The Chemistry of Mononuclear and Polynuclear Ruthenium Carbonyl Complexes Containing Nitrene and Related Ligands PDF Download
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Author: 李家康
Publisher: Open Dissertation Press
ISBN: 9781374698192
Category :
Languages : en
Pages :
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Book Description
This dissertation, "The Chemistry of Mononuclear and Polynuclear Ruthenium Carbonyl Complexes Containing Nitrene and Related Ligands" by 李家康, Ka-hong, Lee, was obtained from The University of Hong Kong (Pokfulam, Hong Kong) and is being sold pursuant to Creative Commons: Attribution 3.0 Hong Kong License. The content of this dissertation has not been altered in any way. We have altered the formatting in order to facilitate the ease of printing and reading of the dissertation. All rights not granted by the above license are retained by the author. DOI: 10.5353/th_b4257468 Subjects: Ruthenium compounds - Analysis Carbonyl compounds - Analysis Nitrenes Ligands
Author: 李家康
Publisher: Open Dissertation Press
ISBN: 9781374698192
Category :
Languages : en
Pages :
Get Book Here
Book Description
This dissertation, "The Chemistry of Mononuclear and Polynuclear Ruthenium Carbonyl Complexes Containing Nitrene and Related Ligands" by 李家康, Ka-hong, Lee, was obtained from The University of Hong Kong (Pokfulam, Hong Kong) and is being sold pursuant to Creative Commons: Attribution 3.0 Hong Kong License. The content of this dissertation has not been altered in any way. We have altered the formatting in order to facilitate the ease of printing and reading of the dissertation. All rights not granted by the above license are retained by the author. DOI: 10.5353/th_b4257468 Subjects: Ruthenium compounds - Analysis Carbonyl compounds - Analysis Nitrenes Ligands
Author: Ka-hong Lee
Publisher:
ISBN:
Category : Carbonyl compounds
Languages : en
Pages : 642
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Book Description
Author: 何毅雯
Publisher: Open Dissertation Press
ISBN: 9781374791152
Category : Science
Languages : en
Pages : 298
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Book Description
This dissertation, "The Chemistry of Ruthenium Carbonyl Clusters Containing Nitrene and Nitrido Ligands" by 何毅雯, Ngai-man, Emmie, Ho, was obtained from The University of Hong Kong (Pokfulam, Hong Kong) and is being sold pursuant to Creative Commons: Attribution 3.0 Hong Kong License. The content of this dissertation has not been altered in any way. We have altered the formatting in order to facilitate the ease of printing and reading of the dissertation. All rights not granted by the above license are retained by the author. DOI: 10.5353/th_b3124029 Subjects: Ruthenium compounds Metal carbonyls Nitrenes Ligands Transition metal complexes
Author: Ngai-man Ho (Emmie)
Publisher:
ISBN:
Category : Ligands
Languages : en
Pages : 562
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Book Description
Author: 劉思慧
Publisher: Open Dissertation Press
ISBN: 9781374781566
Category : Science
Languages : en
Pages : 260
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Book Description
This dissertation, "The Chemistry of Polynuclear Ruthenium Carbonyl Clusters Containing Functionalised Alkyne Ligands" by 劉思慧, Sze-wai, Cindy, Lau, was obtained from The University of Hong Kong (Pokfulam, Hong Kong) and is being sold pursuant to Creative Commons: Attribution 3.0 Hong Kong License. The content of this dissertation has not been altered in any way. We have altered the formatting in order to facilitate the ease of printing and reading of the dissertation. All rights not granted by the above license are retained by the author. DOI: 10.5353/th_b3123878 Subjects: Ruthenium compounds - Synthesis Carbonyl compounds - Synthesis Ligands
Author: Sze-wai Lau (Cindy)
Publisher:
ISBN:
Category : Carbonyl compounds
Languages : en
Pages : 486
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Book Description
Author: Stanley E. Livingstone
Publisher: Elsevier
ISBN: 1483158403
Category : Science
Languages : en
Pages : 225
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Book Description
The Chemistry of Ruthenium, Rhodium, Palladium, Osmium, Iridium and Platinum
Author: Ajay Kumar Mishra
Publisher: CRC Press
ISBN: 1351616501
Category : Science
Languages : en
Pages : 386
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Book Description
This book will describe Ruthenium complexes as chemotherapeutic agent specifically at tumor site. It has been the most challenging task in the area of cancer therapy. Nanoparticles are now emerging as the most effective alternative to traditional chemotherapeutic approach. Nanoparticles have been shown to be useful in this respect. However, in view of organ system complicacies, instead of using nanoparticles as a delivery tool, it will be more appropriate to synthesize a drug of nanoparticle size that can use blood transport mechanism to reach the tumor site and regress cancer. Due to less toxicity and effective bio-distribution, ruthenium (Ru) complexes are of much current interest. Additionally, lumiscent Ru-complexes can be synthesized in nanoparticle size and can be directly traced at tissue level. The book will contain the synthesis, characterization, and applications of various Ruthenium complexes as chemotherapeutic agents. The book will also cover the introduction to chemotherapy, classification of Ru- complexes with respect to their oxidation states and geometry, Ruthenium complexes of nano size: shape and binding- selectivity, binding of ruthenium complexes with DNA, DNA cleavage studies and cytotoxicity. The present book will be more beneficial to researchers, scientists and biomedical. Current book will empower specially to younger generation to create a new world of ruthenium chemistry in material science as well as in medicines. This book will be also beneficial to national/international research laboratories, and academia with interest in the area of coordination chemistry more especially to the Ruthenium compounds and its applications.
Author: Xavier Sala Román
Publisher:
ISBN:
Category :
Languages : en
Pages : 0
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Book Description
Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 417
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Book Description
The products and mechanisms of the thermal reactions of several complexes of the general structure (PMe3)4Ru(X)(Y) and (DMPM)2Ru(X)(Y) where X and Y are hydride, aryl, and benzyl groups, have been investigated. The mechanism of decomposition depends critically on the structure of the complex and the medium in which the thermolysis is carried out. The alkyl hydride complexes are do not react with alkane solvent, but undergo C-H activation processes with aromatic solvents by several different mechanisms. Thermolysis of (PMe3)4Ru(Ph)(Me) or (PMe3)4Ru(Ph)2 leads to the ruthenium benzyne complex (PMe3)4Ru([eta]2-C6H4) (1) by a mechanism which involves reversible dissociation of phosphine. In many ways its chemistry is analogous to that of early rather than late organo transition metal complexes. The synthesis, structure, variable temperature NMR spectroscopy and reactivity of ruthenium complexes containing aryloxide or arylamide ligands are reported. These complexes undergo cleavage of a P-C bond in coordinated trimethylphosphine, insertion of CO and CO2 and hydrogenolysis. Mechanistic studies on these reactions are described. The generation of a series of reactive ruthenium complexes of the general formula (PMe3)4Ru(R)(enolate) is reported. Most of these enolates have been shown to bind to the ruthenium center through the oxygen atom. Two of the enolate complexes 8 and 9 exist in equilibrium between the O- and C-bound forms. The reactions of these compounds are reported, including reactions to form oxygen-containing metallacycles. The structure and reactivity of these ruthenium metallacycles is reported, including their thermal chemistry and reactivity toward protic acids, electrophiles, carbon monoxide, hydrogen and trimethylsilane. 243 refs., 10 tabs.
