Synthesis of ZnO, CuO and Their Composite Nanostructures for Optoelectronics, Sensing and Catalytic Applications

Synthesis of ZnO, CuO and Their Composite Nanostructures for Optoelectronics, Sensing and Catalytic Applications PDF Author: Saima Zaman
Publisher:
ISBN: 9789175198187
Category :
Languages : en
Pages : 59

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Book Description
Research on nanomaterials has become increasingly popular because of their unique physical, chemical, optical and catalytic properties compared to their bulk counterparts. Therefore, many efforts have been made to synthesize multidimensional nanostructures for new and efficient nanodevices. Among those materials, zinc oxide (ZnO), has gained substantial attention owing to many outstanding properties. ZnO besides its wide bandgap of 3.34 eV exhibits a relatively large exciton binding energy (60 meV) at room temperature which is attractive for optoelectronic applications. Likewise, cupric oxide (CuO), having a narrow band gap of 1.2 eV and a variety of chemo-physical properties that are attractive in many fields. Moreover, composite nanostructures of these two oxides (CuO/ZnO) may pave the way for various new applications.??This thesis can be divided into three parts concerning the synthesis, characterization and applications of ZnO, CuO and their composite nanostructures.??In the first part the synthesis, characterization and the fabrication of ZnO nanorods based hybrid light emitting diodes (LEDs) are discussed. The low temperature chemical growth method was used to synthesize ZnO nanorods on different substrates, specifically on flexible non-crystalline substrates. Hybrid LEDs based on ZnO nanorods combined with p-type polymers were fabricated at low temperature to examine the advantage of both materials. A single and blended light emissive polymers layer was studied for controlling the quality of the emitted white light.??The second part deals with the synthesis of CuO nanostructures (NSs) which were then used to fabricate pH sensors and exploit these NSs as a catalyst for degradation of organic dyes. The fabricated pH sensor exhibited a linear response and good potential stability. Furthermore, the catalytic properties of petals and flowers like CuO NSs in the degradation of organic dyes were studied. The results showed that the catalytic reactivity of the CuO is strongly depending on its shape.??In the third part, an attempt to combine the advantages of both ZnO and CuO NSs was performed by developing a two-step chemical growth method to synthesize the composite NSs. The synthesized CuO/ZnO composite NSs revealed an extended light absorption and enhanced defect related visible emission.

Synthesis of ZnO, CuO and Their Composite Nanostructures for Optoelectronics, Sensing and Catalytic Applications

Synthesis of ZnO, CuO and Their Composite Nanostructures for Optoelectronics, Sensing and Catalytic Applications PDF Author: Saima Zaman
Publisher:
ISBN: 9789175198187
Category :
Languages : en
Pages : 59

Get Book Here

Book Description
Research on nanomaterials has become increasingly popular because of their unique physical, chemical, optical and catalytic properties compared to their bulk counterparts. Therefore, many efforts have been made to synthesize multidimensional nanostructures for new and efficient nanodevices. Among those materials, zinc oxide (ZnO), has gained substantial attention owing to many outstanding properties. ZnO besides its wide bandgap of 3.34 eV exhibits a relatively large exciton binding energy (60 meV) at room temperature which is attractive for optoelectronic applications. Likewise, cupric oxide (CuO), having a narrow band gap of 1.2 eV and a variety of chemo-physical properties that are attractive in many fields. Moreover, composite nanostructures of these two oxides (CuO/ZnO) may pave the way for various new applications.??This thesis can be divided into three parts concerning the synthesis, characterization and applications of ZnO, CuO and their composite nanostructures.??In the first part the synthesis, characterization and the fabrication of ZnO nanorods based hybrid light emitting diodes (LEDs) are discussed. The low temperature chemical growth method was used to synthesize ZnO nanorods on different substrates, specifically on flexible non-crystalline substrates. Hybrid LEDs based on ZnO nanorods combined with p-type polymers were fabricated at low temperature to examine the advantage of both materials. A single and blended light emissive polymers layer was studied for controlling the quality of the emitted white light.??The second part deals with the synthesis of CuO nanostructures (NSs) which were then used to fabricate pH sensors and exploit these NSs as a catalyst for degradation of organic dyes. The fabricated pH sensor exhibited a linear response and good potential stability. Furthermore, the catalytic properties of petals and flowers like CuO NSs in the degradation of organic dyes were studied. The results showed that the catalytic reactivity of the CuO is strongly depending on its shape.??In the third part, an attempt to combine the advantages of both ZnO and CuO NSs was performed by developing a two-step chemical growth method to synthesize the composite NSs. The synthesized CuO/ZnO composite NSs revealed an extended light absorption and enhanced defect related visible emission.

