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Author: Stephen Hull
Publisher: Springer
ISBN: 9789048186822
Category : Science
Languages : en
Pages : 300
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Book Description
Solid electrolytes or superionics are materials which exhibit exceptionally high values of ionic conductivity due to the rapid diffusion of one ionic species through a lattice formed by immobile counterions. Originally studied by Faraday in the 1830s, and for many years considered little more than scientific curiosities, ionically conducting solids are now a widely studied class of materials with important technological applications within solid state batteries, gas sensors and fuel cells. This book aims to provide an introduction to solid electrolytes and their historical development. A detailed summary of the major families of superionic compounds will be presented, with particular emphasis on the most important examples. An assessment of our current understanding of the relationship between the crystal structure of superionics and their bulk conduction processes will be given, permitting a discussion of the factors which promote rapid ionic motion within solids. These more 'fundamental' research issues will be complemented by a discussion of the technological applications of ionically conducting solids, their current limitations and future prospects.
Author: Stephen Hull
Publisher: Springer
ISBN: 9789048186822
Category : Science
Languages : en
Pages : 300
Get Book
Book Description
Solid electrolytes or superionics are materials which exhibit exceptionally high values of ionic conductivity due to the rapid diffusion of one ionic species through a lattice formed by immobile counterions. Originally studied by Faraday in the 1830s, and for many years considered little more than scientific curiosities, ionically conducting solids are now a widely studied class of materials with important technological applications within solid state batteries, gas sensors and fuel cells. This book aims to provide an introduction to solid electrolytes and their historical development. A detailed summary of the major families of superionic compounds will be presented, with particular emphasis on the most important examples. An assessment of our current understanding of the relationship between the crystal structure of superionics and their bulk conduction processes will be given, permitting a discussion of the factors which promote rapid ionic motion within solids. These more 'fundamental' research issues will be complemented by a discussion of the technological applications of ionically conducting solids, their current limitations and future prospects.
Author: Paul Hagenmuller
Publisher: Elsevier
ISBN: 1483191656
Category : Science
Languages : en
Pages : 570
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Book Description
Solid Electrolytes: General Principles, Characterization, Materials, Applications presents specific theories and experimental methods in the field of superionic conductors. It discusses that high ionic conductivity in solids requires specific structural and energetic conditions. It addresses the problems involved in the study and use of solid electrolytes. Some of the topics covered in the book are the introduction to the theory of solid electrolytes; macroscopic evidence for liquid nature; structural models; kinetic models; crystal structures and fast ionic conduction; interstitial motion in body-centered cubic structures; and materials with the fluorite and antifluorite structures. The diffraction studies of superionic conductors are covered. The significance of defects and disorder to ionic conductivity are discussed. The text describes the transport mechanisms and lattice defects. A study of the diffusion and ionic conductivity equations is presented. A chapter is devoted to the quasi-elastic neutron scattering. Another section focuses on the complex conductivity in the microwave range. The book can provide useful information to scientists, physicists, students, and researchers.
Author: E. Subbarao
Publisher: Springer Science & Business Media
ISBN: 1461330815
Category : Technology & Engineering
Languages : en
Pages : 309
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Book Description
Defect solid state has been an area of major scientific and technological interest for the last few decades, the resulting important applications sus taining this interest. Solid electrolytes represent one area of defect solid state. The early work on defect ionic crystals and, in particular, the classic results of Kiukkola and Wagner in 1957 on stabilized zirconia and doped thoria laid the foundation for a systematic study of solid electrolytes. In the same year, Ure reported on the ionic conductivity of calcium fluoride. Since then, intense worldwide research has advanced our understanding of the defect structure and electrical conductivity of oxygen ion conductors such as doped zirconia and thoria and of the fluorides. This paved the way for thermo dynamic and kinetic studies using these materials and for technological applications based on the oxygen ion conductors. In the last few years we have seen the emergence of two new classes of solid electrolytes of great signifi cance: the fJ-aluminas and the silver ion conductors. The significance of these discoveries is that now (i) solid electrolytes are available which at room temperature exhibit electrical conductivity comparable to that of liquid electrolytes, (ii) useful electrical conductivity values can be achieved over a wide range of temperature and ambient conditions, and (iii) a wide variety of ions are available as conducting species in solids. The stage is therefore set for a massive effort at developing applications.
