The Molecule-Metal Interface

The Molecule-Metal Interface PDF Author: Norbert Koch
Publisher: John Wiley & Sons
ISBN: 3527653198
Category : Science
Languages : en
Pages : 257

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Book Description
Reviewing recent progress in the fundamental understanding of the molecule-metal interface, this useful addition to the literature focuses on experimental studies and introduces the latest analytical techniques as applied to this interface. The first part covers basic theory and initial principle studies, while the second part introduces readers to photoemission, STM, and synchrotron techniques to examine the atomic structure of the interfaces. The third part presents photoelectron spectroscopy, high-resolution UV photoelectron spectroscopy and electron spin resonance to study the electronic structure of the molecule-metal interface. In the closing chapter the editors discuss future perspectives. Written as a senior graduate or senior undergraduate textbook for students in physics, chemistry, materials science or engineering, the book's interdisciplinary approach makes it equally relevant for researchers working in the field of organic and molecular electronics.

The Molecule-Metal Interface

The Molecule-Metal Interface PDF Author: Norbert Koch
Publisher: John Wiley & Sons
ISBN: 3527653198
Category : Science
Languages : en
Pages : 257

Get Book Here

Book Description
Reviewing recent progress in the fundamental understanding of the molecule-metal interface, this useful addition to the literature focuses on experimental studies and introduces the latest analytical techniques as applied to this interface. The first part covers basic theory and initial principle studies, while the second part introduces readers to photoemission, STM, and synchrotron techniques to examine the atomic structure of the interfaces. The third part presents photoelectron spectroscopy, high-resolution UV photoelectron spectroscopy and electron spin resonance to study the electronic structure of the molecule-metal interface. In the closing chapter the editors discuss future perspectives. Written as a senior graduate or senior undergraduate textbook for students in physics, chemistry, materials science or engineering, the book's interdisciplinary approach makes it equally relevant for researchers working in the field of organic and molecular electronics.

Design and Control of Highly Conductive Single-Molecule Junctions

Design and Control of Highly Conductive Single-Molecule Junctions PDF Author: Satoshi Kaneko
Publisher: Springer
ISBN: 9811044120
Category : Science
Languages : en
Pages : 92

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Book Description
This thesis describes improvements to and control of the electrical conductance in single-molecule junctions (SMJs), which have potential applications in molecular electronics, with a focus on the bonding between the metal and molecule. In order to improve the electrical conductance, the π orbital of the molecule is directly bonded to the metal orbital, because anchoring groups, which were typically used in other studies to bind molecule with metal electrodes, became resistive spacers. Using this direct π-binding, the author has successfully demonstrated highly conductive SMJs involving benzene, endohedral metallofullerene Ce@C82, and nitrogen. Subsequently, the author investigated control of the electrical conductance of SMJs using pyrazine. The nitrogen atom in the π-conjugated system of pyrazine was expected to function as an anchoring point, and two bonding states were expected. One originates primarily from the π orbital, while the other originates primarily from an n state of the nitrogen. Measurements of conductance and dI/dV spectra coupled with theoretical calculations revealed that the pyrazine SMJ has bistable conductance states, in which the pyrazine axis is either tilted or parallel with respect to the junction axis. The bistable states were switched by changing the gap size between the metal electrodes using an external force. Notably, it is difficult to change the electrical properties of bulk-state materials using mechanical force. The findings reveal that the electron transport properties of a SMJ can be controlled by designing a proper metal–molecule interface, which has considerable potential for molecular electronics. Moreover, this thesis will serve as a guideline for every step of SMJ research: design, fabrication, evaluation, and control.

