The Treatment of a Toxic Nitrgenous-containing Organic Compound by Supercritical Water Oxidation and Wet Air Oxidation Processess [sic] PDF Download
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Author: Nur Hezlin Ashraf-Ball
Publisher:
ISBN:
Category :
Languages : en
Pages : 213
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Book Description
![The Treatment of a Toxic Nitrgenous-containing Organic Compound by Supercritical Water Oxidation and Wet Air Oxidation Processess [sic] PDF](https://books.google.com/books/content/images/frontcover/DZQOswEACAAJ?fife=w80-h100)
Author: Nur Hezlin Ashraf-Ball
Publisher:
ISBN:
Category :
Languages : en
Pages : 213
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Author: Oluwaponmile Olumayowa Osibo
Publisher:
ISBN:
Category :
Languages : en
Pages :
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The results of the hydrothermal oxidation of 1,8 diazabicyclo[5.4.0]undec-7-ene (DBU), a toxic nitrogen-containing organic compound by different processes is presented here. Subcritical experiments (wet air oxidation (WAO) and catalytic wet air oxidation(CWAO)), were conducted in a batch reactor and supercritical water oxidation (SCWO) experiments were conducted in a tubular reactor. The key operating parameters investigated were temperature, pressure, initial organic concentration; for catalytic experiments, the effect of catalyst metal loading and weight were also investigated. Commercially available Ru/Al\(_2\)O\(_3\) pellets were selected for catalytic study after various catalysts were screened. Results indicated that temperature was the key operating parameter in all 3 processes that affected DBU removal, TOC removal and ammonia yield. Ru/Al\(_2\)O\(_3\) pellets enhanced the DBU removal, TOC removal and decreased ammonia yield compared to WAO. Complete DBU removal was achieved by catalytic wet air oxidation and supercritical water oxidation. Kinetic data was acquired and a pseudo first order kinetic model was used to quantify the oxidation rate. WAO and CWAO were investigated for the treatment of hazardous industrial effluent with a high initial ammonia concentration and complete ammonia removal was achieved using Ru/Al\(_2\)O\(_3\) pellets. A novel ruthenium coated reticulated foam monolith was investigated as an alternative for heterogeneous catalyst instead of Ru/Al\(_2\)O\(_3\) pellets, the results show that it improved catalyst stability and could be an alternative to pellets for wastewater treatment.
Author: Olcay Tunay
Publisher: IWA Publishing
ISBN: 1843393077
Category : Science
Languages : en
Pages : 361
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Book Description
This book covers the most recent scientific and technological developments (state-of-the-art) in the field of chemical oxidation processes applicable for the efficient treatment of biologically-difficult-to-degrade, toxic and/or recalcitrant effluents originating from different manufacturing processes. It is a comprehensive review of process and pollution profiles as well as conventional, advanced and emerging treatment processes & technologies developed for the most relevant and pollution (wet processing)-intensive industrial sectors. It addresses chemical/photochemical oxidative treatment processes, case-specific treatability problems of major industrial sectors, emerging (novel) as well as pilot/full-scale applications, process integration, treatment system design & sizing criteria (figure-of-merits), cost evaluation and success stories in the application of chemical oxidative treatment processes. Chemical Oxidation Applications for Industrial Wastewaters is an essential reference for lecturers, researchers, industrial and environmental engineers and practitioners working in the field of environmental science and engineering. Visit the IWA WaterWiki to read and share material related to this title: http://www.iwawaterwiki.org/xwiki/bin/view/Articles/CHEMICALOXIDATIONAPPLICATIONSFORINDUSTRIALWASTEWATERS Authors: Professor Olcay Tünay, Professor Isik Kabdasli, Associate Professor Idil Arslan-Alaton and Assistant Professor Tugba Ölmez-Hanci, Environmental Engineering Department, Istanbul Technical University, Turkey.
Author: David Neil Kupferer
Publisher:
ISBN:
Category :
Languages : en
Pages : 57
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Author: Shuzhong Wang
Publisher: Springer Nature
ISBN: 9811393265
Category : Technology & Engineering
Languages : en
Pages : 352
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Book Description
This book systematically presents the technical aspects of supercritical water oxidation and supercritical water gasification for energy and environmental applications, which include reactor design, construction materials, corrosion, salt precipitation, etc. The book provides a comprehensive introduction to the properties of supercritical water, and the industrial applications, reaction mechanisms and reaction kinetics of supercritical water oxidation (SCWO) and supercritical water gasification (SCWG). The reactions occurring in supercritical water are complex, and studying their reaction mechanisms is of great importance for the development of supercritical water processing technologies. Accordingly, the book explains the oxidative mechanisms and kinetics of organic matter in supercritical water in detail. However, the harsh reaction conditions in supercritical water can easily create severe reactor corrosion and salt deposition problems. Therefore, the book also comprehensively reports on the mechanism analysis, state of research, and development trends regarding these two problems. Lastly, the book summarizes the development of supercritical water processing technologies, including studies on SCWO and SCWG, as well as near-zero-emission systems of pollutants based on SCWO technology. In short, the book provides a wealth of valuable information for all readers who are interested in using SCWO for organic waste treatment, and in using SCWG for hydrogen production with wet biomass.
