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Author: Richard Guy Compton
Publisher: World Scientific Publishing Company
ISBN: 1848169515
Category : Science
Languages : en
Pages : 270
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Book Description
The field of electrochemical measurement, with respect to thermodynamics, kinetics and analysis, is widely recognised but the subject can be unpredictable to the novice, even if they have a strong physical and chemical background, especially if they wish to pursue quantitative measurements. Accordingly, some significant experiments are, perhaps wisely, never attempted, while the literature is sadly replete with flawed attempts at rigorous voltammetry.This book presents problems and worked solutions for a wide range of theoretical and experimental subjects in the field of voltammetry. The reader is assumed to have knowledge up to a Master's level of physical chemistry, but no exposure to electrochemistry in general, or voltammetry in particular, is required. The problems included range in difficulty from senior undergraduate to research level, and develop important practical approaches in voltammetry.The problems presented in the earlier chapters focus on the fundamental theories of thermodynamics, electron transfer and diffusion. Voltammetric experiments and their analysis are then considered, including extensive problems on both macroelectrode and microelectrode voltammetry. Convection, hydrodynamic electrodes, homogeneous kinetics, adsorption and electroanalytical applications are discussed in the later chapters, as well as problems on two rapidly developing fields of voltammetry: weakly supported media and nanoscale electrodes.There is huge interest in the experimental procedure of voltammetry at present, and yet no dedicated question and answer book with exclusive voltammetric focus exists, in spite of the inherent challenges of the subject. This book aims to fill that niche.
Author: Richard Guy Compton
Publisher: World Scientific Publishing Company
ISBN: 1848169515
Category : Science
Languages : en
Pages : 270
Get Book Here
Book Description
The field of electrochemical measurement, with respect to thermodynamics, kinetics and analysis, is widely recognised but the subject can be unpredictable to the novice, even if they have a strong physical and chemical background, especially if they wish to pursue quantitative measurements. Accordingly, some significant experiments are, perhaps wisely, never attempted, while the literature is sadly replete with flawed attempts at rigorous voltammetry.This book presents problems and worked solutions for a wide range of theoretical and experimental subjects in the field of voltammetry. The reader is assumed to have knowledge up to a Master's level of physical chemistry, but no exposure to electrochemistry in general, or voltammetry in particular, is required. The problems included range in difficulty from senior undergraduate to research level, and develop important practical approaches in voltammetry.The problems presented in the earlier chapters focus on the fundamental theories of thermodynamics, electron transfer and diffusion. Voltammetric experiments and their analysis are then considered, including extensive problems on both macroelectrode and microelectrode voltammetry. Convection, hydrodynamic electrodes, homogeneous kinetics, adsorption and electroanalytical applications are discussed in the later chapters, as well as problems on two rapidly developing fields of voltammetry: weakly supported media and nanoscale electrodes.There is huge interest in the experimental procedure of voltammetry at present, and yet no dedicated question and answer book with exclusive voltammetric focus exists, in spite of the inherent challenges of the subject. This book aims to fill that niche.
Author: R. G. Compton
Publisher: World Scientific
ISBN: 9812706259
Category : Science
Languages : en
Pages : 384
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Book Description
Considers how to go about designing, explaining and interpreting experiments centered around various forms of voltammetry (cyclic, microelectrode, hydrodynamic, and so on). This book gives introductions to the theories of electron transfer and of diffusion. It also introduces convection and describes hydrodynamic electrodes.
Author: Richard Guy Compton
Publisher: World Scientific
ISBN: 1786348322
Category : Science
Languages : en
Pages : 324
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Book Description
This is the first textbook in the field of electrochemistry that will teach experimental electrochemists how to carry out simulation of electrode processes. Processes at both macro- and micro-electrodes are examined and the simulation of both diffusion-only and diffusion-convection processes are addressed. The simulation of processes with coupled homogeneous kinetics and at microelectrode arrays are further discussed.Over the course of the book the reader's understanding is developed to the point where they will be able to undertake and solve research-level problems. The book leads the reader through from a basic understanding of the principles underlying electrochemical simulation to the development of computer programs which describe the complex processes found in voltammetry.This second edition has been revised throughout, and contains new material relating to random walks in electrochemistry, as well as expanded materials on the checking and validation of simulations, pulse techniques, and square wave voltammetry.
Author: R. G. Compton
Publisher: World Scientific
ISBN: 1786348314
Category : Electrochemistry
Languages : en
Pages : 324
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Book Description
Preface to the second edition -- Preface to the first edition - Introduction -- Mathematical model of an electrochemical system -- Numerical solution of the model system -- Diffusion-only electrochemical problems in one-dimensional systems -- First-order chemical kinetic mechanisms -- Second-order chemical kinetic mechanisms -- Electrochemical simulation in weakly supported media -- Hydrodynamic voltammetry -- Two-dimensional systems: microdisc electrodes -- Heterogeneous surfaces -- Stochastic electrochemistry.
Author: Richard G Compton
Publisher: World Scientific
ISBN: 1786345285
Category : Science
Languages : en
Pages :
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Book Description
he power of electrochemical measurements in respect of thermodynamics, kinetics and analysis is widely recognised but the subject can be unpredictable to the novice even if they have a strong physical and chemical background, especially if they wish to pursue quantitative measurements. Accordingly, some significant experiments are perhaps wisely never attempted while the literature is sadly replete with flawed attempts at rigorous voltammetry. This textbook considers how to implement designing, explaining and interpreting experiments centered on various forms of voltammetry (cyclic, microelectrode, hydrodynamic, etc.). The reader is assumed to have knowledge of physical chemistry equivalent to Master's level but no exposure to electrochemistry in general, or voltammetry in particular. While the book is designed to stand alone, references to important research papers are given to provide an introductory entry into the literature. The third edition contains new material relating to electron transfer theory, experimental requirements, scanning electrochemical microscopy, adsorption, electroanalysis and nanoelectrochemistry.
