Author: Heike Pfau
Publisher: Springer
ISBN: 3319395432
Category : Technology & Engineering
Languages : en
Pages : 133
Book Description
This thesis explores thermal transport in selected rare-earth-based intermetallic compounds to answer questions of great current interest. It also sheds light on the interplay of Kondo physics and Fermi surface changes. By performing thermal conductivity and electrical resistivity measurements at temperatures as low as 25mK, the author demonstrates that the Wiedemann–Franz law, a cornerstone of metal physics, is violated at precisely the magnetic-field-induced quantum critical point of the heavy-fermion metal YbRh2Si2. This first-ever observation of a violation has dramatic consequences, as it implies a breakdown of the quasiparticle picture. Utilizing an innovative technique to measure low-temperature thermal transport isothermally as a function of the magnetic field, the thesis interprets specific, partly newly discovered, high-field transitions in CeRu2Si2 and YbRh2Si2 as Lifshitz transitions related to a change in the Fermi surface. Lastly, by applying this new technique to thermal conductivity measurements of the skutterudite superconductor LaPt4Ge12, the thesis proves that the system is a conventional superconductor with a single energy gap. Thus, it refutes the widespread speculations about unconventional Cooper pairing in this material.
Thermal Transport in Strongly Correlated Rare-Earth Intermetallic Compounds
Author: Heike Pfau
Publisher: Springer
ISBN: 3319395432
Category : Technology & Engineering
Languages : en
Pages : 133
Book Description
This thesis explores thermal transport in selected rare-earth-based intermetallic compounds to answer questions of great current interest. It also sheds light on the interplay of Kondo physics and Fermi surface changes. By performing thermal conductivity and electrical resistivity measurements at temperatures as low as 25mK, the author demonstrates that the Wiedemann–Franz law, a cornerstone of metal physics, is violated at precisely the magnetic-field-induced quantum critical point of the heavy-fermion metal YbRh2Si2. This first-ever observation of a violation has dramatic consequences, as it implies a breakdown of the quasiparticle picture. Utilizing an innovative technique to measure low-temperature thermal transport isothermally as a function of the magnetic field, the thesis interprets specific, partly newly discovered, high-field transitions in CeRu2Si2 and YbRh2Si2 as Lifshitz transitions related to a change in the Fermi surface. Lastly, by applying this new technique to thermal conductivity measurements of the skutterudite superconductor LaPt4Ge12, the thesis proves that the system is a conventional superconductor with a single energy gap. Thus, it refutes the widespread speculations about unconventional Cooper pairing in this material.
Publisher: Springer
ISBN: 3319395432
Category : Technology & Engineering
Languages : en
Pages : 133
Book Description
This thesis explores thermal transport in selected rare-earth-based intermetallic compounds to answer questions of great current interest. It also sheds light on the interplay of Kondo physics and Fermi surface changes. By performing thermal conductivity and electrical resistivity measurements at temperatures as low as 25mK, the author demonstrates that the Wiedemann–Franz law, a cornerstone of metal physics, is violated at precisely the magnetic-field-induced quantum critical point of the heavy-fermion metal YbRh2Si2. This first-ever observation of a violation has dramatic consequences, as it implies a breakdown of the quasiparticle picture. Utilizing an innovative technique to measure low-temperature thermal transport isothermally as a function of the magnetic field, the thesis interprets specific, partly newly discovered, high-field transitions in CeRu2Si2 and YbRh2Si2 as Lifshitz transitions related to a change in the Fermi surface. Lastly, by applying this new technique to thermal conductivity measurements of the skutterudite superconductor LaPt4Ge12, the thesis proves that the system is a conventional superconductor with a single energy gap. Thus, it refutes the widespread speculations about unconventional Cooper pairing in this material.
