Dianion Chemistry in Organic Synthesis PDF Download
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Author: Charles M. Thompson
Publisher: CRC Press
ISBN: 9780849378683
Category : Science
Languages : en
Pages : 264
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Book Description
Many laboratories were reluctant at first to embrace dianion chemistry as part of the standard reaction repertoire. Today, however, researchers can comfortably draw upon the dianion literature to choose an abundance of reagents and strategies that are reliable, effective, and, in many cases, the best answer to a synthetic problem. This interesting book introduces, surveys, and consolidates carbon-based dianion chemistry. Chapter 1 serves as an introduction and as an index of the various dianions covered in the book. Chapters 2 through 5 cover the ensemble of dianion types designated by their first deprotonation site. Each chapter contains an experimental section that explains relevant protocols.
Author: Charles M. Thompson
Publisher: CRC Press
ISBN: 9780849378683
Category : Science
Languages : en
Pages : 264
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Book Description
Many laboratories were reluctant at first to embrace dianion chemistry as part of the standard reaction repertoire. Today, however, researchers can comfortably draw upon the dianion literature to choose an abundance of reagents and strategies that are reliable, effective, and, in many cases, the best answer to a synthetic problem. This interesting book introduces, surveys, and consolidates carbon-based dianion chemistry. Chapter 1 serves as an introduction and as an index of the various dianions covered in the book. Chapters 2 through 5 cover the ensemble of dianion types designated by their first deprotonation site. Each chapter contains an experimental section that explains relevant protocols.
Author: Michael Smith
Publisher: Academic Press
ISBN: 0128008075
Category : Science
Languages : en
Pages : 1108
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Book Description
Organic Synthesis, Fourth Edition, provides a reaction-based approach to this important branch of organic chemistry. Updated and accessible, this eagerly-awaited revision offers a comprehensive foundation for graduate students coming from disparate backgrounds and knowledge levels, to provide them with critical working knowledge of basic reactions, stereochemistry and conformational principles. This reliable resource uniquely incorporates molecular modeling content, problems, and visualizations, and includes reaction examples and homework problems drawn from the latest in the current literature. In the Fourth Edition, the organization of the book has been improved to better serve students and professors and accommodate important updates in the field. The first chapter reviews basic retrosynthesis, conformations and stereochemistry. The next three chapters provide an introduction to and a review of functional group exchange reactions; these are followed by chapters reviewing protecting groups, oxidation and reduction reactions and reagents, hydroboration, selectivity in reactions. A separate chapter discusses strategies of organic synthesis, and he book then delves deeper in teaching the reactions required to actually complete a synthesis. Carbon-carbon bond formation reactions using both nucleophilic carbon reactions are presented, and then electrophilic carbon reactions, followed by pericyclic reactions and radical and carbene reactions. The important organometallic reactions have been consolidated into a single chapter. Finally, the chapter on combinatorial chemistry has been removed from the strategies chapter and placed in a separate chapter, along with valuable and forward-looking content on green organic chemistry, process chemistry and continuous flow chemistry. Throughout the text, Organic Synthesis, Fourth Edition utilizes Spartan-generated molecular models, class tested content, and useful pedagogical features to aid student study and retention, including Chapter Review Questions, and Homework Problems. A full Solutions Manual is also available online for qualified instructors, to support teaching. - Winner, 2018 Textbook Excellence Award (Texty) from the Textbook and Academic Authors Association - Fully revised and updated throughout, and organized into 19 chapters for a more cogent and versatile presentation of concepts - Includes reaction examples taken from literature research reported between 2010-2015 - Features new full-color art and new chapter content on process chemistry and green organic chemistry - Offers valuable study and teaching tools, including Chapter Review Questions and Homework Problems for students; Solutions Manual for qualified course instructors
Author: Adam Jacobs
Publisher: Cambridge University Press
ISBN: 9780521467766
Category : Science
Languages : en
Pages : 328
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Book Description
First/second year text in chemistry.
Author: Dr. Rajesh Chandra Verma
Publisher: Thakur Publication Private Limited
ISBN: 9357552707
Category : Education
Languages : en
Pages : 320
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Book Description
Buy ORGANIC SYNTHESIS-A Paper-I e-Book in English Language for B.Sc 5th Semester UP State Universities By Thakur publication.
Author: S. G. Davies
Publisher: Elsevier
ISBN: 1483285847
Category : Science
Languages : en
Pages : 430
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Book Description
Although organotransition metal chemistry has been developing rapidly over the past 20 years, it is only recently that applications of transition metal complexes to organic synthesis have started to be exploited. This unique book provides an introduction to organometallic chemistry for chemists who have little or no experience in the field, describes the work that has already been done using organotransition metal complexes for synthesis, and indicates to organic and organometallic chemists the type of synthetic problems that can be solved using organometallic compounds. It covers all major advances that have been made in this rapidly expanding area of chemistry, including not only reactions that already have well established applications for synthesis but also many recently discovered potentially useful reactions, providing a survey of recent literature.
