Some Observations on the Basic Chemistry of Plutonium PDF Download
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Author: E. S. Maxwell
Publisher:
ISBN:
Category : Plutonium
Languages : en
Pages : 8
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Book Description
On prolonged heating in dilute nitric acid (0.5M to 6.8M) a considerable amount of Pu(+4) is oxidized to Pu(+8). Precipitation of the plus three plutonium oxalate is complete in fifteen minutes. Oxidation of Pu(+4) to Pu(+8) by bromine is quantitative at 105 deg C after 1/2 hour; at 50 deg C the rate of oxidation is slow, but measurable. At room temperature the rate is too slow to measure. A method of converting PuC13 to Pu(NO3)4 is given. A solubility of NaPuO2Ac3 increases with temperature the value at 25 deg C being 19.5 g/iiter and that at 95 deg C, 37.5 g/liter. Supersaturation was observed on slow cooling of a saturated solution. p2.
Author: E. S. Maxwell
Publisher:
ISBN:
Category : Plutonium
Languages : en
Pages : 8
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Book Description
On prolonged heating in dilute nitric acid (0.5M to 6.8M) a considerable amount of Pu(+4) is oxidized to Pu(+8). Precipitation of the plus three plutonium oxalate is complete in fifteen minutes. Oxidation of Pu(+4) to Pu(+8) by bromine is quantitative at 105 deg C after 1/2 hour; at 50 deg C the rate of oxidation is slow, but measurable. At room temperature the rate is too slow to measure. A method of converting PuC13 to Pu(NO3)4 is given. A solubility of NaPuO2Ac3 increases with temperature the value at 25 deg C being 19.5 g/iiter and that at 95 deg C, 37.5 g/liter. Supersaturation was observed on slow cooling of a saturated solution. p2.
Author:
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ISBN:
Category : Nuclear energy
Languages : en
Pages : 658
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Author:
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ISBN:
Category :
Languages : en
Pages : 5
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Book Description
On prolonged heating in dilute nitric acid (0.5M to 6.8M) a considerable amount of Pu(+4) is oxidized to Pu(+8). Precipitation of the plus three plutonium oxalate is complete in fifteen minutes. Oxidation of Pu(+4) to Pu(+8) by bromine is quantitative at 105 deg C after 1/2 hour; at 50 deg C the rate of oxidation is slow, but measurable. At room temperature the rate is too slow to measure. A method of converting PuC13 to Pu(NO3)4 is given. A solubility of NaPuO2Ac3 increases with temperature the value at 25 deg C being 19.5 g/iiter and that at 95 deg C, 37.5 g/liter. Supersaturation was observed on slow cooling of a saturated solution. p2.
Author:
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ISBN:
Category : Actinide elements
Languages : en
Pages : 358
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Author: Joseph S. Griffo
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ISBN:
Category : Nuclear energy
Languages : en
Pages : 44
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Author: U.S. Atomic Energy Commission
Publisher:
ISBN:
Category : Nuclear energy
Languages : en
Pages : 106
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Author: Jesse M. Cleveland
Publisher:
ISBN:
Category : Science
Languages : en
Pages : 688
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Book Description
Dr. Cleveland's monographs is a comprehensive and authoritative treatise on the theory and practice of plutonium chemistry and is of value to all chemists interested in the chemistry of the actinide elements.
Author:
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Category : Nuclear energy
Languages : en
Pages : 564
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Author: U.S. Atomic Energy Commission
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Category :
Languages : en
Pages : 414
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Author:
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Category : Science
Languages : en
Pages : 96
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