SOA Formation

SOA Formation PDF Author:
Publisher:
ISBN:
Category : Aerosols
Languages : en
Pages : 196

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Book Description

SOA Formation

SOA Formation PDF Author:
Publisher:
ISBN:
Category : Aerosols
Languages : en
Pages : 196

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Book Description


Modeling the Formation and Evolution of Secondary Organic Aerosol During CalNex 2010

Modeling the Formation and Evolution of Secondary Organic Aerosol During CalNex 2010 PDF Author: José Luis Jiménez
Publisher:
ISBN:
Category : Aerosols
Languages : en
Pages : 120

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Simulation and Assessment of Chemical Processes in a Multiphase Environment

Simulation and Assessment of Chemical Processes in a Multiphase Environment PDF Author: Ian Barnes
Publisher: Springer Science & Business Media
ISBN: 1402088469
Category : Technology & Engineering
Languages : en
Pages : 549

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Book Description
The book reviews the current state of knowledge on the chemical and physical processes occurring in the environmental media (i) the atmosphere, (ii) the aqueous phase and (iii) soil and identifies the strengths and weaknesses of the chemical mechanisms (both explicit and condensed) currently available to simulate the multimedia environmental chemistry of volatile organic compounds (VOCs) and particulate matter in these media. Contributions examine how well this knowledge has been incorporated into different types of CT models and appraise the current status and significant issues in the development and usage of the models. Model simulations of some real world chemical perturbations to the Earth system are presented which appraise the performance of the models in relation to "real world" observations. Serious caveats in our understanding of chemical processes and their simulation in the various compartments of the Earth system are highlighted and areas are identified that need urgent improvement, in particular with respect to environmental security.

Formation Mechanism and Control Strategies of Haze in China

Formation Mechanism and Control Strategies of Haze in China PDF Author: Hong He
Publisher: Springer Nature
ISBN: 9811969566
Category : Science
Languages : en
Pages : 263

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Book Description
This book summarizes the new major research findings about formation mechanism and control strategies of haze in China, including basic theories, key technologies, equipment and platforms and the applications and implementations of control technologies, in implementing the Strategic Priority Research Program (Class B) of Chinese Academy of Sciences. Different types of air pollution processes experienced by the developed countries in different stages are out-breaking simultaneously in China in the recent years and resulting a new type of “haze chemistry smog” pollution, which is different from the “London smog” and the “Los Angeles photochemical smog”. This book provides a useful reference for related researchers, engineers and policy-makers engaged in atmospheric pollution research, prevention and control in China and other countries.

Atmospheric and Aerosol Chemistry

Atmospheric and Aerosol Chemistry PDF Author: V. Faye McNeill
Publisher: Springer
ISBN: 3642412157
Category : Science
Languages : en
Pages : 267

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Book Description
Christian George, Barbara D’Anna, Hartmut Herrmann, Christian Weller, Veronica Vaida, D. J. Donaldson, Thorsten Bartels-Rausch, Markus Ammann - Emerging Areas in Atmospheric Photochemistry. Lisa Whalley, Daniel Stone, Dwayne Heard - New Insights into the Tropospheric Oxidation of Isoprene: Combining Field Measurements, Laboratory Studies, Chemical Modelling and Quantum Theory. Neil M. Donahue, Allen L. Robinson, Erica R. Trump, Ilona Riipinen, Jesse H. Kroll - Volatility and Aging of Atmospheric Organic Aerosol. P. A. Ariya, G. Kos, R. Mortazavi, E. D. Hudson, V. Kanthasamy, N. Eltouny, J. Sun, C. Wilde - Bio-Organic Materials in the Atmosphere and Snow: Measurement and Characterization. V. Faye McNeill, Neha Sareen, Allison N. Schwier - Surface-Active Organics in Atmospheric Aerosols.

Atmospheric Aerosols

Atmospheric Aerosols PDF Author: Hayder Abdul-Razzak
Publisher: BoD – Books on Demand
ISBN: 9535107283
Category : Science
Languages : en
Pages : 494

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Book Description
The book is divided into two sections. The first section presents characterization of atmospheric aerosols and their impact on regional climate from East Asia to the Pacific. Ground-based, air-born, and satellite data were collected and analyzed. Detailed information about measurement techniques and atmospheric conditions were provided as well. In the second section, authors provide detailed information about the organic and inorganic constituents of atmospheric aerosols. They discuss the chemical and physical processes, temporal and spatial distribution, emissions, formation, and transportation of aerosol particles. In addition, new measurement techniques are introduced. This book hopes to serve as a useful resource to resolve some of the issues associated with the complex nature of the interaction between atmospheric aerosols and climatology.

