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Author: Charles E. Carraher Jr.
Publisher: Springer Science & Business Media
ISBN: 1461306698
Category : Science
Languages : en
Pages : 506
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Book Description
Research on metal-containing polymers began in the early 1960's when several workers found that vinyl ferrocene and other vinylic transition metal TI -complexes would undergo polymerization under the same conditions as conventional organic monomers to form high polymers which incorporated a potentially reactive metal as an integral part of the polymer structures. Some of these materials could act as semi conductors and possessed one or two dimensional conductivity. Thus applications in electronics could be visualized immediately. Other workers found that reactions used to make simple metal chelates could be used to prepare polymers if the ligands were designed properly. As interest in homogeneous catalysts developed in the late 60's and early 70's, several investigators began binding homogeneous catalysts onto polymers, where the advantage of homogeneous catalysis - known reaction mechanisms and the advantage of heterogeneous catalysis - simplicity and ease of recovery of catalysts could both be obtained. Indeed the polymer matrix itself often enhanced the selectivity of the catalyst. The first symposium on Organometallic Polymers, held at the National Meeting of the American Chemical Society in September 1977, attracted a large number of scientists interested in this field, both established investigators and newcomers. Subsequent symposia in 1977, 1979, 1983, and 1987 have seen the field mature. Hundreds of papers and patents have been published.
Author: Charles E. Carraher Jr.
Publisher: Springer Science & Business Media
ISBN: 1461306698
Category : Science
Languages : en
Pages : 506
Get Book Here
Book Description
Research on metal-containing polymers began in the early 1960's when several workers found that vinyl ferrocene and other vinylic transition metal TI -complexes would undergo polymerization under the same conditions as conventional organic monomers to form high polymers which incorporated a potentially reactive metal as an integral part of the polymer structures. Some of these materials could act as semi conductors and possessed one or two dimensional conductivity. Thus applications in electronics could be visualized immediately. Other workers found that reactions used to make simple metal chelates could be used to prepare polymers if the ligands were designed properly. As interest in homogeneous catalysts developed in the late 60's and early 70's, several investigators began binding homogeneous catalysts onto polymers, where the advantage of homogeneous catalysis - known reaction mechanisms and the advantage of heterogeneous catalysis - simplicity and ease of recovery of catalysts could both be obtained. Indeed the polymer matrix itself often enhanced the selectivity of the catalyst. The first symposium on Organometallic Polymers, held at the National Meeting of the American Chemical Society in September 1977, attracted a large number of scientists interested in this field, both established investigators and newcomers. Subsequent symposia in 1977, 1979, 1983, and 1987 have seen the field mature. Hundreds of papers and patents have been published.
Author:
Publisher: Newnes
ISBN: 0080878628
Category : Technology & Engineering
Languages : en
Pages : 7752
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Book Description
The progress in polymer science is revealed in the chapters of Polymer Science: A Comprehensive Reference, Ten Volume Set. In Volume 1, this is reflected in the improved understanding of the properties of polymers in solution, in bulk and in confined situations such as in thin films. Volume 2 addresses new characterization techniques, such as high resolution optical microscopy, scanning probe microscopy and other procedures for surface and interface characterization. Volume 3 presents the great progress achieved in precise synthetic polymerization techniques for vinyl monomers to control macromolecular architecture: the development of metallocene and post-metallocene catalysis for olefin polymerization, new ionic polymerization procedures, and atom transfer radical polymerization, nitroxide mediated polymerization, and reversible addition-fragmentation chain transfer systems as the most often used controlled/living radical polymerization methods. Volume 4 is devoted to kinetics, mechanisms and applications of ring opening polymerization of heterocyclic monomers and cycloolefins (ROMP), as well as to various less common polymerization techniques. Polycondensation and non-chain polymerizations, including dendrimer synthesis and various "click" procedures, are covered in Volume 5. Volume 6 focuses on several aspects of controlled macromolecular architectures and soft nano-objects including hybrids and bioconjugates. Many of the achievements would have not been possible without new characterization techniques like AFM that allowed direct imaging of single molecules and nano-objects with a precision available only recently. An entirely new aspect in polymer science is based on the combination of bottom-up methods such as polymer synthesis and molecularly programmed self-assembly with top-down structuring such as lithography and surface templating, as presented in Volume 7. It encompasses polymer and nanoparticle assembly in bulk and under confined conditions or influenced by an external field, including thin films, inorganic-organic hybrids, or nanofibers. Volume 8 expands these concepts focusing on applications in advanced technologies, e.g. in electronic industry and centers on combination with top down approach and functional properties like conductivity. Another type of functionality that is of rapidly increasing importance in polymer science is introduced in volume 9. It deals with various aspects of polymers in biology and medicine, including the response of living cells and tissue to the contact with biofunctional particles and surfaces. The last volume is devoted to the scope and potential provided by environmentally benign and green polymers, as well as energy-related polymers. They discuss new technologies needed for a sustainable economy in our world of limited resources. Provides broad and in-depth coverage of all aspects of polymer science from synthesis/polymerization, properties, and characterization methods and techniques to nanostructures, sustainability and energy, and biomedical uses of polymers Provides a definitive source for those entering or researching in this area by integrating the multidisciplinary aspects of the science into one unique, up-to-date reference work Electronic version has complete cross-referencing and multi-media components Volume editors are world experts in their field (including a Nobel Prize winner)
Author: Alaa S. Abd-El-Aziz
Publisher: John Wiley & Sons
ISBN: 047171254X
Category : Technology & Engineering
Languages : en
Pages : 368
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Book Description
This series provides a useful, applications-oriented forum for the next generation of macromolecules and materials. Volume 4 provides useful descriptions of Group IV metals and their applications, including silicon-, organogermanium-, organotin-, and organolead-containing polymers. A high-quality team of macromolecular experts from around the world have put together these leading macromolecule titles.