Scientific and Technical Aerospace Reports
Author:
Publisher:
ISBN:
Category : Aeronautics
Languages : en
Pages : 652
Book Description
Publisher:
ISBN:
Category : Aeronautics
Languages : en
Pages : 652
Book Description
Introduction to Condensed Matter Chemistry
Author: Jihong Yu
Publisher: Elsevier
ISBN: 0443161410
Category : Technology & Engineering
Languages : en
Pages : 462
Book Description
Introduction to Condensed Matter Chemistry offers a general view of chemistry from the perspective of condensed matter chemistry, analyzing and contrasting chemical reactions in a more realistic setting than traditional thinking. Readers will also find discussions on the goals and major scientific questions in condensed matter chemistry and the molecular engineering of functional condensed matter. Processes and products of chemical reactions should not be determined solely by the structure and composition of these basic species but also by the complex and possibly multilevel structured physical and chemical environment, together referred to as their condensed state. Relevant matters in condensed state should be the main bodies of chemical reactions, which is applicable not only to solids and liquids but also to gas molecules as reactions among gas molecules can take place only in the presence of catalysts in specific condensed states or after their state transition under extreme reaction conditions. This book provides new insights on the liquid state chemistry, definitions, aspects, and interactions, summarizing fundamentals of main chemical reactions from a new perspective. - Helps to establish the new field of Condensed Matter Chemistry - Highlights the molecular engineering of functional condensed matter - Focuses on both liquid and solid state chemistry
Publisher: Elsevier
ISBN: 0443161410
Category : Technology & Engineering
Languages : en
Pages : 462
Book Description
Introduction to Condensed Matter Chemistry offers a general view of chemistry from the perspective of condensed matter chemistry, analyzing and contrasting chemical reactions in a more realistic setting than traditional thinking. Readers will also find discussions on the goals and major scientific questions in condensed matter chemistry and the molecular engineering of functional condensed matter. Processes and products of chemical reactions should not be determined solely by the structure and composition of these basic species but also by the complex and possibly multilevel structured physical and chemical environment, together referred to as their condensed state. Relevant matters in condensed state should be the main bodies of chemical reactions, which is applicable not only to solids and liquids but also to gas molecules as reactions among gas molecules can take place only in the presence of catalysts in specific condensed states or after their state transition under extreme reaction conditions. This book provides new insights on the liquid state chemistry, definitions, aspects, and interactions, summarizing fundamentals of main chemical reactions from a new perspective. - Helps to establish the new field of Condensed Matter Chemistry - Highlights the molecular engineering of functional condensed matter - Focuses on both liquid and solid state chemistry
Proceedings of the National Academy of Sciences of the United States of America
Author: National Academy of Sciences (U.S.).
Publisher:
ISBN:
Category : Science
Languages : en
Pages : 1276
Book Description
Publisher:
ISBN:
Category : Science
Languages : en
Pages : 1276
Book Description
Nuclear Science Abstracts
Author:
Publisher:
ISBN:
Category : Nuclear energy
Languages : en
Pages : 722
Book Description
Publisher:
ISBN:
Category : Nuclear energy
Languages : en
Pages : 722
Book Description
Energy Research Abstracts
Author:
Publisher:
ISBN:
Category : Power resources
Languages : en
Pages : 980
Book Description
Publisher:
ISBN:
Category : Power resources
Languages : en
Pages : 980
Book Description
Alloys and Intermetallic Compounds
Author: Cristina Artini
Publisher: CRC Press
ISBN: 1351647652
Category : Science
Languages : en
Pages : 267
Book Description
This book focuses on the role of modeling in the design of alloys and intermetallic compounds. It includes an introduction to the most important and most used modeling techniques, such as CALPHAD and ab-initio methods, as well as a section devoted to the latest developments in applications of alloys. The book emphasizes the correlation between modeling and technological developments while discussing topics such as wettability of Ultra High Temperature Ceramics by metals, active brazing of diamonds to metals in cutting tools, surface issues in medicine, novel Fe-based superconductors, metallic glasses, high entropy alloys, and thermoelectric materials.
Publisher: CRC Press
ISBN: 1351647652
Category : Science
Languages : en
Pages : 267
Book Description
This book focuses on the role of modeling in the design of alloys and intermetallic compounds. It includes an introduction to the most important and most used modeling techniques, such as CALPHAD and ab-initio methods, as well as a section devoted to the latest developments in applications of alloys. The book emphasizes the correlation between modeling and technological developments while discussing topics such as wettability of Ultra High Temperature Ceramics by metals, active brazing of diamonds to metals in cutting tools, surface issues in medicine, novel Fe-based superconductors, metallic glasses, high entropy alloys, and thermoelectric materials.
