The Principles of Ion-selective Electrodes and of Membrane Transport PDF Download
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Author: W. E. Morf
Publisher: Elsevier Science & Technology
ISBN:
Category : Science
Languages : en
Pages : 530
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Book Description
The Principles of Ion-Selective Electrodes and of Membrane Transport ...
Author: W.E. Morf
Publisher: Elsevier
ISBN: 0444597557
Category : Science
Languages : en
Pages : 446
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Book Description
The Principles of Ion Selective Electrodes and of Membrane Transport is a collection of research works on the theory, principles, and fundamentals of ion-selective electrodes and of membrane transport. This book is organized into two parts encompassing 15 chapters that highlight the application of the membrane model. Part A is a general discussion of membrane potentials and membrane transport. This part describes the formulations of the interfacial potential contribution due to phase boundaries. This part also explores the diffusion potential, the nonideality of diffusion layers or membrane phases, the liquid-junction potential arising in conventional potentiometric measuring cells. Other topics covered in this part include the practical solution for the membrane potential; the ion-transport and the electrical properties of bulk membranes; and the characteristics of lipid bilayer membranes. Part B considers the fundamentals of ion-selective electrodes. This part begins with discussions of the principles, response behavior, ion selectivity, and detection limits of solid-state membrane electrodes. This part also examines several important extensions and modifications of the Sandblom-Eisenman-Walker theory; the characteristics of neutral carrier membrane electrodes; and the theory of glass electrodes.
Author: Henry Freiser
Publisher: Springer Science & Business Media
ISBN: 1468425927
Category : Science
Languages : en
Pages : 448
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Book Description
Ion-selective electrodes continue to be one of the more excIting developments in electro analytical chemistry in the last 10 years. This is evidenced in the large and continually growing literature in the field. It is important and necessary in such a rapidly growing area to be able to "take stock," i. e. , to present a well-rounded, up-to-date review of important developments. In this volume, reviews by many of the leading practitioners and pioneers in this field contribute to what we consider to be a generous coverage of both fundamental aspects of ion-selective electrodes and their applications to analytical chemistry. Although this volume is not intended to be exhaustive, we have attempted to produce a "stand alone" text dealing with all major current developments. Indeed, since some of the theoretical approaches are not yet universally agreed on, each of the first five chapters deals with theory and principles of the nature and behavior of ion-selective electrodes from the vantage point of the authors' own experience and understanding. In view of the rapid expansion of this field, plans for future volumes are now being formulated. Henry Freiser Tucson, Arizona vii Contents Chapter 1 Theory and Principles of Membrane Electrodes R. P. Buck 1. Potential Generating Processes . . . . . . . . . . . . . . . . 1 1. 1. Interfaces, Fixed Charges, Charged Sites, and Charge Carriers 1 1. 2. Ion Exchange as a Potential-Generating Process 5 1. 3. Diffusion and Migration . . . . . . . . . . . . 8 1. 4. Electrochemical Potentials, Fluxes, and Mobility . . 10 1. 5.
Author: N Lakshminarayanaiah
Publisher: Elsevier
ISBN: 0323153291
Category : Science
Languages : en
Pages : 379
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Book Description
Membrane Electrodes considers the significant developments in the field of sensing probes, with an emphasis on membrane electrodes. This book is organized into three parts encompassing 11 chapters. Part I is an introduction to the variety of ion-selective membrane electrodes that have been constructed and with which experiments have been conducted. This part deals first with the thermodynamic principles and other concepts underlying the description of the behavior of electrolyte solutions, followed by a discussion on the various theories of membrane potential applicable to a variety of solid and liquid membrane electrodes. Part II describes the preparation, properties, and uses of the various solid and liquid membrane electrodes. Part III presents glass membrane electrodes as a prelude to the description of other membrane systems in which glass electrodes are invariably used as the primary sensing device. This book will prove useful to students, technologists, and researchers in various fields of science and technology.
Author: Henry Freiser
Publisher: Springer
ISBN: 9780306339073
Category : Science
Languages : en
Pages : 454
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Book Description
Ion-selective electrodes continue to be one of the more excIting developments in electro analytical chemistry in the last 10 years. This is evidenced in the large and continually growing literature in the field. It is important and necessary in such a rapidly growing area to be able to "take stock," i. e. , to present a well-rounded, up-to-date review of important developments. In this volume, reviews by many of the leading practitioners and pioneers in this field contribute to what we consider to be a generous coverage of both fundamental aspects of ion-selective electrodes and their applications to analytical chemistry. Although this volume is not intended to be exhaustive, we have attempted to produce a "stand alone" text dealing with all major current developments. Indeed, since some of the theoretical approaches are not yet universally agreed on, each of the first five chapters deals with theory and principles of the nature and behavior of ion-selective electrodes from the vantage point of the authors' own experience and understanding. In view of the rapid expansion of this field, plans for future volumes are now being formulated. Henry Freiser Tucson, Arizona vii Contents Chapter 1 Theory and Principles of Membrane Electrodes R. P. Buck 1. Potential Generating Processes . . . . . . . . . . . . . . . . 1 1. 1. Interfaces, Fixed Charges, Charged Sites, and Charge Carriers 1 1. 2. Ion Exchange as a Potential-Generating Process 5 1. 3. Diffusion and Migration . . . . . . . . . . . . 8 1. 4. Electrochemical Potentials, Fluxes, and Mobility . . 10 1. 5.