Author: Ramaswamy Murugan
Publisher: Springer Nature
ISBN: 3030315819
Category : Science
Languages : en
Pages : 373
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Book Description
This book highlights the state of the art in solid electrolytes, with particular emphasis on lithium garnets, electrolyte-electrode interfaces and all-solid-state batteries based on lithium garnets. Written by an international group of renowned experts, the book addresses how garnet-type solid electrolytes are contributing to the development of safe high energy density Li batteries. Unlike the flammable organic liquid electrolyte used in existing rechargeable Li batteries, garnet-type solid electrolytes are intrinsically chemically stable in contact with metallic lithium and potential positive electrodes, while offering reasonable Li conductivity. The book's respective chapters cover a broad spectrum of topics related to solid electrolytes, including interfacial engineering to resolve the electrolyte-electrode interfaces, the latest developments in the processing of thin and ultrathin lithium garnet membranes, and fabrication strategies for the high-performance solid-state batteries.This highly informative and intriguing book will appeal to postgraduate students and researchers at academic and industrial laboratories with an interest in the advancement of high energy-density lithium metal batteries
Author: César Sequeira
Publisher: Elsevier
ISBN: 1845699777
Category : Technology & Engineering
Languages : en
Pages : 640
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Book Description
Polymer electrolytes are electrolytic materials that are widely used in batteries, fuel cells and other applications such as supercapacitors, photoelectrochemical and electrochromic devices. Polymer electrolytes: Fundamentals and applications provides an important review of this class of ionic conductors, their properties and applications.Part one reviews the various types of polymer electrolyte compounds, with chapters on ceramic polymer electrolytes, natural polymer-based polymer electrolytes, composite polymer electrolytes, lithium-doped hybrid polymer electrolytes, hybrid inorganic-organic polymer electrolytes. There are also chapters on ways of characterising and modelling polymer electrolytes. Part two discusses applications such as solar cells, supercapacitors, electrochromic and electrochemical devices, fuel cells and batteries.With its distinguished editors and international team of contributors, Polymer electrolytes: Fundamentals and applications is a standard reference for all those researching and using polymer electrolytes in such areas as battery and fuel cell technology for automotive and other applications. Provides an important review of this class of ionic conductors, their properties and applications in practical devices Explores categories of polymer electrolytes and conductivity measurements Features a comprehensive analysis of current developments in polymer electrolytes and highlights a new type of polymer electrolyte
Author: Sanjib Bhattacharya
Publisher: Springer Nature
ISBN: 9811932697
Category : Science
Languages : en
Pages : 190
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Book Description
This book presents recent developments and future scopes of glassy systems, such as their electrical and optical properties, use as electrodes, photonics devices, battery applications and others, which are of great interest for material scientists and professionals. Each chapter is designed to increase coherence, containing examples and question sets as exercises for in-depth understanding of the text. It provides a valuable resource for researchers, professionals and students in the area of material research especially on Li-doped glasses.
Author: Amulya Laskar
Publisher: Elsevier
ISBN: 0323142931
Category : Science
Languages : en
Pages : 731
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Book Description
Superionic Solids and Solid Electrolytes: Recent Trends describes the fundamental aspects, unique properties, and potential applications of superionic solids and solid electrolytes. These materials significantly contribute to the development of the solid state ionics technology. This book is divided into 17 chapters, and begins with an overview of various materials, such as glasses, heterogeneous or dispersed phase conductors, proton conductors, Nasicon, and fluorites. These topics are followed by a discussion on the problems related with entropy effects, subsurface space charge, and defect formation parameters. Significant chapters deal with the phenomenological, fractal, molecular dynamics, fluctuations, and correlations in superionic solid and solid electrolyte materials. A chapter tackles the solid state battery applications of solid electrolytes. This text ends with a chapter on the prediction of the potentials of activity in superionics. This book will be of value to graduate students and researchers who are interested in the solid state ionics technology.
Author: Šárka Nenadálová
Publisher: Trans Tech Publications Ltd
ISBN: 3036411593
Category : Science
Languages : en
Pages : 222
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Book Description
Special topic volume with invited peer-reviewed papers only
Author: Meng Zheng
Publisher: Frontiers Media SA
ISBN: 283250986X
Category : Science
Languages : en
Pages : 138
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Book Description
Author: Shanqing Zhang
Publisher: John Wiley & Sons
ISBN: 3527350683
Category : Technology & Engineering
Languages : en
Pages : 229
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Book Description
Functional Polymers for Metal-Ion Batteries Unique and useful book covering fundamental knowledge and practical applications of polymer materials in energy storage systems In Functional Polymers for Metal-Ion Batteries, the recent development and achievements of polymer-based materials are comprehensively analyzed in four directions, including electrode materials, binders, separators, and solid electrolytes, highlighting the working mechanisms, classification, design strategies, and practical applications of these polymer materials in mental-ion batteries. Specific sample topics covered in Functional Polymers for Metal-Ion Batteries include: Prominent advantages of various solid-state electrolytes, such as low flammability, easy processability, more tolerance to vibration, shock, and mechanical deformation Why and how functional polymers present opportunities to maximize energy density and pursue the sustainability of the battery industry How the application of functional polymers in metal-ion batteries helps enhance the high energy density of energy storage devices and reduce carbon footprint during production How development of functional separators could significantly lower the cost of battery manufacturing Providing a comprehensive understanding of the role of polymers in the whole configuration of metal-ion batteries from electrodes to electrolytes, Functional Polymers for Metal-Ion Batteries is an ideal resource for materials scientists, electrochemists, and polymer, solid state, and physical chemists who wish to understand the latest developments of this technology.
