The Synthesis and Reactions of Cationic Alkyl Complexes of Group(IV) Transition Metals

The Synthesis and Reactions of Cationic Alkyl Complexes of Group(IV) Transition Metals PDF Author: Andrew James Jaggar
Publisher:
ISBN:
Category :
Languages : en
Pages :

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The Synthesis and Reactions of Cationic Alkyl Complexes of Group(IV) Transition Metals

The Synthesis and Reactions of Cationic Alkyl Complexes of Group(IV) Transition Metals PDF Author: Andrew James Jaggar
Publisher:
ISBN:
Category :
Languages : en
Pages :

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The Synthesis and Reactions of Cationic Organotransition Metal Complexes

The Synthesis and Reactions of Cationic Organotransition Metal Complexes PDF Author: Paul K. Baker
Publisher:
ISBN:
Category :
Languages : en
Pages : 376

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Organometallic Chemistry

Organometallic Chemistry PDF Author: E W Abel
Publisher: Royal Society of Chemistry
ISBN: 1847554105
Category : Science
Languages : en
Pages : 516

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Book Description
Organometallic chemistry is an interdisciplinary science which continues to grow at a rapid pace. Although there is continued interest in synthetic and structural studies the last decade has seen a growing interest in the potential of organometallic chemistry to provide answers to problems in catalysis synthetic organic chemistry and also in the development of new materials. This Specialist Periodical Report aims to reflect these current interests reviewing progress in theoretical organometallic chemistry, main group chemistry, the lanthanides and all aspects of transition metal chemistry. Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued. The current list of Specialist Periodical Reports can be seen on the inside flap of this volume.

Synthesis and Chemistry of Cationic D Sup 0 Metal Alkyl Complexes

Synthesis and Chemistry of Cationic D Sup 0 Metal Alkyl Complexes PDF Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 29

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The objective of this project is to develop new types of electrophilic metal alkyl complexes for catalytic C-H activation and olefin polymerization chemistry, and associated fundamental mechanistic studies. We have focused our efforts on four classes of early metal alkyl complexes: (1) cationic group 4 Cp2M(R) complexes (1) which are active species in Cp2MX2-based Ziegler-Natta olefin polymerization catalyst systems and which catalyze productive C-H activation reactions of heterocycles, (2) neutral (dicarbollide)(Cp*)M(R) complexes (2) which are structurally are electronically very similar to 1, (3) half-sandwich complexes CpM(R)2(L){sub n} which are highly coordinatively and electronically unsaturated, and (4) new group 5 (dicarbollide)(Cp)MR2 and (dicarbollide)2 MR complexes which are more unsaturated than group 5 Cp2M systems due to incorporation of the dicarbollide ligand.

Synthesis and Chemistry of Cationic D° Metal Alkyl Complexes. Progress Report, July 1988--May 1991

Synthesis and Chemistry of Cationic D° Metal Alkyl Complexes. Progress Report, July 1988--May 1991 PDF Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 29

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Book Description
The objective of this project is to develop new types of electrophilic metal alkyl complexes for catalytic C-H activation and olefin polymerization chemistry, and associated fundamental mechanistic studies. We have focused our efforts on four classes of early metal alkyl complexes: (1) cationic group 4 Cp2M(R) complexes (1) which are active species in Cp2MX2-based Ziegler-Natta olefin polymerization catalyst systems and which catalyze productive C-H activation reactions of heterocycles, (2) neutral (dicarbollide)(Cp*)M(R) complexes (2) which are structurally are electronically very similar to 1, (3) half-sandwich complexes CpM(R)2(L){sub n} which are highly coordinatively and electronically unsaturated, and (4) new group 5 (dicarbollide)(Cp)MR2 and (dicarbollide)2 MR complexes which are more unsaturated than group 5 Cp2M systems due to incorporation of the dicarbollide ligand.