Nanostructured Zinc Oxide

Nanostructured Zinc Oxide PDF Author: Kamlendra Awasthi
Publisher: Elsevier
ISBN: 0128189010
Category : Technology & Engineering
Languages : en
Pages : 781

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Book Description
Nanostructured Zinc Oxide covers the various routes for the synthesis of different types of nanostructured zinc oxide including; 1D (nanorods, nanowires etc.), 2D and 3D (nanosheets, nanoparticles, nanospheres etc.). This comprehensive overview provides readers with a clear understanding of the various parameters controlling morphologies. The book also reviews key properties of ZnO including optical, electronic, thermal, piezoelectric and surface properties and techniques in order to tailor key properties. There is a large emphasis in the book on ZnO nanostructures and their role in optoelectronics. ZnO is very interesting and widely investigated material for a number of applications. This book presents up-to-date information about the ZnO nanostructures-based applications such as gas sensing, pH sensing, photocatalysis, antibacterial activity, drug delivery, and electrodes for optoelectronics. Reviews methods to synthesize, tailor, and characterize 1D, 2D, and 3D zinc oxide nanostructured materials Discusses key properties of zinc oxide nanostructured materials including optical, electronic, thermal, piezoelectric, and surface properties Addresses most relevant zinc oxide applications in optoelectronics such as light-emitting diodes, solar cells, and sensors

Metal Oxide Nanostructures

Metal Oxide Nanostructures PDF Author: Daniela Nunes
Publisher: Elsevier
ISBN: 012811505X
Category : Technology & Engineering
Languages : en
Pages : 328

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Book Description
Metal Oxide Nanostructures: Synthesis, Properties and Applications covers the theoretical and experimental aspects related to design, synthesis, fabrication, processing, structural, morphological, optical and electronic properties on the topic. In addition, it reviews surface functionalization and hybrid materials, focusing on the advantages of these oxide nanostructures. The book concludes with the current and future prospective applications of these materials. Users will find a complete overview of all the important topics related to oxide nanostructures, from the physics of the materials, to its application. Delves into hybrid structured metal oxides and their promising use in the next generation of electronic devices Includes fundamental chapters on synthesis design and the properties of metal oxide nanostructures Provides an in-depth overview of novel applications, including chromogenics, electronics and energy

Zinc Oxide Nanostructures: Synthesis and Characterization

Zinc Oxide Nanostructures: Synthesis and Characterization PDF Author: Sotirios Baskoutas
Publisher: MDPI
ISBN: 3038973025
Category : Electronic books
Languages : en
Pages : 303

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Book Description
This book is a printed edition of the Special Issue "Zinc Oxide Nanostructures: Synthesis and Characterization" that was published in Materials

Photocatalytic Activity of Hydrothermally Synthesized ZnO-CuO Nanocomposite

Photocatalytic Activity of Hydrothermally Synthesized ZnO-CuO Nanocomposite PDF Author: Mohammad Fuad Nur Taufique
Publisher:
ISBN:
Category : Copper oxide semiconductors
Languages : en
Pages : 106

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Book Description
Zinc oxide and copper oxide semiconductor nanostructures have tremendous potential in optoelectronic applications and energy technology. ZnO-CuO nanocomposite have been synthesized by energy efficient hydrothermal method from single stock solution. Structural properties of the nanocomposite samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and Raman spectroscopy. Optical properties were studied by photoluminescence (PL) spectroscopy. Rietveld analysis of the XRD data and SEM data confirmed the nanocomposite of ZnO-CuO with different ratios of ZnO and CuO. Raman spectra of the nanocomposites consist of optical vibrational mode of ZnO and CuO. The unique photoluminescence spectra have characteristic peaks in the visible range which confirmed that the nanocomposite can absorb better in the solar visible region. Further, synthesized samples were used for degradation of methylene blue dye under illumination of UV-Vis light to check the photocatalytic activity. Some nanocomposite samples have shown photocatalytic efficiency of 56% under the illumination of UV-Vis light. The efficiency of the catalyst, their growth mechanism, and the photocatalytic mechanism have been discussed in details. These ZnO-CuO nanocomposites can be used as effective photocatalytic material for waste water decontamination as well as hydrogen generation for energy applications.