Chemical Bonding at Surfaces and Interfaces

Chemical Bonding at Surfaces and Interfaces PDF Author: Anders Nilsson
Publisher: Elsevier
ISBN: 0080551912
Category : Science
Languages : en
Pages : 533

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Book Description
Molecular surface science has made enormous progress in the past 30 years. The development can be characterized by a revolution in fundamental knowledge obtained from simple model systems and by an explosion in the number of experimental techniques. The last 10 years has seen an equally rapid development of quantum mechanical modeling of surface processes using Density Functional Theory (DFT). Chemical Bonding at Surfaces and Interfaces focuses on phenomena and concepts rather than on experimental or theoretical techniques. The aim is to provide the common basis for describing the interaction of atoms and molecules with surfaces and this to be used very broadly in science and technology. The book begins with an overview of structural information on surface adsorbates and discusses the structure of a number of important chemisorption systems. Chapter 2 describes in detail the chemical bond between atoms or molecules and a metal surface in the observed surface structures. A detailed description of experimental information on the dynamics of bond-formation and bond-breaking at surfaces make up Chapter 3. Followed by an in-depth analysis of aspects of heterogeneous catalysis based on the d-band model. In Chapter 5 adsorption and chemistry on the enormously important Si and Ge semiconductor surfaces are covered. In the remaining two Chapters the book moves on from solid-gas interfaces and looks at solid-liquid interface processes. In the final chapter an overview is given of the environmentally important chemical processes occurring on mineral and oxide surfaces in contact with water and electrolytes. - Gives examples of how modern theoretical DFT techniques can be used to design heterogeneous catalysts - This book suits the rapid introduction of methods and concepts from surface science into a broad range of scientific disciplines where the interaction between a solid and the surrounding gas or liquid phase is an essential component - Shows how insight into chemical bonding at surfaces can be applied to a range of scientific problems in heterogeneous catalysis, electrochemistry, environmental science and semiconductor processing - Provides both the fundamental perspective and an overview of chemical bonding in terms of structure, electronic structure and dynamics of bond rearrangements at surfaces

Physics of Surfaces and Interfaces

Physics of Surfaces and Interfaces PDF Author: Harald Ibach
Publisher: Springer Science & Business Media
ISBN: 3540347100
Category : Science
Languages : en
Pages : 653

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Book Description
This graduate-level textbook covers the major developments in surface sciences of recent decades, from experimental tricks and basic techniques to the latest experimental methods and theoretical understanding. It is unique in its attempt to treat the physics of surfaces, thin films and interfaces, surface chemistry, thermodynamics, statistical physics and the physics of the solid/electrolyte interface in an integral manner, rather than in separate compartments. It is designed as a handbook for the researcher as well as a study-text for graduate students. Written explanations are supported by 350 graphs and illustrations.

Noble Metals

Noble Metals PDF Author: Yen-Hsun Su
Publisher: BoD – Books on Demand
ISBN: 9533078987
Category : Technology & Engineering
Languages : en
Pages : 430

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Book Description
This book provides a broad spectrum of insights into the optical principle, resource, fabrication, nanoscience, and nanotechnology of noble metal. It also looks at the advanced implementation of noble metal in the field of nanoscale materials, catalysts and biosystem. This book is ideal not only for scientific researchers but also as a reference for professionals in material science, engineering, nonascience and plasmonics.

Light Scattering in Solids

Light Scattering in Solids PDF Author: J. L. Birman
Publisher: Springer Science & Business Media
ISBN: 1461573505
Category : Science
Languages : en
Pages : 525

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Book Description
The Second USA-USSR Symposium on Light Scattering in Con densed Matter was held in New York City 21-25 May 1979. The present volume is the proceedings of that conference, and contains all manuscripts received prior to 1 August 1979, representing scientific contributions presented. A few manus cripts were not received, but for completeness the corresponding abstract is printed. No record was kept of the discussion, so that some of the flavor of the meeting is missing. This is par ticularly unfortunate in the case of some topics which were in a stage of rapid development and where the papers presented sti mulated much discussion - such as the sessions on spatial dis persion and resonance inelastic (Brillouin or Raman) scattering in crystals, enhanced Raman scattering from molecules on metal surfaces, and the onset of turbulence in fluids. The background and history of the US-USSR Seminar-Symposia on light scattering was given in the preface to the proceedings of the First Symposium held in Moscow May 1975, published as "Theory of Light Scattering in Condensed Matter" ed. B. Bendow, J. L. Birman, V. M. Agranovich (Plenum Press, N. Y. 1976). Strong scientific interest on both sides in continuing this series resulted in a plan for the second symposium to be held in New York in 1977. For a variety of reasons it was necessary to cancel the planned 1977 event, almost at the last minute.