Organometallic Chemistry

Organometallic Chemistry PDF Author: Ionel Haiduc
Publisher: Walter de Gruyter GmbH & Co KG
ISBN: 3110695278
Category : Science
Languages : en
Pages : 443

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Book Description
This book provides the reader with a comprehensive introduction to the topic of organometallic chemistry. With an easy to follow structure covering both non-transition metals and transition metals as well as the applications of organometallic reagents in organic synthesis, this book is a must-have for the organometallic chemist. Thematic overview of organometallic compounds of transition and non-transition metals. Covers structures as well as applications.

Transition Metals in the Synthesis of Complex Organic Molecules

Transition Metals in the Synthesis of Complex Organic Molecules PDF Author: Louis S. Hegedus
Publisher:
ISBN:
Category : Science
Languages : en
Pages : 380

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Book Description
A text for use in a one-semester course for upper-level students familiar with basic organic chemistry, or as a survey course for practicing organic chemists. Chapters 1 and 2 present a brief overview of the formalisms and mechanisms required to understand the processes discussed in chapters 3-10, which deal with the application of transition metal organometallic chemistry to organic synthesis with specific attention to applications with complex molecules. Updates and expands chapters 13-20 of Principles and Applications of Organotransition Metal Chemistry, 2nd ed. (1987). Published by University Science Books, 20 Edgehill Rd., Mill Valley, CA 94941. Annotation copyright by Book News, Inc., Portland, OR

Advances in Organometallic Chemistry

Advances in Organometallic Chemistry PDF Author:
Publisher: Academic Press
ISBN: 0128121858
Category : Science
Languages : en
Pages : 268

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Book Description
Advances in Organometallic Chemistry, Volume 68 contains authoritative review articles of worldwide known researchers in the field of organometallic chemistry. This updated volume includes new chapters that cover Water Oxidation at Base Metal Molecular Catalysts, Functionalization Of White and Red Phosphorus in the Coordination Sphere of Transition Metal Complexes, Carbon Dioxide Transition Metal Complexes, Synthesis and Reaction Chemistry of Alkylidene Complexes with Group 4 and 5 Transition Metals: Effective Catalysts for Olefin Metathesis Polymerization and the Other Organic Transformations, and Recent Advances in Heteroatom Stabilized Carbones and Their Metal Complexes. This long-standing serial is known for its comprehensive coverage of topics in organometallic synthesis, reactions, mechanisms, homogeneous catalysis, and more. It is ideal for a wide range of researchers involved in organometallic chemistry, including synthetic protocols, mechanistic studies and practical applications. - Contains contributions from leading authorities in the field of organometallic chemistry - Covers topics in organometallic synthesis, reactions, mechanisms, homogeneous catalysis, and more - Informs and updates readers on all the latest developments in the field - Carefully edited to provide easy-to-read material

Index to Theses with Abstracts Accepted for Higher Degrees by the Universities of Great Britain and Ireland and the Council for National Academic Awards

Index to Theses with Abstracts Accepted for Higher Degrees by the Universities of Great Britain and Ireland and the Council for National Academic Awards PDF Author:
Publisher:
ISBN:
Category : Dissertations, Academic
Languages : en
Pages : 870

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Book Description
Theses on any subject submitted by the academic libraries in the UK and Ireland.

Chemical Transformations of Vinylidenecyclopropanes

Chemical Transformations of Vinylidenecyclopropanes PDF Author: Lixiong Shao
Publisher: Springer Science & Business Media
ISBN: 3642275737
Category : Science
Languages : en
Pages : 73

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Book Description
Modern organic synthesis has paid much attention to the chemistry of small carbocycles. Vinylidenecyclopropanes (VDCPs), which have strained cyclopropyl group connected with an allene moiety and yet are thermally stable and reactive substances in organic chemistry, are versatile intermediates in organic synthesis. In this volume, Dr. Lixiong Shao, Dr. Jianmei Lu and Prof. Dr. Min Shi review their investigations on the chemistry of VDCPs, mainly including the preparation, the reactivities upon treatment with Lewis or Brønsted acid, as well as transition metal catalysts and some other miscellaneous analogues. The contributions aroused a renaissance of cationic intermediates in the chemistry of VDCPs.