Metal Oxides for Optoelectronics and Optics-Based Medical Applications

Metal Oxides for Optoelectronics and Optics-Based Medical Applications PDF Author: Suresh Sagadevan
Publisher: Elsevier
ISBN: 0323858252
Category : Technology & Engineering
Languages : en
Pages : 464

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Book Description
Metal Oxides for Optoelectronics and Optics-based Medical Applications reviews recent advances in metal oxides and their mechanisms for optoelectronic, photoluminescent and medical applications. In addition, the book examines the integration of key chemistry concepts with nanoelectronics that can improve performance in a diverse range of applications. Sections place a strong emphasis on synthesis processes that can improve the metal oxides’ physical properties and the reflected surface chemical changes that can impact their performance in various devices like light-emitting diodes, luminescence materials, solar cells, etc. Finally, the book discusses the challenges associated with the handling and maintenance of metal oxides crystalline properties. This book will be suitable for academics and those working in R&D in industry looking to learn more about cheaper and more effective methods to produce metal oxides for use in the fields of electronics, photonics, biophotonics and engineering. Reviews the latest advances in the utilization of metal oxide materials in photonics, optoelectronics and optics-based medical applications Considers the most relevant synthesis strategies for the development of high-performing metal oxide-based devices Addresses a wide range of metal oxides including photonic crystals, fibers, metastructures, glasses, and more

ZnO and Their Hybrid Nano-Structures

ZnO and Their Hybrid Nano-Structures PDF Author: Gaurav Sharma
Publisher: Materials Research Forum LLC
ISBN: 1644902389
Category : Technology & Engineering
Languages : en
Pages : 333

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Book Description
ZnO and its hybrid nanostructures have unique optical, physical and chemical properties. The book covers recent trends in processing techniques and applications. Topics include solar cells, photo-voltaic devices, fuel cells, uv filters, lasers, light-emitting diodes, photo-detectors, spin-tronic devices, magnetic semiconductors, nano-generators, piezotronics, photo-catalytic applications against harmful organic pollutants like dyes, heavy metals, antibiotics, and sensors such as bio sensors, chemical sensors, gas sensors. Keywords: ZnO, Nano ZnO, Point Defects, Magnetic Semiconductors, Hybrid Nanostructures, Cell Applications, Nanoadsorbant for Heavy Metal Removals, Diagnostics, ZnO Nano-Carriers, ZnO Thin Films Fabrication.

ZnO Nanostructures

ZnO Nanostructures PDF Author: Dana Crawford
Publisher:
ISBN: 9781536167740
Category : Technology & Engineering
Languages : en
Pages : 200

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Book Description
"Different ZnO nanostructures are attributed to different electronic properties which are favourable in the application of photocatalysis, sensing and energy harvesting. The non toxic behaviour of ZnO nanostructures lead to the use of this material in environmental sensing and environmental remediation. In ZnO Nanostructures: Advances in Research and Applications, a large-scale synthesis of undoped low-dimensional semiconductor metal oxide nanostructures is performed by simple wet-chemical method using reducing agents at low temperature. The detailed structural, compositional, and optical characterizations of the ZnO nanoparticles were evaluated by powder X-ray diffraction pattern, Fourier-transform infra-red spectroscopy, X-ray photoelectron spectroscopy, electron dispersion spectroscopy and UV-vis. Spectroscopy. Following this, the authors describe the structure electrochemical sensors, listing scientific papers focusing on the detection of different pathogens and analytes, as well as reporting and comparing the performance of the sensors prepared by various groups around the world. The concluding chapter deals with synthesis protocols of ZnO heterostructures along with their role in optoelectronic applications. Their thermodynamic stability and correlation among morphology, defects, and heterostructure with luminating and catalytic properties is also described"--

Synthesis and Characterization of ZnO/Graphene Nanostructures for Electronics and Photocatalysis