Author: Sabu Thomas
Publisher: Elsevier
ISBN: 0128213582
Category : Technology & Engineering
Languages : en
Pages : 578
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Book Description
Polyhedral Oligomeric Silsesquioxane (POSS) Polymer Nanocomposites: From Synthesis to Applications offers extensive coverage of polyhedral oligomeric silsesquioxanes and their nanocomposites, including their synthesis, characterization, interfacial interactions and advanced applications. Sections introduce essentials, information on their preparation and discussions on polymeric materials, including elastomers, thermoplastics, thermosetting polymers, polymer blends and IPNs. Further sections cover the latest analysis techniques, examine the properties of POSS-polymer nanocomposites, and discuss key application areas, such as biological, energy, defense, and space. Finally, issues surrounding industry implementation and lifecycle are explored. This is a valuable reference for researchers, scientists and advanced students in the areas of polymer composites and nanocomposites, polymer chemistry, polymer physics, polymer science, and materials science and engineering. In an industrial setting, this book will be of great interest to scientists, R&D professionals, and engineers across industries and disciplines. - Covers all aspects of polyhedral oligomeric silsesquioxanes (POSS) and their nanocomposites, including synthesis and characterization techniques, properties, analysis, applications and trends - Targets POSS nanocomposites, describing synthesis, characterization and the selection of POSS filler types according to polymeric material - Explains the preparation and utilization of POSS polymer nanocomposites for cutting-edge applications, including biological, energy, and defense field applications
Author: Constantin V. Uglea
Publisher: CRC Press
ISBN: 9780849349546
Category : Technology & Engineering
Languages : en
Pages : 388
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Book Description
This book provides an excellent introduction to the fundamentals of oligomer chemistry. Each section describes the synthesis, separation, physico-chemical characterization, and present and future applications of individual classes of oligomers organized according to the chemical structure of the main chain. In addition, this book features up-to-date references from both journals and patents and an extensive appendix covering synthesis and characterization methods of oligomeric derivatives. Synthesis and Characterization of Oligomers is a broad, state-of-the-art survey and will be useful not only for students and professionals working with oligomers, but also chemists who are new to the field.
Author: Alaa S. Abd-El-Aziz
Publisher: John Wiley & Sons
ISBN: 0471466565
Category : Technology & Engineering
Languages : en
Pages : 305
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Book Description
Metal- and metalloid-containing macromolecules are defined as large molecules (i.e., polymers, DNA, proteins) that contain a metal or metalloid group affiliated with the molecule. Compiled by an all-star cast of macromolecular experts, Macromolecules Containing Metal and Metal-Like Elements, Volume 2, Organoiron-Containing Polymers: Provides useful descriptions of applications for the reader to apply in his/her research into materials, polymers, and medicine/drug development. Covers non-linear optical materials, speciality magnetic materials, liquid crystals, anticancer and antiviral drugs, treatment of arthritis, antibacterial drugs, antifouling materials, treatment of certain vitamin deficiencies, electrical conductors and semiconductors, piezoelectronic materials, electrodes, UV absorption applications, super-strength materials, special lubricants and gaskets, selective catalytic and multisite catalytic agents.
Author: Charles E. Carraher Jr.