Environmental Science and Technology: Sustainable Development II

Environmental Science and Technology: Sustainable Development II PDF Author: Yang Zeng
Publisher: Springer Nature
ISBN: 3031546849
Category :
Languages : en
Pages : 437

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Book Description


Investigation of Fundamental Processes Governing Secondary Organic Aerosol Formation in Laboratory Chambers

Investigation of Fundamental Processes Governing Secondary Organic Aerosol Formation in Laboratory Chambers PDF Author: Xuan Zhang
Publisher:
ISBN:
Category : Electronic dissertations
Languages : en
Pages : 562

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Book Description
Our understanding of the processes and mechanisms by which secondary organic aerosol (SOA) is formed is derived from laboratory chamber studies. In the atmosphere, SOA formation is primarily driven by progressive photooxidation of SOA precursors, coupled with their gas-particle partitioning. In the chamber environment, SOA-forming vapors undergo multiple chemical and physical processes that involve production and removal via gas-phase reactions; partitioning onto suspended particles vs. particles deposited on the chamber wall; and direct deposition on the chamber wall. The main focus of this dissertation is to characterize the interactions of organic vapors with suspended particles and the chamber wall and explore how these intertwined processes in laboratory chambers govern SOA formation and evolution. A Functional Group Oxidation Model (FGOM) that represents SOA formation and evolution in terms of the competition between functionalization and fragmentation, the extent of oxygen atom addition, and the change of volatility, is developed. The FGOM contains a set of parameters that are to be determined by fitting of the model to laboratory chamber data. The sensitivity of the model prediction to variation of the adjustable parameters allows one to assess the relative importance of various pathways involved in SOA formation. A critical aspect of the environmental chamber is the presence of the wall, which can induce deposition of SOA-forming vapors and promote heterogeneous reactions. An experimental protocol and model framework are first developed to constrain the vapor-wall interactions. By optimal fitting the model predictions to the observed wall-induced decay profiles of 25 oxidized organic compounds, the dominant parameter governing the extent of wall deposition of a compound is identified, i.e., wall accommodation coefficient. By correlating this parameter with the molecular properties of a compound via its volatility, the wall-induced deposition rate of an organic compound can be predicted based on its carbon and oxygen numbers in the molecule. Heterogeneous transformation of delta-hydroxycarbonyl, a major first-generation product from long-chain alkane photochemistry, is observed on the surface of particles and walls. The uniqueness of this reaction scheme is the production of substituted dihydrofuran, which is highly reactive towards ozone, OH, and NO3, thereby opening a reaction pathway that is not usually accessible to alkanes. A spectrum of highly-oxygenated products with carboxylic acid, ester, and ether functional groups is produced from the substituted dihydrofuran chemistry, thereby affecting the average oxidation state of the alkane-derived SOA. The vapor wall loss correction is applied to several chamber-derived SOA systems generated from both anthropogenic and biogenic sources. Experimental and modeling approaches are employed to constrain the partitioning behavior of SOA-forming vapors onto suspended particles vs. chamber walls. It is demonstrated that deposition of SOA-forming vapors to the chamber wall during photooxidation experiments can lead to substantial and systematic underestimation of SOA. Therefore, it is likely that a lack of proper accounting for vapor wall losses that suppress chamber-derived SOA yields contribute substantially to the underprediction of ambient SOA concentrations in atmospheric models.

The Chemistry and Biology of Volatiles

The Chemistry and Biology of Volatiles PDF Author: Andreas Herrmann
Publisher: John Wiley & Sons
ISBN: 1119956986
Category : Science
Languages : en
Pages : 408

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Book Description
"Coming to a conclusion, this wonderful, informative and very interesting book presents an excellent overview of small volatile organic compounds and their role in our life and environment. Really fascinating is the entirety of scientific disciplines which were addressed by this book." –Flavour and Fragrance Journal, 2011 "... this book deserves to be a well-used reference in the library of any laboratory specialising in VOC". –Chemistry World, 2011 Volatile compounds are molecules with a relatively low molecular weight allowing for an efficient evaporation into the air. They are found in many areas of our everyday-life: they are responsible for the communication between species such as plants, insects or mammals; they serve as flavours or fragrances in many food products or perfumed consumer articles; and they play an important role in atmospheric chemistry. This book takes an interdisciplinary approach to volatile molecules. Review-style introductions to the main topics in volatile chemistry and biology are provided by international experts, building into a broad overview of this fascinating field. Topics covered include: The structural variety of volatile compounds Biogeneration of volatiles Synthesis of natural and non-natural volatiles Analysis of volatiles Volatile compounds as semiochemicals in plant-plant or plant-insect interactions Volatiles in pest control Pheromones and the influence of volatiles on mammals Olfaction and human perception Volatiles as fragrances The generation of flavours and food aroma compounds Stabilisation and controlled release of volatiles The impact of volatiles on the environment and the atmosphere

Transport and Chemical Transformation in the Troposphere

Transport and Chemical Transformation in the Troposphere PDF Author: Pauline M. Midgley
Publisher: Springer Science & Business Media
ISBN: 3642567223
Category : Science
Languages : en
Pages : 306

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Book Description
The sixth EUROTRAC Symposium was held in Garmisch-Partenkirchen, th st Gennany from 27 - 31 March 2000. Some 375 scientists from 28 different countries (from the USA to Uzbekistan) gathered together and contributed to a lively week. Symposium 2000 was the second Symposium of the second phase, EUROTRAC- 2 which is EUREKA environmental project number 1489, and also the ftrst one organised by the new team at the International Scientiftc Secretariat (ISS). We stayed with the tried and tested EUROTRAC format, giving ample time for poster sessions as well as side meetings and workshops. The invited talks, over 35 in all, contributed breadth and depth. The Symposium had the focal points of "Shaping the Future" and "Scientiftc Research and Environmental Policy". The "Highlights from the Subprojects" were well represented by a series of talks and of course by the ca 300 posters. Guest poster contributions added to the spectrum of scientiftc coverage. An innovation for 2000 is the publication of these Proceedings in a book containing the extended abstracts of the lectures and a companion CD-ROM with the extended abstracts of the posters as well as the lectures. The availability of the Proceedings on a CD will enable us to distribute them more widely.