Encyclopedia of Materials
Author: K. H. J. Buschow
Publisher:
ISBN:
Category : Materials
Languages : en
Pages : 856
Book Description
Accompanyind CR-ROM conrtains The Encyclopedia of Materials Science and Technology on a web access disc.
Publisher:
ISBN:
Category : Materials
Languages : en
Pages : 856
Book Description
Accompanyind CR-ROM conrtains The Encyclopedia of Materials Science and Technology on a web access disc.
Scientific Bulletin
Author:
Publisher:
ISBN:
Category : Research
Languages : en
Pages : 802
Book Description
Publisher:
ISBN:
Category : Research
Languages : en
Pages : 802
Book Description
Rare-Earths and Actinides in High Energy Spectroscopy
Author: Christiane Bonnelle
Publisher: Springer
ISBN: 904812879X
Category : Science
Languages : en
Pages : 393
Book Description
This unique monograph covers recent theoretical and experimental results on the complex character of f electrons in materials containing lanthanides (rare earths) or actinides, such as alpha-cerium and delta-plutonium. It answers the urgent need for a general presentation of the body of experimental and theoretical results presently available in this challenging domain. Some of the fast developing applications of lanthanide and actinide materials are mentioned. Materials containing atoms with an open f shell have electronic and crystalline properties that are controlled by the localized or delocalized character of the f electrons. This book gives a theoretical discussion of the various spectroscopic methods that shed light on the character of the f electrons and on the connection between their localization and the properties of these materials. Part 1 covers the characteristics of the f electrons in atoms and solids and includes a discussion of the properties of lanthanides and actinides in connection with the f electrons. Part 2 describes the various spectroscopic methods that are used to establish the electronic distributions and energies of the states. Examples involve the determination of f electron distributions by high energy spectroscopy methods with separate treatment of the valence and core electrons. Part 3 concentrates on the theoretical treatment of electronic transitions involving f electrons and simulations of the lanthanide spectra, including comparison with the available experimental data. Part 4 discusses the localized or delocalized character of the f electrons in actinides and their compounds, including comparison (analogies & differences) between the 4f and 5f electron materials. This monograph should be of great value for researchers, academics and engineers working in the fields of high energy spectroscopy, electronic and nuclear science and technology, as well as materials involving rare earths and radio-elements.
Publisher: Springer
ISBN: 904812879X
Category : Science
Languages : en
Pages : 393
Book Description
This unique monograph covers recent theoretical and experimental results on the complex character of f electrons in materials containing lanthanides (rare earths) or actinides, such as alpha-cerium and delta-plutonium. It answers the urgent need for a general presentation of the body of experimental and theoretical results presently available in this challenging domain. Some of the fast developing applications of lanthanide and actinide materials are mentioned. Materials containing atoms with an open f shell have electronic and crystalline properties that are controlled by the localized or delocalized character of the f electrons. This book gives a theoretical discussion of the various spectroscopic methods that shed light on the character of the f electrons and on the connection between their localization and the properties of these materials. Part 1 covers the characteristics of the f electrons in atoms and solids and includes a discussion of the properties of lanthanides and actinides in connection with the f electrons. Part 2 describes the various spectroscopic methods that are used to establish the electronic distributions and energies of the states. Examples involve the determination of f electron distributions by high energy spectroscopy methods with separate treatment of the valence and core electrons. Part 3 concentrates on the theoretical treatment of electronic transitions involving f electrons and simulations of the lanthanide spectra, including comparison with the available experimental data. Part 4 discusses the localized or delocalized character of the f electrons in actinides and their compounds, including comparison (analogies & differences) between the 4f and 5f electron materials. This monograph should be of great value for researchers, academics and engineers working in the fields of high energy spectroscopy, electronic and nuclear science and technology, as well as materials involving rare earths and radio-elements.