Thermal Electrocyclic Reactions PDF Download
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Author: Elliot Marvell
Publisher: Elsevier
ISBN: 0323150454
Category : Science
Languages : en
Pages : 435
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Book Description
Thermal Electrocyclic Reactions explores the applications of thermal electrocyclic reactions to stereospecific synthesis. This book is divided into nine chapters, and begins with a presentation of the theory of electrocylic reactions using orbital conversions through symmetry operations and correlation diagrams. Considerable chapters are devoted to various conjugate systems entering an electrocyclic process, including two-electron, four electron-three-, four-, and five-atom, and six electron-five-, and six-atom systems. The remaining chapters examine the electrocyclic reaction of longer systems, including eight or more p electrons, as well as conjugated systems with an odd number of electrons, which constitute a special case in the conservation of orbital symmetry. This book will be of great value to organic chemists and researchers.
Author: Elliot Marvell
Publisher: Elsevier
ISBN: 0323150454
Category : Science
Languages : en
Pages : 435
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Book Description
Thermal Electrocyclic Reactions explores the applications of thermal electrocyclic reactions to stereospecific synthesis. This book is divided into nine chapters, and begins with a presentation of the theory of electrocylic reactions using orbital conversions through symmetry operations and correlation diagrams. Considerable chapters are devoted to various conjugate systems entering an electrocyclic process, including two-electron, four electron-three-, four-, and five-atom, and six electron-five-, and six-atom systems. The remaining chapters examine the electrocyclic reaction of longer systems, including eight or more p electrons, as well as conjugated systems with an odd number of electrons, which constitute a special case in the conservation of orbital symmetry. This book will be of great value to organic chemists and researchers.
Author: Edward Adam Kallel
Publisher:
ISBN:
Category :
Languages : en
Pages : 306
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Book Description
Author: T. L. Gilchrist
Publisher: Cambridge University Press
ISBN: 9780521220149
Category : Science
Languages : en
Pages : 324
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Book Description
First published in 1979 as the second edition of a 1972 original, this textbook provides a systematic account of an important area of organic chemistry - that of cycloadditions and molecular rearrangements. The necessary theoretical background for understanding these reactions is presented in non-mathematical form and various alternative approaches to the theory are compared. The core of the book is a descriptive account of various types of cycloaddition and rearrangement reactions. The synthetic importance of these reactions is emphasised and, by providing the mechanistic background, the book demonstrates to the reader the relationship between the different types of reactions. This book will be of value to anyone with an interest in organic chemistry.
Author: R. B. Woodward
Publisher: Elsevier
ISBN: 148328204X
Category : Science
Languages : en
Pages : 185
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Book Description
The Conservation of Orbital Symmetry examines the principle of conservation of orbital symmetry and its use. The central content of the principle was that reactions occur readily when there is congruence between orbital symmetry characteristics of reactants and products, and only with difficulty when that congruence does not obtain—or to put it more succinctly, orbital symmetry is conserved in concerted reaction. This principle is expected to endure, whatever the language in which it may be couched, or whatever greater precision may be developed in its application and extension. The book opens with a review of the elementary aspects of the molecular orbital theory of bonding. This is followed by separate chapters on correlation diagrams, the conservation of orbital symmetry, theory of electrocyclic reactions, theory of cycloadditions and cycloreversions, and theory of sigmatropic reactions. Subsequent chapters deal with group transfers and eliminations; secondary conformational effects in concerted cycloaddition reactions; and generalized selection rules for pericyclic reactions.
Author: Joseph J. Gajewski
Publisher: Elsevier
ISBN: 0080472982
Category : Science
Languages : en
Pages : 465
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Book Description
Hydrocarbon Thermal Isomerizations summarizes rearrangements which are induced by heating neutral hydrocarbons under non-catalytic conditions in the vapor phase or in non-polar solution. This subject has attracted the interest of mechanistic organic chemists and theorists in the last quarter century because it is one of the few fields workable by state of the art techniques of both camps. This work collects together most of the crucial rate and stereochemical data in a single volume, along with a critical analysis of each of these reactions. Unlike reviews or other books in this area that focus on reaction types, e.g.. electrocyclic reactions, or Claisen rearrangements, this volume is organized like the Chemical Abstracts Formula Index, but with an important exception: all of the relevant derivatives of each parent compound are discussed with the parent and not in their logical formula index positions. As it is not always obvious what is a parent material and what is a derivative, detailed cross-references are included throughout. An important aspect of this edition is the inclusion of calculational results that provide insight, often more than was anticipated, into these relatively simple reactions. Energetics of thermal isomerization reactions Stereochemistry of thermal isomerization reactions Organization to facilitate and integrate global analyses Comparison of experimental and theoretical results
Author: W. Carruthers
Publisher: Cambridge University Press
ISBN: 1107567459
Category : Political Science
Languages : en
Pages : 506
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Book Description
Textbook on modern methods of organic synthesis.