Author: Jie Jack Li
Publisher: CRC Press
ISBN: 1315353199
Category : Medical
Languages : en
Pages : 304
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Book Description
Gives a comprehensive and up-to-date summary of carbocation chemistry. Discusses the widespread applications of carbocation chemistry, with an emphasis on organic synthesis. Contains the contributions of highly experienced authors. Provides a panoramic view of carbocation chemistry, which is part of the foundation of organic chemistry.
Author: A. Bruylants
Publisher: Butterworth-Heinemann
ISBN: 1483156176
Category : Science
Languages : en
Pages : 278
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Book Description
Organic Synthesis is a collection of papers dealing with synthetic tools, the effect of pressure on the electronic states of organic solids, and some novel approaches to alkylations. Some papers explain the cyclopropanation of silyl enol ethers and the two-phase reactions in the chemistry of carbanions and halocarbenes as useful tools in organic synthesis. One paper investigates the "biogenetic-type" synthesis of the bicyclic penicillin-cephalosporin antibiotics from an acyclic tripeptide equivalent. Another paper explains the advantages of the two-phase system to generate trihalomethylanions and dihalocarbenes as it allows the investigator to carry out all the reactions typical for these species easily. The system also readily applies to the reactions of some carbanions with aromatic nitrocompounds. Thallium(III) nitrate (TTN) can be used as an oxidant in organic synthesis; reactions that follow it use include the oxidations and oxidative rearrangements of olefins, acetylenes, ketones and compounds containing carbon-nitrogen double bonds. Another paper presents some examples that use singlet oxygen in synthetic organic chemistry. This collection is useful for researchers, technicians, and scientists whose works involve organic chemistry, analytical chemistry, and other related fields of chemistry, such as physical chemistry and inorganic chemistry.
Author:
Publisher: Newnes
ISBN: 008097743X
Category : Science
Languages : en
Pages : 9815
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Book Description
The second edition of Comprehensive Organic Synthesis—winner of the 2015 PROSE Award for Multivolume Reference/Science from the Association of American Publishers—builds upon the highly respected first edition in drawing together the new common themes that underlie the many disparate areas of organic chemistry. These themes support effective and efficient synthetic strategies, thus providing a comprehensive overview of this important discipline. Fully revised and updated, this new set forms an essential reference work for all those seeking information on the solution of synthetic problems, whether they are experienced practitioners or chemists whose major interests lie outside organic synthesis. In addition, synthetic chemists requiring the essential facts in new areas, as well as students completely new to the field, will find Comprehensive Organic Synthesis, Second Edition, Nine Volume Set an invaluable source, providing an authoritative overview of core concepts. Winner of the 2015 PROSE Award for Multivolume Reference/Science from the Association of American Publishers Contains more than170 articles across nine volumes, including detailed analysis of core topics such as bonds, oxidation, and reduction Includes more than10,000 schemes and images Fully revised and updated; important growth areas—including combinatorial chemistry, new technological, industrial, and green chemistry developments—are covered extensively
Author: P. Perlmutter
Publisher: Elsevier
ISBN: 1483293785
Category : Science
Languages : en
Pages : 394
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Book Description
This book provides an introduction to the chemistry of conjugate reactions, a group of reactions that constitute one of the most important classes of chemical reactions in organic synthesis. The book is organised in terms of the major classes of conjugate acceptors. Within each of these classes, the chemistry and applications of conjugate additions with several different categories of nucleophiles have been examined. Where several different nucleophiles achieve the same synthetic transformation, they are cross-referenced within the book and qualitative comparisons offered where appropriate. Examples of the use of conjugate additions in total synthesis of important molecules are included, with a special emphasis throughout the book on stereoselectivity. This will be a useful main text for graduate and postgraduate courses on conjugate addition reactions or the Michael reaction. It could also serve as a supplementary text for courses on topics such as the chemistry of organocopper reagents, enamines and carbanion chemistry.
Author: Janos Fendler
Publisher: Elsevier
ISBN: 0323146015
Category : Science
Languages : en
Pages : 561
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Book Description
Catalysis in Micellar and Macromolecular Systems provides a comprehensive monograph on the catalyses elicited by aqueous and nonaqueous micelles, synthetic and naturally occurring polymers, and phase-transfer catalysts. It delineates the principles involved in designing appropriate catalytic systems throughout. Additionally, an attempt has been made to tabulate the available data exhaustively. The book discusses the preparation and purification of surfactants; the physical and chemical properties of surfactants and micelles; solubilization in aqueous micellar systems; and the principles of micellar catalysis. Separate chapters cover micellar catalysis of hydrolyses, solvolyses, aminolyses, and miscellaneous ionic reactions; micellar effects on organic equilibria and nucleophilic substitution reactions, and on hydrophobic interactions and protein structure; and radical and excited state reactions in micellar systems. The final chapters deal with interactions in and catalysis by micelles in nonaqueous solvents and in liquid crystalline phases; and catalysis in macromolecular and related systems. This book is aimed at the industrial and academic researcher regardless of his arbitrarily defined subfield, be it organic, inorganic, biological, colloid, etc. The treatment provides guidance and stimulus to bioorganic, inorganic, pharmaceutical, colloid, physical, and polymer chemists as well as to those who seek novel and unique catalysts in industrial processes. It can also serve as the basis of a graduate course.
