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Author: Yu S. Matros
Publisher: VSP
ISBN: 9789067641272
Category : Science
Languages : en
Pages : 728
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Book Description
In the last decades the investigation methods of unsteady state catalytic processes have been widely developed by the response-technique methods. From this research emerged the realization that under unsteady state conditions and, especially under artificially created ones, it is possible to increase the productivity or selectivity of a catalyst or a catalytical process as a whole. The scientific literature in this field is mostly theoretical and aims at structuring and analysing mathematical models of unsteady state catalytical processes. In this book the theoretical and applied aspects of an efficiency of artificially created unsteady conditions in catalysis are discussed. It contains the lectures from researchers from all over the world that were held during the International Conference ''Unsteady State Processes in Catalysis'', 5--8 June 1990, Novosibirsk (USSR). Topics include: -- The problems of dynamics of a catalyst surface -- Kinetic models of unsteady processes -- Dynamics of chemical reactors -- Artificially created unsteady processes in a catalytic reactor.
Author: Yu S. Matros
Publisher: VSP
ISBN: 9789067641272
Category : Science
Languages : en
Pages : 728
Get Book Here
Book Description
In the last decades the investigation methods of unsteady state catalytic processes have been widely developed by the response-technique methods. From this research emerged the realization that under unsteady state conditions and, especially under artificially created ones, it is possible to increase the productivity or selectivity of a catalyst or a catalytical process as a whole. The scientific literature in this field is mostly theoretical and aims at structuring and analysing mathematical models of unsteady state catalytical processes. In this book the theoretical and applied aspects of an efficiency of artificially created unsteady conditions in catalysis are discussed. It contains the lectures from researchers from all over the world that were held during the International Conference ''Unsteady State Processes in Catalysis'', 5--8 June 1990, Novosibirsk (USSR). Topics include: -- The problems of dynamics of a catalyst surface -- Kinetic models of unsteady processes -- Dynamics of chemical reactors -- Artificially created unsteady processes in a catalytic reactor.
Author: Y.S. Matros
Publisher: Elsevier
ISBN: 0080960766
Category : Technology & Engineering
Languages : en
Pages : 419
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Book Description
This book deals with catalytic processes under forced non-steady-state conditions. It demonstrates, both theoretically and practically, that forced non-steady-state processes are highly efficient compared with steady-state processes, and illustrates this with a wealth of practical examples.The first part of the book describes the theoretical and experimental basis of efficient processes, mathematical models of non-steady-state processes in reactors, influence of a non-steady-state catalyst surface, problems of optimization, the theory of a heat front in the fixed catalyst bed, and methods to create efficient cyclic regimes. The second part considers the following processes: sulphur dioxide oxidation in sulphuric acid production, cleaning of effluent gases from toxic impurities, production of high-potency heat, ammonia and methanol synthesis etc.The book will appeal to many readers: chemical engineers (especially in the field of mathematical modelling of reactors with a fixed catalyst bed); personnel of chemical plants and machine-manufacturing companies dealing with maintenance and installation of catalytic reactors; specialists in detoxification of the effluents from organic admixtures and carbon monoxide; students of technical colleges and universities
Author: P. L. Silveston
Publisher: Butterworth-Heinemann
ISBN: 0123918669
Category : Science
Languages : en
Pages : 793
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Book Description
This comprehensive review, prepared by 24 experts, many of whom are pioneers of the subject, brings together in one place over 40 years of research in this unique publication. This book will assist R & D specialists, research chemists, chemical engineers or process managers harnessing periodic operations to improve their process plant performance. Periodic Operation of Reactors covers process fundamentals, research equipment and methods and provides "the state of the art" for the periodic operation of many industrially important catalytic reactions. Emphasis is on experimental results, modeling and simulation. Combined reaction and separation are dealt with, including simulated moving bed chromatographic, pressure and temperature swing and circulating bed reactors. Thus, Periodic Operation of Reactors offers readers a single comprehensive source for the broad and diverse new subject. This exciting new publication is a "must have" for any professional working in chemical process research and development. - A comprehensive reference on the fundamentals, development and applications of periodic operation - Contributors and editors include the pioneers of the subject as well as the leading researchers in the field - Covers both fundamentals and the state of the art for each operation scenario, and brings all types of periodic operation together in a single volume - Discussion is focused on experimental results rather than theoretical ones; provides a rich source of experimental data, plus process models - Accompanying website with modelling data
Author: Oleg V. Krylov
Publisher: CRC Press
ISBN: 1351083473
Category : Science
Languages : en
Pages : 312
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Book Description
Nonequilibrium Processes in Catalysis presents modern ideas and experimental data (e.g., molecular beams, laser technique) on adsorption and catalysis, the mechanism of energy exchange in the processes of particles interaction with a surface, and the lifetimes of excited particles on a surface. Previously unpublished theoretical information regarding the principle of chemoenergetical stimulation accounting for the acceleration of one reaction at the expense of reactant excitation in another is provided, and new ideas about nonequilibrium surface diffusion are explored. Examples of the formation of nonequilibrium dissipative structures in catalysis are presented, including auto-oscillations, auto-waves, multiplicity of kinetic regimes, nonequilibrium phase transition, and decelerated electron exchange between solid and adsorbed species. The book also describes new experimental methods for studying nonequilibrium and quick processes in catalysis. Nonequilibrium Processes in Catalysis will benefit physicists involved with surface science, chemists involved with adsorption and catalysis, engineers, vacuum scientists, physical chemists, materials chemists, students, and others interested in these processes.