Publisher: CRC Press
ISBN: 1439809569
Category : Technology & Engineering
Languages : en
Pages : 804
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Book Description
Updated to reflect a growing focus on green chemistry in the scientific community and in compliance with the American Chemical Society’s Committee on Professional Training guidelines, Carraher’s Polymer Chemistry, Eighth Edition integrates the core areas that contribute to the growth of polymer science. It supplies the basic understanding of polymers essential to the training of science, biomedical, and engineering students. New in the Eighth Edition: Updating of analytical, physical, and special characterization techniques Increased emphasis on carbon nanotubes, tapes and glues, butyl rubber, polystyrene, polypropylene, polyethylene, poly(ethylene glycols), shear-thickening fluids, photo-chemistry and photophysics, dental materials, and aramids New sections on copolymers, including fluoroelastomers, nitrile rubbers, acrylonitrile-butadiene-styrene terpolymers, and EPDM rubber New units on spliceosomes, asphalt, and fly ash and aluminosilicates Larger focus on the molecular behavior of materials, including nano-scale behavior, nanotechnology, and nanomaterials Continuing to provide a user-friendly approach to the world of polymeric materials, the book allows students to integrate their chemical knowledge and establish a connection between fundamental and applied chemical information. It contains all of the elements of an introductory text with synthesis, property, application, and characterization. Special sections in each chapter contain definitions, learning objectives, questions, and additional reading, with case studies woven into the text fabric. Symbols, trade names, websites, and other useful ancillaries appear in the appendices to supplement the text.
Author: Management Association, Information Resources
Publisher: IGI Global
ISBN: 1799887367
Category : Technology & Engineering
Languages : en
Pages : 1917
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Book Description
The use of nanotechnologies continues to grow, as nanomaterials have proven their versatility and use in many different fields and industries within the scientific profession. Using nanotechnology, materials can be made lighter, more durable, more reactive, and more efficient leading nanoscale materials to enhance many everyday products and processes. With many different sizes, shapes, and internal structures, the applications are endless. These uses range from pharmaceutics to materials such as cement or cloth, electronics, environmental sustainability, and more. Therefore, there has been a recent surge of research focused on the synthesis and characterizations of these nanomaterials to better understand how they can be used, their applications, and the many different types. The Research Anthology on Synthesis, Characterization, and Applications of Nanomaterials seeks to address not only how nanomaterials are created, used, or characterized, but also to apply this knowledge to the multidimensional industries, fields, and applications of nanomaterials and nanoscience. This includes topics such as both natural and manmade nanomaterials; the size, shape, reactivity, and other essential characteristics of nanomaterials; challenges and potential effects of using nanomaterials; and the advantages of nanomaterials with multidisciplinary uses. This book is ideally designed for researchers, engineers, practitioners, industrialists, educators, strategists, policymakers, scientists, and students working in fields that include materials engineering, engineering science, nanotechnology, biotechnology, microbiology, drug design and delivery, medicine, and more.
Author: Charles E. Carraher Jr.
Publisher: CRC Press
ISBN: 1498737455
Category : Science
Languages : en
Pages : 794
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Book Description
Carraher's Polymer Chemistry, Tenth Edition integrates the core areas of polymer science. Along with updating of each chapter, newly added content reflects the growing applications in Biochemistry, Biomaterials, and Sustainable Industries. Providing a user-friendly approach to the world of polymeric materials, the book allows students to integrate their chemical knowledge and establish a connection between fundamental and applied chemical information. It contains all of the elements of an introductory text with synthesis, property, application, and characterization. Special sections in each chapter contain definitions, learning objectives, questions, case studies and additional reading.
Author: Klaus Müllen
Publisher: John Wiley & Sons
ISBN: 352761205X
Category : Technology & Engineering
Languages : en
Pages : 630
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Book Description
Electroactive oligomers form an important class of advanced materials for the development of new devices such as thin-film, flexible batteries; semiconductors; large-area optical displays; and sensors. In addition, the study of oligomeric model compounds is an essential prerequisite for understanding and developing polymers for electronics and optoelectronics applications. Written and edited by leading scientists in the field, this applications-oriented handbook represents the first comprehensive, systematic study of electroactive oligomeric materials. Special emphasis is placed on a critical review of the literature; relevant materials and technical data are collected in tables throughout. Includes - materials synthesis - structure--property relationship as a function of chain-length - applications in optics and electronics - oligomers as models for polymers - the role of oligomers in tomorrow's technology? Electronic Materials - The Oligomer Approach offers a stimulating combination of basic concepts and practical applications. It is sure to become a standard reference source that no-one working in the field can do without.