Author: Erno Lindner
Publisher: CRC Press
ISBN: 1351079980
Category : Science
Languages : en
Pages : 146
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Book Description
The present book deals with the principle of the aforementioned techniques and discusses the information they provide for electrode kinetics. Special attention is paid to the activity step method, since this technique is carried out under zero current potentiometric conditions and allows the study of the processes at the perturbed membrane-solution interface.
Author: Daniel Ammann
Publisher: Springer
ISBN:
Category : Electrochemical analysis
Languages : en
Pages : 372
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Book Description
Author: Konstantin N. Mikhelson
Publisher: Springer
ISBN: 9783642368875
Category : Science
Languages : en
Pages : 162
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Book Description
Ion-selective electrodes (ISEs) have a wide range of applications in clinical, environmental, food and pharmaceutical analysis as well as further uses in chemistry and life sciences. Based on his profound experience as a researcher in ISEs and a course instructor, the author summarizes current knowledge for advanced teaching and training purposes with a particular focus on ionophore-based ISEs. Coverage includes the basics of measuring with ISEs, essential membrane potential theory and a comprehensive overview of the various classes of ion-selective electrodes. The principles of constructing ISEs are outlined, and the transfer of methods into routine analysis is considered. Advanced students, researchers, and practitioners will benefit from this expedient introduction.
Author: James R. Sandifer
Publisher: VCH Publishers
ISBN:
Category : Science
Languages : en
Pages : 160
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Book Description
Chemists in disciplines ranging from solid-state physics to electrochemistry and biology explain the role of ion-transfer kinetics in their particular field and in applications to energy conservation, biosensing, photography, medicine, and a wide range of other areas. Includes detailed enough instruction in the experimental methodology that the reader should be able to test the principles experimentally, and even to write computer programs to simulate ion-transfer properties of hypothetical materials incorporated into equally hypothetical products, presumably for hypothetical customers. Annotation copyright by Book News, Inc., Portland, OR
Author: Joseph Wang
Publisher: John Wiley & Sons
ISBN: 0471460796
Category : Science
Languages : en
Pages : 228
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Book Description
The critically acclaimed guide to the principles, techniques, and instruments of electroanalytical chemistry-now expanded and revised Joseph Wang, internationally renowned authority on electroanalytical techniques, thoroughly revises his acclaimed book to reflect the rapid growth the field has experienced in recent years. He substantially expands the theoretical discussion while providing comprehensive coverage of the latest advances through late 1999, introducing such exciting new topics as self-assembled monolayers, DNA biosensors, lab-on-a-chip, detection for capillary electrophoresis, single molecule detection, and sol-gel surface modification. Along with numerous references from the current literature and new worked-out examples, Analytical Electrochemistry, Second Edition offers clear, reader-friendly explanations of the fundamental principles of electrochemical processes as well as important insight into the potential of electroanalysis for problem solving in a wide range of fields, from clinical diagnostics to environmental science. Key topics include: The basics of electrode reactions and the structure of the interfacial region Tools for elucidating electrode reactions and high-resolution surface characterization An overview of finite-current controlled potential techniques Electrochemical instrumentation and electrode materials Principles of potentiometric measurements and ion-selective electrodes Chemical sensors, including biosensors, gas sensors, solid-state devices, and sensor arrays
Author: K. Cammann
Publisher: Springer Science & Business Media
ISBN: 3642672760
Category : Science
Languages : en
Pages : 239
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Book Description
The first section introduces the electrochemical nomenclature necessary for under standing the literature on ion-selective electrodes and discusses the general principles behind all electrodes. The second section is concerned with the problems which arise in any accurate elec trode potential measurement in practice. Here the most important reference electrodes are discussed with special reference to their use in conjunction with ion-selective elec trodes. From experience, almost 75% of all problems which arise when working with ion-selective electrodes are on account of the reference electrode. After the reader is aquainted with the basic problems involved, the third section deals with individual ion-selective electrodes; their properties, handling and methods of pre paration. Here the discussion of these electrodes is not arranged according to the spe cies detected, but rather according to the kind of construction, since from this view point characteristic properties are much the same and handling procedures need only be described once for an entire series of similar electrodes. The fourth section discusses amplifiers. Here the problems of high-ohmic EMF meas urements such as noise level, insulation, static charging and ground loops are discussed. The fifth section is devoted to the various evaluation methods. Here a few schemes and examples are provided to indicate optimum practical procedures and the accura cies attainable with the various methods are discussed. The last section describes special set-ups such as clinical flow-thru cells, microelec trodes for measuring intracellular ionic activities, industrial on-line techniques and continuous environmental protection monitors.