Compendium of Surface and Interface Analysis

Compendium of Surface and Interface Analysis PDF Author: The Surface Science Society of Japan
Publisher: Springer
ISBN: 9811061564
Category : Technology & Engineering
Languages : en
Pages : 807

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Book Description
This book concisely illustrates the techniques of major surface analysis and their applications to a few key examples. Surfaces play crucial roles in various interfacial processes, and their electronic/geometric structures rule the physical/chemical properties. In the last several decades, various techniques for surface analysis have been developed in conjunction with advances in optics, electronics, and quantum beams. This book provides a useful resource for a wide range of scientists and engineers from students to professionals in understanding the main points of each technique, such as principles, capabilities and requirements, at a glance. It is a contemporary encyclopedia for selecting the appropriate method depending on the reader's purpose.

Wspc Reference On Organic Electronics, The: Organic Semiconductors (In 2 Volumes)

Wspc Reference On Organic Electronics, The: Organic Semiconductors (In 2 Volumes) PDF Author: Seth R Marder
Publisher: World Scientific
ISBN: 9814699241
Category : Science
Languages : en
Pages : 896

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Book Description
This 2-volume set provides the reader with a basic understanding of the foundational concepts pertaining to the design, synthesis, and applications of conjugated organic materials used as organic semiconductors, in areas including organic photovoltaic devices, light-emitting diodes, field-effect transistors, spintronics, actuation, bioelectronics, thermoelectrics, and nonlinear optics.While there are many monographs in these various areas, the emphasis here is both on the fundamental chemistry and physics concepts underlying the field of organic semiconductors and on how these concepts drive a broad range of applications. This makes the volumes ideal introductory textbooks in the subject. They will thus offer great value to both junior and senior scientists working in areas ranging from organic chemistry to condensed matter physics and materials science and engineering.Number of Illustrations and Tables: 168 b/w illus., 242 colour illus., 13 tables.

Electronic Processes in Organic Electronics

Electronic Processes in Organic Electronics PDF Author: Hisao Ishii
Publisher: Springer
ISBN: 4431552065
Category : Science
Languages : en
Pages : 427

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Book Description
The book covers a variety of studies of organic semiconductors, from fundamental electronic states to device applications, including theoretical studies. Furthermore, innovative experimental techniques, e.g., ultrahigh sensitivity photoelectron spectroscopy, photoelectron yield spectroscopy, spin-resolved scanning tunneling microscopy (STM), and a material processing method with optical-vortex and polarization-vortex lasers, are introduced. As this book is intended to serve as a textbook for a graduate level course or as reference material for researchers in organic electronics and nanoscience from electronic states, fundamental science that is necessary to understand the research is described. It does not duplicate the books already written on organic electronics, but focuses mainly on electronic properties that arise from the nature of organic semiconductors (molecular solids). The new experimental methods introduced in this book are applicable to various materials (e.g., metals, inorganic and organic materials). Thus the book is also useful for experts working in physics, chemistry, and related engineering and industrial fields.

Handbook of Single-Molecule Electronics

Handbook of Single-Molecule Electronics PDF Author: Kasper Moth-Poulsen
Publisher: CRC Press
ISBN: 9814463396
Category : Science
Languages : en
Pages : 439

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Book Description
Single-molecule electronics has evolved as a vibrant research field during the last two decades. The vision is to be able to create electronic components at the highest level of miniaturization-the single molecule. This book compiles and details cutting-edge research with contributions from chemists, physicists, theoreticians, and engineers. It cov