Synthesis and Reactions of Cobalt and Rhodium Organometallic Complexes PDF Download
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Author: Jennifer Susan Protopopoff
Publisher:
ISBN:
Category : Organocobalt compounds
Languages : en
Pages :
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Author: Jennifer Susan Protopopoff
Publisher:
ISBN:
Category : Organocobalt compounds
Languages : en
Pages :
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Author: Weihao Da
Publisher:
ISBN:
Category :
Languages : en
Pages : 0
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Supramolecular chemistry has seen a burgeoning interest over the last few decades for the fascinating findings that lie beyond the molecule. Supramolecular chemistry can also offer a fresh interface with biological and materials science. My research project is focused on designing, synthesizing, and exploring the intrinsic properties of complexes based on cobalt, rhodium, and platinum. In each case, thiourea/guanidine derivatives are our ligands of choice to confer H-bonding sites for second-sphere coordination of guest molecules. Second-sphere H-bonding interactions with three different guest molecules were analyzed to obtain association constants (K[subscript a] values) from ~ 10[superscript 2] M[superscript-1] to ~10[superscript 4] M[superscript -1] via UV-vis titration studies. Five sets of single crystal X-Ray diffraction data of our novel complexes were also acquired, alongside the result of a thermochromism test of one of our cobalt complexes. Obtained interesting features include self-recognition and self-assembled structures. Overall, six novel thiourea/guanidine ligand-containing complexes – two for each of cobalt (II), rhodium (III) and platinum (II) - were synthesized. Through these dynamic H-bonding interactions, we see potential applications of our molecules across the fields of medicine, biology, agriculture, and more. Our Host-Guest studies prove that these complexes are able to bind with DNA nucleobase-like molecules via hydrogen bonding, meaning that anticancer assays of our platinum (II) and rhodium (III) thiourea/guanidine-containing compounds are promising avenues for future evaluation. Results of dilution studies show potential supramolecular oligomer structures formed in dynamic system. Finally, testing our compounds within the arena of organometallic catalysis for specific reactions is also promising work that lies ahead.
Author: Carmen Claver
Publisher: Springer
ISBN: 3319666657
Category : Science
Languages : en
Pages : 291
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Book Description
The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics of pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors. All chapters from Topics in Organometallic Chemistry are published OnlineFirst with an individual DOI. In references, Topics in Organometallic Chemistry is abbrev iated as Top Organomet Chem and cited as a journal.
Author: C. White
Publisher: Springer
ISBN: 9781461374770
Category : Medical
Languages : en
Pages : 0
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Thisisoneofthefirstvolumestobepublishedintheseriesof Chapman and Hall Chemistry Sourcebookswhichprovidescarefullytailoredinformationtoworkersin specializedareasofchemistry.Theinformationcontainedinthisbookisderivedfromthe Dictionary of Organometallic Compounds,publishedinNovember1984. Theorganometalliccompoundsofcobalt,rhodiumandiridiumconstituteanimportant classoforganometallics:notonlydotheymeritstudyintheirownrightbuttheyarealso increasinglyusedbothascatalystsandaslaboratoryreagentsinorganicsynthesis. His thereforeanticipatedthatthisparticularcompendiumwillreachawidereadership. Thedatabankonthepropertiesoforganometalliccompounds,whichisrepresentedin itscurrentformbythe Dictionary of Organometallic Compoundsanditssubset publicationssuchasthisvolume,willbekeptcontinuouslyup-to-date. Supplementstothe main Dictionarywillappearannuallyandrevisededitionsofthis Sourcebookwillbe publishedfrom timetotimeasdemandspermits. C. White vii Introduction 1. UsingtheSourcebook (2) Anycompoundwithanestablisheduse,suchas incatalysis,asasyntheticreagentorstartingmaterial. The Sourcebook is divided into element sections: (3) Other compounds of particular chemical, within each section the arrangement of entries is in structural, biological or historical interest, especially order of molecular formula according to the Hill those thought toexhibitunusual bondingcharacteris convention (i.e. C, then H, then other elements in tics. alphabetical sequence of element symbol; where no carbon is present, the elements including Hare Some compounds which are not considered orderedstrictlyalphabetically). sufficiently important to justify separate entries of Every entry is numbered to assist ready location their own have been included as derivatives in the and the entry number consists of a metal element entries of other compounds. These may include for symbolfollowed byafive-digit number. example: (1) Organicderivativesintheclassicalsense. Indexes (2) Donor-acceptorcomplexes.