Synthesis and Characterization of ZnO/Graphene Nanostructures for Electronics and Photocatalysis PDF Author: Seyed Ebrahim Chalangar
Publisher: Linköping University Electronic Press
ISBN: 9179296823
Category :
Languages : en
Pages : 132

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Book Description
Recent rapid development of electronics and electro-optical devices demands affordable and reliable materials with enhanced performance. Forming nanocomposites of already well-known materials is one possible route towards novel functional materials with desirable synergistic enhanced properties. Incompatible chemical properties, mismatched crystal structures and weak bonding interactions between the substances, however, often limit the number of possible nanocomposites. Moreover, using an inexpensive, facile, large-area and flexible fabrication technique is crucial to employ the new composites in industrially viable applications. This thesis focuses on the synthesis and characterization of different zinc oxide/graphene (ZnO/GR) nanocomposites, well suited for optoelectronics and photocatalysis applications. Two different approaches of i) substrate-free random synthesis, and ii) template-assisted selective area synthesis were studied in detail. In the first approach, ZnO nanoparticles/rods were grown on GR. The obtained nanocomposites were investigated for better GR dispersity, electrical conductivity and optical properties. Besides, by adding silver iodide to the nanocomposite, an enhanced plasmonic solar-driven photocatalyst was synthesized and analyzed. In the second approach, arrays of single, vertically aligned ZnO nanorods were synthesized using a colloidal lithography-patterned sol-gel ZnO seed layer. Our demonstrated nanofabrication technique with simple, substrate independent, and large wafer-scale area compatibility improved the alignment and surface density of ZnO nanorods over large selective growth areas. Eventually, we found a novel method to further enhance the vertical alignment of the ZnO nanorods by introducing a GR buffer layer between the Si substrate and the ZnO seed layer, together with the mentioned patterning technique. The synthesized nanocomposites were analyzed using a large variety of experimental techniques including electron microscopy, photoelectron spectroscopy, x-ray diffraction, photoluminescence and cathodoluminescence spectroscopy for in-depth studies of their morphology, chemical and optical properties. Our findings show that the designed ZnO/GR nanocomposites with vertically aligned ZnO nanorods of high crystalline quality, synthesized with the developed low-cost nanofabrication technique, can lead to novel devices offering higher performance at a significantly lower fabrication cost.

1D Semiconducting Hybrid Nanostructures

1D Semiconducting Hybrid Nanostructures PDF Author: Arvind Kumar
Publisher: John Wiley & Sons
ISBN: 3527350276
Category : Technology & Engineering
Languages : en
Pages : 373

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Book Description
In-depth discussion on the physics, chemistry, and engineering beneath the construction of 1D semiconducting hybrid materials 1D Semiconducting Hybrid Nanostructures: Synthesis and Applications in Gas Sensing and Optoelectronics provides breakthrough research developments and trends in a variety of 1D hybrid nanostructures for chemi-resistive gas sensors and optoelectronics applications, including recent investigations and developments regarding the innovative designing approaches, fabrications, and methods used to characterize these hybrid nanostructures. The text also includes the surface and interface properties of 1D hybrid semiconducting nanostructured materials, as well as their optimization for applications in gas sensing and optoelectronics. This book further addresses the different issues of sensitivity, selectivity, and operating temperature of gas sensors based on hybrid 1D nanostructures. Moreover, it covers the novel and additional functional optoelectronic properties that originate at the interface of 1D semiconducting nanostructures combined with other low dimensional materials. Some of the specific sample topics covered in this book include: Gas sensing and optoelectronic applications of one-dimensional semiconducting hybrid nanostructures, plus synthesis and gas sensing application of 1D semiconducting hybrid nanostructures Room temperature gas sensing properties of metal oxide nanowire/graphene hybrid structures and highly sensitive room temperature gas sensors based on organic-inorganic nanofibers Synthesis and applications of 1D hybrid tin oxide nanostructures and recent advances in semiconducting nanowires-based hybrid structures for solar application Types of semiconducting hybrid nanostructures for optoelectronic devices and hybrid 1D semiconducting ZnO/GaN nanostructures Thanks to its comprehensive coverage of the subject from highly qualified authors who have significant experience in the field, 1D Semiconducting Hybrid Nanostructures is a must-have reference for senior undergraduate and graduate students, professionals, researchers, in the field of semiconductor physics, materials science, surface science, and chemical engineering.