Author: Kwoliang David Tau
Publisher:
ISBN:
Category : Phosphine
Languages : en
Pages : 288
Book Description
SYNTHESIS AND CHARACTERIZATION OF POLYPHOSPHINE LIGANDS AND THEIR PLATINUM METAL COMPLEXES.
Author: Kwoliang David Tau
Publisher:
ISBN:
Category : Phosphine
Languages : en
Pages : 288
Book Description
Publisher:
ISBN:
Category : Phosphine
Languages : en
Pages : 288
Book Description
Synthesis and Characterization of Polyphosphine Ligands and Their Platinum Metal Complexes
Author: Kwoliang David Tau
Publisher:
ISBN:
Category :
Languages : en
Pages :
Book Description
Publisher:
ISBN:
Category :
Languages : en
Pages :
Book Description
Synthesis and Characterization of Platinum Complexes with Oximes-based Ligands
Author: Michael Hilton
Publisher:
ISBN:
Category : Anisotropy
Languages : en
Pages : 214
Book Description
Classic Magnus' Green Salt and several tetracyanoplatinates represent one-dimensional coordination polymers. They have been examined previously for their unique optical properties and electrical conductivity. Mixed valence tetracyanoplatinates have an appearance and conductivity similar to a metal. Both of these traits are attributed to the close distance between platinum centers in the extended one dimensional structures of these complexes. The aim of this research was to synthesize and characterize a series of new 1D oximes-based platinum complexes with a primary interest in their anisotropic properties. I selected a group of N,O mixed donor chelating ligands with various steric and electronic properties. Therefore, complexes formed are tunable for a particular application as 1D solids. Ten compounds of PtL2 compositions were prepared and used in this study. A visual indication of the formation of the 1D solids with close metallophilic Pt···Pt interactions is in the dark green, blue or purple color of the complexes: Thus, complexes show a charge-transfer band 600-900 nm in the UV-visible spectra. Synthesized Pt-complexes were studied using IR, UV-visible spectroscopy and X-ray analysis. Solutions studies also included dynamic light scattering. Isotopic labeling with 15N of some of the ligands allowed better understanding of their IR and NMR spectra. Four out of ten studied Pt-complexes demonstrated presence of metallophilic Pt···Pt interactions.
Publisher:
ISBN:
Category : Anisotropy
Languages : en
Pages : 214
Book Description
Classic Magnus' Green Salt and several tetracyanoplatinates represent one-dimensional coordination polymers. They have been examined previously for their unique optical properties and electrical conductivity. Mixed valence tetracyanoplatinates have an appearance and conductivity similar to a metal. Both of these traits are attributed to the close distance between platinum centers in the extended one dimensional structures of these complexes. The aim of this research was to synthesize and characterize a series of new 1D oximes-based platinum complexes with a primary interest in their anisotropic properties. I selected a group of N,O mixed donor chelating ligands with various steric and electronic properties. Therefore, complexes formed are tunable for a particular application as 1D solids. Ten compounds of PtL2 compositions were prepared and used in this study. A visual indication of the formation of the 1D solids with close metallophilic Pt···Pt interactions is in the dark green, blue or purple color of the complexes: Thus, complexes show a charge-transfer band 600-900 nm in the UV-visible spectra. Synthesized Pt-complexes were studied using IR, UV-visible spectroscopy and X-ray analysis. Solutions studies also included dynamic light scattering. Isotopic labeling with 15N of some of the ligands allowed better understanding of their IR and NMR spectra. Four out of ten studied Pt-complexes demonstrated presence of metallophilic Pt···Pt interactions.
I. Synthesis, Characterization and Reactivity of Platinum(II) Metal Complexes of Phosphorus-containing Mesocycles. II. Bifunctional Phosphines as Reagents in Carbon Tetrachloride-promoted Chlorination Reactions
Author: Susan Deborah Toto
Publisher:
ISBN:
Category :
Languages : en
Pages : 504
Book Description
Publisher:
ISBN:
Category :
Languages : en
Pages : 504
Book Description
Synthesis and characterization of platinum(II) complexes with thiophene-based ligands
Author: Julienne Sarabia
Publisher:
ISBN:
Category : Ligands
Languages : en
Pages : 0
Book Description
Publisher:
ISBN:
Category : Ligands
Languages : en
Pages : 0
Book Description
Synthesis, Characterization and Reactivity of Platinum(0)-tetraphosphion Complexes and Group VIII Metal Phosphine Complexes Coordinated to Alkoxide and Hydroxide Ligands
Author: Lisa Marie Green
Publisher:
ISBN:
Category : Ligands
Languages : en
Pages : 502
Book Description
Publisher:
ISBN:
Category : Ligands
Languages : en
Pages : 502
Book Description
Synthesis and Characterization of Platinum (II) Complexes with Sulfur- and Nitrogen- Containing Ligands
Author: Jun Wen
Publisher:
ISBN:
Category : Ligands
Languages : en
Pages : 96
Book Description
Publisher:
ISBN:
Category : Ligands
Languages : en
Pages : 96
Book Description
Synthesis and Characterization of Platinum (II) Complexes with Diazine Ligands
Author: Julien Priqueler
Publisher:
ISBN:
Category :
Languages : en
Pages :
Book Description
Publisher:
ISBN:
Category :
Languages : en
Pages :
Book Description
The Synthesis and Characterization of Bidentate Phosphine and Arsine Ligands and Their Complexes with Palladium (II) and Platinum (II)
Author: David Michael Anthony Minahan
Publisher:
ISBN:
Category : Ligands
Languages : en
Pages : 332
Book Description
Publisher:
ISBN:
Category : Ligands
Languages : en
Pages : 332
Book Description
Synthesis and characterization of bismetalated platinum complexes containing benzothiophene functionalized ligands
Author: Asad Hashmi
Publisher:
ISBN:
Category : Ligands
Languages : en
Pages : 0
Book Description
Publisher:
ISBN:
Category : Ligands
Languages : en
Pages : 0
Book Description