Author: Metin Balcı
Publisher: John Wiley & Sons
ISBN: 3527349642
Category : Science
Languages : en
Pages : 644
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Book Description
An accessible and step-by-step exploration of organic reaction mechanisms In Reaction Mechanisms in Organic Chemistry, eminent researcher Dr. Metin Balci delivers an excellent textbook for understanding organic reaction mechanisms. The book offers a way for undergraduate and graduate students to understand???rather than memorize???the principles of reaction mechanisms. It includes the most important reaction types, including substitution, elimination, addition, pericyclic, and C-C coupling reactions. Each chapter contains problems and accompanying solutions that cover central concepts in organic chemistry. Students will learn to understand the foundational nature of ideas like Lewis acids and bases, electron density, the mesomeric effect, and the inductive effect via the use of detailed examples and an expansive discussion of the concept of hybridization. Along with sections covering aromaticity and the chemistry of intermediates, the book includes: A thorough introduction to basic concepts in organic reactions, including covalent bonding, hybridization, electrophiles and nucleophiles, and inductive and mesomeric effects Comprehensive explorations of nucleophilic substitution reactions, including optical activity and stereochemistry of SN2 reactions Practical discussions of elimination reactions, including halogene elimination and Hofmann elimination In-depth examinations of addition reactions, including the addition of water to alkenes and the epoxidation of alkenes Perfect for students of chemistry, biochemistry, and pharmacy, Reaction Mechanisms in Organic Chemistry will also earn a place in the libraries of researchers and lecturers in these fields seeking a one-stop resource on organic reaction mechanisms.
Author: Dr. Rajshree Khare
Publisher: Thakur Publication Private Limited
ISBN: 9357555501
Category : Education
Languages : en
Pages : 224
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Book Description
Revised Curriculum and Credit Framework of Under Graduate Programme, Haryana According to KUK/CRS University Syllabus as Per NEP-2020.
Author: Paul H. Scudder
Publisher: John Wiley & Sons
ISBN: 1119718996
Category : Science
Languages : en
Pages : 612
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Book Description
Electron Flow in Organic Chemistry Teaches students to solve problems in Organic Chemistry using methods of analysis that are valuable and portable to other fields Electron Flow in Organic Chemistry provides a unique decision-based approach that develops a chemical intuition based on a crosschecked analysis process. Assuming only a general background in chemistry, this acclaimed textbook teaches students how to write reasonable reaction mechanisms and use analytical tools to solve both simple and complex problems in organic chemistry. As in previous editions, the author breaks down challenging organic mechanisms into a limited number of core elemental mechanistic processes, the electron flow pathways, to explain all organic reactions—using flow charts as decision maps, energy surfaces as problem space maps, and correlation matrices to display all possible interactions. The third edition features entirely new chapters on crosschecking chemical reactions through good mechanistic thinking and solving spectral analysis problems using organic structure elucidation strategies. This edition also includes more biochemical reaction mechanism examples, additional exercises with answers, expanded discussion of how general chemistry concepts can show that structure determines reactivity, and new appendix covering transition metal organometallics. Emphasizing critical thinking rather than memorization to solve mechanistic problems, this popular textbook: Features new and expanded material throughout, including more flowcharts, correlation matrices, energy surfaces, and algorithms that illustrate key decision-making processes Provides examples from the field of biochemistry of relevance to students in chemistry, biology, and medicine Incorporates principles from computer science and artificial intelligence to teach decision-making processes Contains a general bibliography, quick-reference charts and tables, pathway summaries, a major decisions guide, and other helpful tools Offers material for instructors including a solutions manual, supplemental exercises with detailed answers for each chapter usable as an exam file, and additional online resources Electron Flow in Organic Chemistry: A Decision-Based Guide to Organic Mechanisms, Third Edition, is the perfect primary textbook for advanced undergraduate or beginning graduate courses in organic reaction mechanisms, and an excellent supplement for graduate courses in physical organic chemistry, enzymatic reaction mechanisms, and biochemistry.
Author: Audrey Miller
Publisher: Academic Press
ISBN: 9780124967120
Category : Science
Languages : en
Pages : 492
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Book Description
This book helps students understand functional group transformations and synthetic methods by organizing them into a set of general principles and guidelines for determining and writing mechanisms."--BOOK JACKET.