Author:
Publisher:
ISBN:
Category : Organometallic chemistry
Languages : en
Pages : 600
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Author: Piet W.N.M. van Leeuwen
Publisher: Springer Science & Business Media
ISBN: 0306469472
Category : Science
Languages : en
Pages : 291
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Book Description
In the last decade there have been numerous advances in the area of rhodium-catalyzed hydroformylation, such as highly selective catalysts of industrial importance, new insights into mechanisms of the reaction, very selective asymmetric catalysts, in situ characterization and application to organic synthesis. The views on hydroformylation which still prevail in the current textbooks have become obsolete in several respects. Therefore, it was felt timely to collect these advances in a book. The book contains a series of chapters discussing several rhodium systems arranged according to ligand type, including asymmetric ligands, a chapter on applications in organic chemistry, a chapter on modern processes and separations, and a chapter on catalyst preparation and laboratory techniques. This book concentrates on highlights, rather than a concise review mentioning all articles in just one line. The book aims at an audience of advanced students, experts in the field, and scientists from related fields. The didactic approach also makes it useful as a guide for an advanced course.
Author: Ken Tanaka
Publisher: John Wiley & Sons
ISBN: 3527343644
Category : Science
Languages : en
Pages : 684
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Book Description
An essential reference to the highly effective reactions applied to modern organic synthesis Rhodium complexes are one of the most important transition metals for organic synthesis due to their ability to catalyze a variety of useful transformations. Rhodium Catalysis in Organic Synthesis explores the most recent progress and new developments in the field of catalytic cyclization reactions using rhodium(I) complexes and catalytic carbon-hydrogen bond activation reactions using rhodium(II) and rhodium(III) complexes. Edited by a noted expert in the field with contributions from a panel of leading international scientists, Rhodium Catalysis in Organic Synthesis presents the essential information in one comprehensive volume. Designed to be an accessible resource, the book is arranged by different reaction types. All the chapters provide insight into each transformation and include information on the history, selectivity, scope, mechanism, and application. In addition, the chapters offer a summary and outlook of each transformation. This important resource: -Offers a comprehensive review of how rhodium complexes catalyze a variety of highly useful reactions for organic synthesis (e.g. coupling reactions, CH-bond functionalization, hydroformylation, cyclization reactions and others) -Includes information on the most recent developments that contain a range of new, efficient, elegant, reliable and useful reactions -Presents a volume edited by one of the international leading scientists working in the field today -Contains the information that can be applied by researchers in academia and also professionals in pharmaceutical, agrochemical and fine chemical companies Written for academics and synthetic chemists working with organometallics, Rhodium Catalysis in Organic Synthesis contains the most recent information available on the developments and applications in the field of catalytic cyclization reactions using rhodium complexes.
Author: Geoffrey Wilkinson
Publisher:
ISBN:
Category : Organometallic chemistry
Languages : en
Pages : 650
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Author: Jiro Tsuji
Publisher: Springer
ISBN:
Category : Science
Languages : en
Pages : 220
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Book Description
In 1970 I wrote a review article for "Topics in Current Chemistry", surveying the general reaction patterns of transition-metal complexes from the standpoint of organic synthesis. The article seems to have evoked wide interest, and I therefore thought it appropriate to treat the subject more comprehensively in the form of a monograph. Organometallic chemistry is a rapidly growing field of intensive research. In this field, the application of organometallic compounds to organic synthesis is an important subject and many unique synthetic methods have been discovered, especially in the last decade. Syntheses using transition-metal com pounds are now in the foreground of organic chemistry. The purpose of this monograph is to give a bird's-eye view of this field to both organic and inorganic chemists through a mechanistic approach. A systematic unification of the voluminous data accumulated in this field is now urgently required. This subject is discussed by classifying various reactions into general patterns and by illustrating them with a limited number of pertinent examples.
Author: 麥成達
Publisher: Open Dissertation Press
ISBN: 9781374757059
Category :
Languages : en
Pages :
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This dissertation, "Synthesis and Reactivities of Cobalt and Rhodium Complexes With Macrocyclic Tertiary Amine and Multianionic Amide Ligands" by 麥成達, Shing-tat, Mak, was obtained from The University of Hong Kong (Pokfulam, Hong Kong) and is being sold pursuant to Creative Commons: Attribution 3.0 Hong Kong License. The content of this dissertation has not been altered in any way. We have altered the formatting in order to facilitate the ease of printing and reading of the dissertation. All rights not granted by the above license are retained by the author. DOI: 10.5353/th_b3123130 Subjects: Cobalt Rhodium Iridium Electrochemistry