Author: Richard Guy Compton
Publisher: World Scientific
ISBN: 1783263261
Category : Science
Languages : en
Pages : 260
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Book Description
This is the first textbook in the field of electrochemistry that will teach experimental electrochemists how to carry out simulation of electrode processes. Processes at both macro- and micro-electrodes are examined and the simulation of both diffusion-only and diffusion-convection processes are addressed. The simulation of processes with coupled homogeneous kinetics and at microelectrode arrays are further discussed. Over the course of the book the reader's understanding is developed to the point where they will be able to undertake and solve research-level problems. The book leads the reader through from a basic understanding of the principles underlying electrochemical simulation to the development of computer programs which describe the complex processes found in voltammetry.This is the third book in the “Understanding Voltammetry” series, published with Imperial College Press and written by the Compton group. Other books in the series include “Understanding Voltammetry”, written by Richard G Compton with Craig Banks and also “Understanding Voltammetry: Problems and Solutions” (2012) written by Richard G Compton with Christopher Batchelor-McAuley and Edmund Dickinson. These are and continue to be successful textbooks for graduates in electrochemistry and electroanalytical studies.
Author: Allen J. Bard
Publisher: Wiley Global Education
ISBN: 1118312805
Category : Science
Languages : de
Pages : 862
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Book Description
Das führende Werk auf seinem Gebiet - jetzt durchgängig auf den neuesten Stand gebracht! Die theoretischen Grundlagen der Elektrochemie, erweitert um die aktuellsten Erkenntnisse in der Theorie des Elektronentransfers, werden hier ebenso besprochen wie alle wichtigen Anwendungen, darunter modernste Verfahren (Ultramikroelektroden, modifizierte Elektroden, LCEC, Impedanzspektrometrie, neue Varianten der Pulsvoltammetrie und andere). In erster Linie als Lehrbuch gedacht, läßt sich das Werk aber auch hervorragend zum Selbststudium und zur Auffrischung des Wissensstandes verwenden. Lediglich elementare Grundkenntnisse der physikalischen Chemie werden vorausgesetzt.
Author: Joseph Wang
Publisher: John Wiley & Sons
ISBN: 0471460796
Category : Science
Languages : en
Pages : 228
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Book Description
The critically acclaimed guide to the principles, techniques, and instruments of electroanalytical chemistry-now expanded and revised Joseph Wang, internationally renowned authority on electroanalytical techniques, thoroughly revises his acclaimed book to reflect the rapid growth the field has experienced in recent years. He substantially expands the theoretical discussion while providing comprehensive coverage of the latest advances through late 1999, introducing such exciting new topics as self-assembled monolayers, DNA biosensors, lab-on-a-chip, detection for capillary electrophoresis, single molecule detection, and sol-gel surface modification. Along with numerous references from the current literature and new worked-out examples, Analytical Electrochemistry, Second Edition offers clear, reader-friendly explanations of the fundamental principles of electrochemical processes as well as important insight into the potential of electroanalysis for problem solving in a wide range of fields, from clinical diagnostics to environmental science. Key topics include: The basics of electrode reactions and the structure of the interfacial region Tools for elucidating electrode reactions and high-resolution surface characterization An overview of finite-current controlled potential techniques Electrochemical instrumentation and electrode materials Principles of potentiometric measurements and ion-selective electrodes Chemical sensors, including biosensors, gas sensors, solid-state devices, and sensor arrays
Author: Yuki Saito
Publisher: Nova Science Publishers
ISBN: 9781629480572
Category : Science
Languages : en
Pages : 0
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Book Description
Voltammetry is the study of current as a function of applied potential and is a category of electroanalytical methods used in analytical chemistry and various industrial processes. In this book, the authors discuss the theory, types and applications of voltammetry. Topics include voltammetric techniques in electrocatalytic studies; voltammetry and stoichography for studying the chemical composition and real structure of solid inorganic substances and materials; voltammetric techniques applied on organic compounds related to agroalimentary and health systems; using voltammetry as a promising analytical technique in the study of compounds of biological importance; automatised determination of metallothionein by adsorptive transfer stripping techniques coupled with Brdicka reaction; overcoming drawbacks and going further with practical electroanalysis; voltammetric determination of metals as food contaminants; dual dynamic voltammetry with rotating ring-disk electrodes; linear voltammetry of anodic selective dissolution of homogeneous metallic alloys; electrooxidation of glycine and a-alanine on platinum; and temperature responses in linear voltammetry.
Author: Derek Pletcher
Publisher: Royal Society of Chemistry
ISBN: 1788018249
Category : Science
Languages : en
Pages : 315
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Book Description
This user friendly introduction highlights the importance of electrochemistry and its applications to the modern world and the future. In contrast to other texts currently available, it emphasises understanding and avoids using many pages of complex equations. It also describes the diverse applications of electrochemistry rather than focusing on analytical chemistry alone. Although the book follows a similar structure to the first edition, the earlier chapters have been extensively up-dated and the later chapters are entirely new. The text is supported by a large number of figures which illustrate key points. The book starts by describing the essential electrochemical techniques before moving on to cover experimental problems and applications. To reflect the present interest in fuel cells and the environment, these have become the focus of the final chapters. A useful appendix contains problems with fully worked answers to test the reader's understanding.
