A Kinetic Study of the Oxidation of Uranium Tetrachloride PDF Download
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Author: John Van Wazer
Publisher:
ISBN:
Category : Oxidation
Languages : en
Pages : 6
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Book Description
Author: John Van Wazer
Publisher:
ISBN:
Category : Oxidation
Languages : en
Pages : 6
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Book Description
Author: John Lyman Ballif
Publisher:
ISBN:
Category : Oxidation
Languages : en
Pages : 216
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Author: Floyd Beatty Baker
Publisher:
ISBN:
Category : Cerium
Languages : en
Pages : 204
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Book Description
Author: Basilios Kanellakopulos
Publisher:
ISBN:
Category :
Languages : en
Pages : 9
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Book Description
Author: Andrew J. Timpone
Publisher:
ISBN:
Category :
Languages : en
Pages : 180
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Author: Peter Raymond Openshaw
Publisher:
ISBN:
Category :
Languages : en
Pages : 420
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Book Description
Author: W. R. DeHollander
Publisher:
ISBN:
Category : Chemical kinetics
Languages : en
Pages : 74
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Author: U.S. Atomic Energy Commission
Publisher:
ISBN:
Category : Nuclear energy
Languages : en
Pages : 818
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Book Description
Consists of AECD 1-2023 (no. 1-1779 called MDDC).
Author: Marcelle Gaune-Escard
Publisher: John Wiley & Sons
ISBN: 1118448820
Category : Science
Languages : en
Pages : 902
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Book Description
Written to record and report on recent research progresses in the field of molten salts, Molten Salts Chemistry and Technology focuses on molten salts and ionic liquids for sustainable supply and application of materials. Including coverage of molten salt reactors, electrodeposition, aluminium electrolysis, electrochemistry, and electrowinning, the text provides researchers and postgraduate students with applications include energy conversion (solar cells and fuel cells), heat storage, green solvents, metallurgy, nuclear industry, pharmaceutics and biotechnology.
Author:
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Category :
Languages : en
Pages :
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The kinetic study of low temperature oxidation of uranium in moist environment was conducted by means of system pressure measurement and gas chromatographic analysis of environmental gases. A mechanism including intermediate hydride phase formation at the metal-oxide interface was proposed. Principal conclusions are: 1) Moisture is principally responsible for the oxidation of uranium under these test conditions. 2) The reaction rate is principally dependent linearly on time; however logarithmic dependency and subsequent exponential time dependency, V = k t/sup 1.5/, are observed in the very early stage of oxidation. 3) Oxygen stifles the reaction by preventing the formation of reaction product hydrogen, hence stifles the formation of intermediate hydride phase. 4) Hydrogen accelerates the reaction by the counter effect to that of oxygen. 5) The formation of hydride is confirmed by the measurement of hydrogen yield of the gaseous system as well as the x-ray diffraction study. 6) The reaction rate is linearly dependent on imitial water vapor pressure. 7) Activation energy of the reaction determined as a spread value between 5 to 12 kcal/moles. 8) The approximate amount of hydride is determined. 9) The possibilities of the mechanisms involving a combined effect of formation and destruction of protective layer are suggested. (auth).
