexes- acid hydrolysis, Base hydrolysis, Racemization of tris chelate complexes, Electrophilic attack on ligands. Chapter 4. Reaction Mechanism of Transition Metal Complexes – II: Mechanism of ligand displacement reactions in square planar complexes, The trans effect, Theories of trans effect, Mechanism of electron transfer reactions – types; Outer sphere electron transfer mechanism and inner sphere electron transfer mechanism, Electron exchange. Chapter 5. Isopoly and Heteropoly Acids and Salts: Isopoly and Heteropoly acids and salts of Mo and W: structures of isopoly and heteropoly anions. Chapter 6. Crystal Structures: Structures of some binary and ternary compounds such as fluorite, antifluorite, rutile, antirutile, crystobalite, layer lattices- CdI2, BiI3; ReO3, Mn2O3, corundum, pervoskite, Ilmenite and Calcite. Chapter 7. Metal-Ligand Bonding: Limitation of crystal field theory, Molecular orbital theory, octahedral, tetrahedral or square planar complexes, π-bonding and molecular orbital theory. Chapter 8. Electronic Spectra of Transition Metal Complexes: Spectroscopic ground states, Correlation and spin-orbit coupling in free ions for Ist series of transition metals, Orgel and Tanabe-Sugano diagrams for transition metal complexes (d1 – d9 states), Calculation of Dq, B and β parameters, Effect of distortion on the d-orbital energy levels, Structural evidence from electronic spectrum, John-Tellar effect, Spectrochemical and nephalauxetic series, Charge transfer spectra, Electronic spectra of molecular addition compounds. Chapter 9. Magantic Properties of Transition Metal Complexes: Elementary theory of magneto - chemistry, Guoy’s method for determination of magnetic susceptibility, Calculation of magnetic moments, Magnetic properties of free ions, Orbital contribution, effect of ligand-field, Application of magneto-chemistry in structure determination, Magnetic exchange coupling and spin state cross over. Chapter 10. Metal Clusters: Structure and bonding in higher boranes, Wade’s rules, Carboranes, Metal Carbonyl Clusters - Low Nuclearity Carbonyl Clusters, Total Electron Count (TEC). Chapter 11. Metal-π Complexes: Metal carbonyls, structure and bonding, Vibrational spectra of metal carbonyls for bonding and structure elucidation, Important reactions of metal carbonyls; Preparation, bonding, structure and important reactions of transition metal nitrosyl, dinitrogen and dioxygen complexes; Tertiary phosphine as ligand.
Author:
Publisher: Academic Press
ISBN: 0123859050
Category : Science
Languages : en
Pages : 461
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Book Description
The Advances in Inorganic Chemistry series present timely and informative summaries of the current progress in a variety of subject areas within inorganic chemistry, ranging from bio-inorganic to solid state studies. This acclaimed serial features reviews written by experts in the field and serves as an indispensable reference to advanced researchers. Each volume contains an index, and each chapter is fully referenced. - Features comprehensive reviews on the latest developments - Includes contributions from leading experts in the field - Serves as an indispensable reference to advanced researchers
Author: T. Ohno
Publisher:
ISBN:
Category :
Languages : en
Pages :
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