Author: Mauricio Julio Angeles Hernández
Publisher:
ISBN:
Category :
Languages : en
Pages : 294
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Author: Lisete Dos Santos Pinto
Publisher:
ISBN:
Category :
Languages : en
Pages : 224
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Author:
Publisher:
ISBN:
Category :
Languages : en
Pages :
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The results of the catalytic oxidation in supercritical water of two non-biodegradable and highly toxic nitrogen-containing organic compounds (DBU and quinoline) are presented. The reactions were studied in a tubular xed-bed reactor over three catalysts: Pt/Al\(_2\)O\(_3\), CuO/Al \(_2\)O\(_3\) and MnO\(_2\)/CuO. The effect of operating conditions, namely temperature, pressure, oxygen concentration and initial concentration of the organic compounds were studied to evaluate their influence on its removal. Reaction rates were calculated from the experimental data collected. In addition, the selectivities and stabilities of the catalysts were investigated. Before conducting the experimental study the isothermal and isobaric operation of the reactor was veried together with the complete decomposition of hydrogen peroxide to oxygen and water in the preheating section and the reproducibility of experimental data was verified. Absence of external concentration gradients was determined experimentally for each reaction. The results showed that temperature was the main controlling variable of the catalytic oxidation. On the contrary, the effect of pressure depended on the catalyst used. Increasing the concentration of the organic compound did not aect their oxidation. Meanwhile, oxygen concentration above a stoichiometric ratio of two did not considerably improve the reaction. A power-law kinetic model was proposed to quantify the oxidation reaction. Three Langmuir-Hinshelwood-Hougen-Watson reaction rates were also explored to the experimental data. In the absence of a specic reaction mechanism the kinetic data were best represented by the power-law kinetic model. CO2 was the main carbon product of the reaction with small amounts of inorganic carbon species dissolved in the liquid effluent. Meanwhile, NH\(_4\), NO\(_3\) and NO\(_2\) ions were the only nitrogen species detected in the liquid effluent. Pt/Al\(_2\)O\(_3\) proved to be the most effective catalyst because it promo.
Author: Faihan Saleh Alsoqyani
Publisher:
ISBN:
Category :
Languages : en
Pages :
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Book Description
Author: Mihaela I. Stefan
Publisher: IWA Publishing
ISBN: 1780407181
Category : Science
Languages : en
Pages : 712
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Book Description
Advanced Oxidation Processes (AOPs) rely on the efficient generation of reactive radical species and are increasingly attractive options for water remediation from a wide variety of organic micropollutants of human health and/or environmental concern. Advanced Oxidation Processes for Water Treatment covers the key advanced oxidation processes developed for chemical contaminant destruction in polluted water sources, some of which have been implemented successfully at water treatment plants around the world. The book is structured in two sections; the first part is dedicated to the most relevant AOPs, whereas the topics covered in the second section include the photochemistry of chemical contaminants in the aquatic environment, advanced water treatment for water reuse, implementation of advanced treatment processes for drinking water production at a state-of-the art water treatment plant in Europe, advanced treatment of municipal and industrial wastewater, and green technologies for water remediation. The advanced oxidation processes discussed in the book cover the following aspects: - Process principles including the most recent scientific findings and interpretation. - Classes of compounds suitable to AOP treatment and examples of reaction mechanisms. - Chemical and photochemical degradation kinetics and modelling. - Water quality impact on process performance and practical considerations on process parameter selection criteria. - Process limitations and byproduct formation and strategies to mitigate any potential adverse effects on the treated water quality. - AOP equipment design and economics considerations. - Research studies and outcomes. - Case studies relevant to process implementation to water treatment. - Commercial applications. - Future research needs. Advanced Oxidation Processes for Water Treatment presents the most recent scientific and technological achievements in process understanding and implementation, and addresses to anyone interested in water remediation, including water industry professionals, consulting engineers, regulators, academics, students. Editor: Mihaela I. Stefan - Trojan Technologies - Canada