Author: Andreas Jess
Publisher: John Wiley & Sons
ISBN: 3527815643
Category : Technology & Engineering
Languages : en
Pages : 908
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Book Description
A fully updated edition of a popular textbook covering the four disciplines of chemical technology?featuring new developments in the field Clear and thorough throughout, this textbook covers the major sub-disciplines of modern chemical technology?chemistry, thermal and mechanical unit operations, chemical reaction engineering, and general chemical technology?alongside raw materials, energy sources and detailed descriptions of 24 important industrial processes and products. It brings information on energy and raw material consumption and production data of chemicals up to date and offers not just improved and extended chapters, but completely new ones as well. This new edition of Chemical Technology: From Principles to Products features a new chapter illustrating the global economic map and its development from the 15th century until today, and another on energy consumption in human history. Chemical key technologies for a future sustainable energy system such as power-to-X and hydrogen storage are now also examined. Chapters on inorganic products, material reserves, and water consumption and resources have been extended, while another presents environmental aspects of plastic pollution and handling of plastic waste. The book also adds four important processes to its pages: production of titanium dioxide, silicon, production and chemical recycling of polytetrafluoroethylene, and fermentative synthesis of amino acids. -Provides comprehensive coverage of chemical technology?from the fundamentals to 24 of the most important processes -Intertwines the four disciplines of chemical technology: chemistry, thermal and mechanical unit operations, chemical reaction engineering and general chemical technology -Fully updated with new content on: power-to-X and hydrogen storage; inorganic products, including metals, glass, and ceramics; water consumption and pollution; and additional industrial processes -Written by authors with extensive experience in teaching the topic and helping students understand the complex concepts Chemical Technology: From Principles to Products, Second Edition is an ideal textbook for advanced students of chemical technology and will appeal to anyone in chemical engineering.
Author: Ilenia Rossetti
Publisher: MDPI
ISBN: 303921778X
Category : Science
Languages : en
Pages : 134
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Book Description
Increasing attention is being paid to the development of effective technologies for the sequestration of CO2 and its storage. Hopefully, this will result in processes that can lead to its valorisation as a chemical, e.g., for the regeneration of fuels, but also for the production of intermediates. These are usually energy demands and rather slow processes, requiring energy input and catalysts. Some examples are the innovative strategies for the hydrogenation, photoconversion, or electroreduction of carbon dioxide. This book collects original research papers, reviews, and commentaries focused on the challenges related to the valorisation and conversion of CO2.
Author: G.F. Froment
Publisher: Elsevier
ISBN: 0080530621
Category : Technology & Engineering
Languages : en
Pages : 611
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Book Description
Many processes of the chemical industry are based upon heterogeneous catalysis. Two important items of these processes are the development of the catalyst itself and the design and optimization of the reactor. Both aspects would benefit from rigorous and accurate kinetic modeling, based upon information on the working catalyst gained from classical steady state experimentation, but also from studies using surface science techniques, from quantum chemical calculations providing more insight into possible reaction pathways and from transient experimentation dealing with reactions and reactors. This information is seldom combined into a kinetic model and into a quantitative description of the process. Generally the catalytic aspects are dealt with by chemists and by physicists, while the chemical engineers are called upon for mechanical aspects of the reactor design and its control. The symposium "Dynamics of Surfaces and Reaction Kinetics in Heterogeneous Catalysis" aims at illustrating a more global and concerted approach through a number of prestigious keynote lectures and severely screened oral and poster presentations.
Author: John H. Seinfeld
Publisher: Academic Press
ISBN: 0080565727
Category : Technology & Engineering
Languages : en
Pages : 309
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Book Description
Advances in Chemical Engineering
Author: P L Silverton
Publisher: CRC Press
ISBN: 9789056991067
Category : Science
Languages : en
Pages : 650
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Book Description
Composition modulation is a method of operating a catalytic reactor to improve catalyst activity or selectivity and has been under study for more than 25 years. In the last few years, several commercial applications have been realized and more will certainly appear. A large international research literature now exists. This book examines this literature and attempts to organize and analyze it with the intent of identifying the magnitude of improvements possible, why modulation is effective, and what questions remain unanswered. Topics include hydrogenation, oxidation, reduction, and polymerization reactions for NOX, SOX, NH3, and hydrocarbons.
Author: Manfred Baerns
Publisher: Springer Science & Business Media
ISBN: 3662059819
Category : Science
Languages : en
Pages : 540
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Book Description
Written by a team of internationally recognized experts, this book addresses the most important types of catalytic reactions and catalysts as used in industrial practice. Both applied aspects and the essential scientific principles are described. The main topics can be summarized as follows: heterogeneous, homogeneous and biocatalysis, catalyst preparation and characterization, catalytic reaction engineering and kinetics, catalyst deactivation and industrial perspective.
