Author: David Alexander Vaccaro
Publisher:
ISBN:
Category :
Languages : en
Pages : 0
Book Description
Lastly, the ability of the [TismPriBenz]Zn halide series to form ion pair complexes was investigated. [TismPriBenz]ZnI can react with ZnI2 to afford {[TismPriBenz]Zn}2[Zn3I8], which contains the novel zinc halide species [Zn3I8]2−. Additionally, all of the [TismPriBenz]ZnX (X = Cl, Br, I) complexes are able to react with excess ZnX2 in THF to give the series {[TismPriBenz]Zn}[Zn(THF)X3].
The Synthesis and Structural Characterization of Main Group and Lanthanide Metal Compounds Supported by the Multidentate [N3C] Donor Ligand Tris[(1-isopropylbenzimidazol-2-yl)dimethylsilyl]methyl, [TismPriBenz]M
Author: David Alexander Vaccaro
Publisher:
ISBN:
Category :
Languages : en
Pages : 0
Book Description
Lastly, the ability of the [TismPriBenz]Zn halide series to form ion pair complexes was investigated. [TismPriBenz]ZnI can react with ZnI2 to afford {[TismPriBenz]Zn}2[Zn3I8], which contains the novel zinc halide species [Zn3I8]2−. Additionally, all of the [TismPriBenz]ZnX (X = Cl, Br, I) complexes are able to react with excess ZnX2 in THF to give the series {[TismPriBenz]Zn}[Zn(THF)X3].
Publisher:
ISBN:
Category :
Languages : en
Pages : 0
Book Description
Lastly, the ability of the [TismPriBenz]Zn halide series to form ion pair complexes was investigated. [TismPriBenz]ZnI can react with ZnI2 to afford {[TismPriBenz]Zn}2[Zn3I8], which contains the novel zinc halide species [Zn3I8]2−. Additionally, all of the [TismPriBenz]ZnX (X = Cl, Br, I) complexes are able to react with excess ZnX2 in THF to give the series {[TismPriBenz]Zn}[Zn(THF)X3].
The Synthesis and Structural Characterization of Main Group and Transition Metal Complexes Supported by Nitrogen Based Ligands
Author:
Publisher:
ISBN:
Category :
Languages : en
Pages :
Book Description
Nitrogen based monodentate and bidentate chelating ligands have captured a significant interest due to their ability to coordinate to a wide variety of elements. The â-diketimine, â-ketoiminato, formamidine, pyridineselenolate, and pyrazinecarboxamide ligands have all been employed in this study to further investigate the coordination preferences among main group and transition metals. Steric and electronic properties of these ligands can easily be altered by manipulating the substituents attached, thus leading to predictable structures with potential for many useful and significant applications. Investigations have shown that temperature, solvent, and metal halide employed are all key factors in the reaction outcomes. All of the complexes obtained throughout these studies have been characterized by X-ray crystallography along with other spectroscopic techniques, including NMR, IR, UV/Vis, and M/S. â-diketiminato ligands, [{N(R)C(Me)}2C(H)] where R = Dipp, Mes, commonly referred to as nacnac, have played an important role in the synthesis of novel pnictogenium complexes. Results show that through manipulation of the halide precursor, reaction stoichiometry, and the R substituent on the nacnac both N, N'- and N, C'-metal chelated complexes can be achieved. Additionally, â-ketiminato ligands, [RN(H)(C(Me))2C(Me)=O] where R = Dipp, and [RN(H)C(Me)CHC(Me)=O] where R = C2H4NEt2, have been studied. Both ligands were investigated with a range of d and p block metal halides and alkyls in order to compare and contrast the bulky, flexible, and even multi-dentate nature of each ligand. The preferred metal geometry remains constant for products with either ligand, but the steric protection offered by the individual ligands governs the nuclearity of the products, ranging from tetrameric cages to simple adducts. The formamidinate ligand, [RN(H)C(H)NR] where R = Dipp, was employed in synthesizing several aluminum and zinc complexes. In addition to their numerous applications as cata.
Publisher:
ISBN:
Category :
Languages : en
Pages :
Book Description
Nitrogen based monodentate and bidentate chelating ligands have captured a significant interest due to their ability to coordinate to a wide variety of elements. The â-diketimine, â-ketoiminato, formamidine, pyridineselenolate, and pyrazinecarboxamide ligands have all been employed in this study to further investigate the coordination preferences among main group and transition metals. Steric and electronic properties of these ligands can easily be altered by manipulating the substituents attached, thus leading to predictable structures with potential for many useful and significant applications. Investigations have shown that temperature, solvent, and metal halide employed are all key factors in the reaction outcomes. All of the complexes obtained throughout these studies have been characterized by X-ray crystallography along with other spectroscopic techniques, including NMR, IR, UV/Vis, and M/S. â-diketiminato ligands, [{N(R)C(Me)}2C(H)] where R = Dipp, Mes, commonly referred to as nacnac, have played an important role in the synthesis of novel pnictogenium complexes. Results show that through manipulation of the halide precursor, reaction stoichiometry, and the R substituent on the nacnac both N, N'- and N, C'-metal chelated complexes can be achieved. Additionally, â-ketiminato ligands, [RN(H)(C(Me))2C(Me)=O] where R = Dipp, and [RN(H)C(Me)CHC(Me)=O] where R = C2H4NEt2, have been studied. Both ligands were investigated with a range of d and p block metal halides and alkyls in order to compare and contrast the bulky, flexible, and even multi-dentate nature of each ligand. The preferred metal geometry remains constant for products with either ligand, but the steric protection offered by the individual ligands governs the nuclearity of the products, ranging from tetrameric cages to simple adducts. The formamidinate ligand, [RN(H)C(H)NR] where R = Dipp, was employed in synthesizing several aluminum and zinc complexes. In addition to their numerous applications as cata.
Synthesis and Structural Characterization of Main-group Metal Complexes of a Substituted-fulvalene Ligand, 5,14-H-bisindeno [2,3-F, H] Naphthalene
Author: Dennis Malaba
Publisher:
ISBN:
Category : Ligands
Languages : en
Pages : 496
Book Description
Publisher:
ISBN:
Category : Ligands
Languages : en
Pages : 496
Book Description
The Synthesis and Structural Characterization of Some Multiple Donor Ligands and Their Metal Complexes
Author: Steven P. Rowley
Publisher:
ISBN:
Category :
Languages : en
Pages : 558
Book Description
Publisher:
ISBN:
Category :
Languages : en
Pages : 558
Book Description
The Synthesis and Structural Characterisation of the Lanthanide and Transition Metal Coordination Polymers Formed with Novel Multidentate Ligands
Author: D. A. Grachvogel
Publisher:
ISBN:
Category :
Languages : en
Pages :
Book Description
Publisher:
ISBN:
Category :
Languages : en
Pages :
Book Description