Sintering and Catalysis

Sintering and Catalysis PDF Author: G. Kuczynski
Publisher: Springer Science & Business Media
ISBN: 1468409344
Category : Technology & Engineering
Languages : en
Pages : 506

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Book Description
The proceedings of the 4th International Conference on Sin tering and Related Phenomena, contained in this volume, have been broadened in scope to include the phenomena of sintering and coa lescence of catalytic materials dispersed upon refractory oxides. For it has long been recognized within the circles of chemists and chemical engineers working in the field of catalysis that one of the chief causes of the decline in heterogeneous catalytic activity and/or selectivity is, indeed sintering, or perhaps using a better term, coalescence of the supported catalytic metal and compounds thereof. Essentially catalytic deactivation by sintering is now weIl recognized as Ostwald ripening; which of course is a phenome non familiar to scientists grappling with the problem of sintering of powder compacts. The 4th Conference at Notre Dame marks the first occasion at which scientists and engineers of each discipline were assembled in the same room to exchange views on these phenome na of mutual concern. In the wake of the Conference at Notre Dame, all parties acknowledged the synergistic benefit which issued from this exchange, both at the formal and informal level. All were persuaded that signal benefits will be realized by a continuation of this collab oration in the form of future sintering conferences in which both powder metallurgists and catalytic scientists and engineers would participate.

Sintering and Heterogeneous Catalysis

Sintering and Heterogeneous Catalysis PDF Author: G. Kuczynski
Publisher: Springer Science & Business Media
ISBN: 146132761X
Category : Technology & Engineering
Languages : en
Pages : 348

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Book Description
The Sixth International Conference on Sintering and Related Phenomena took place at the University of Notre Dame, Notre Dame, Indiana June 6-8, 1983. This conference was also the twentieth Conference on Ceramic Sciences organized yearly by a "confederation" of four institutions: North Carolina University at Raleigh, N.C., the University of California at Berkeley, CA, Alfred University at Alfred, NY and the University of Notre Dame, Notre Dame, IN. The papers presented at the last Notre Dame conference collect ed in this volume, reflect the progress in our understanding of the process of sintering achieved in the past four years. It seems that the analysis of the two particle models is finally extended to the analysis of the models of compacts. In these investigations strong emphasis is put on pore-grain boundar ies interaction which appear to be central to this problem. It is to be hoped that in the near future an adequate model of the compact will be developed which may serve as a useful basis of powder tech nology. Also, the effects of atmosphere on the sintering of ceramics after a long period of neglect, seem to attract the attention of more workers in the field.

Strong Metal-support Interactions

Strong Metal-support Interactions PDF Author: R. T. K. Baker
Publisher:
ISBN:
Category : Science
Languages : en
Pages : 258

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Book Description


Ultrathin Oxide Layers for Solar and Electrocatalytic Systems

Ultrathin Oxide Layers for Solar and Electrocatalytic Systems PDF Author: Heinz Frei
Publisher: Royal Society of Chemistry
ISBN: 1839163712
Category : Technology & Engineering
Languages : en
Pages : 321

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Book Description
Ultrathin metal oxide layers have emerged in recent years as a powerful approach for substantially enhancing the performance of photo, electro, or thermal catalytic systems for energy, in some cases even enabling the use of highly attractive materials previously found unsuitable. This development is due to the confluence of new synthetic preparation methods for ultrathin oxide layers and a more advanced understanding of interfacial phenomena on the nano and atomic scale. This book brings together the fundamentals and applications of ultrathin oxide layers while highlighting connections and future opportunities with the intent of accelerating the use of these materials and techniques for new and emerging applications of catalysis for energy. It comprehensively covers the state-of-the-art synthetic methods of ultrathin oxide layers, their structural and functional characterization, and the broad range of applications in the field of catalysis for energy. Edited by leaders in the field, and with contributions from global experts, this title will be of interest to graduate students and researchers across materials science and chemistry who are interested in ultrathin oxide layers and their applications in solar energy conversion, renewable energy, photocatalysis, electrocatalysis and protective coatings.

Nanoparticle Design and Characterization for Catalytic Applications in Sustainable Chemistry

Nanoparticle Design and Characterization for Catalytic Applications in Sustainable Chemistry PDF Author: Rafael Luque
Publisher: Royal Society of Chemistry
ISBN: 1788014901
Category : Science
Languages : en
Pages : 370

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Book Description
This book presents an introduction to the preparation and characterisation of nanomaterials and their design for specific catalytic applications.

Progress in Catalyst Deactivation

Progress in Catalyst Deactivation PDF Author: J.L. Figueiredo
Publisher: Springer Science & Business Media
ISBN: 940097597X
Category : Science
Languages : en
Pages : 398

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Book Description
Most catalysts used in the chemical and petrochemical indus tries are strongly affected by one or another form of deactivation, leading to poor performances and reduced life. The increasing num ber of scientific communications devoted to the subject in recent years, and culminating with an International Symposium held in Antwerp in October 1980, is a measure of the interest it arouses in both the industrial and academic communities. A stage has been reached whereby it was thought that a NATO Advanced Study Institute on "Catalyst Deactivation" might be fruit ful in establishing the state of the art and in stimulating a more systematic research on the phenomenon. Such a meeting was held ~n Lagos, Portugal, from 18 to 29 May 1981. The purpose of the Institute was to present and discuss in a didatic and systematic way the various processes that lead to cata lyst deactivation, namely coking, poisoning and solid state trans formations, and at the same time to promote the exchange of ideas and experiences among the participants, drawn from industry and uni versity. The lectures presented at the Institute are collected in this volume with the exception of Dr. L.L.Hegedus "Catalyst Poisoning", which has been previously published (Catalysis Reviews, Science md Engineering, 23, 377-476, 1981).

Catalysis

Catalysis PDF Author: John R. Anderson
Publisher: Springer Science & Business Media
ISBN: 3642932789
Category : Science
Languages : en
Pages : 270

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Book Description
Catalytic oxidation processes are bf central importance to a substantial part of large-scale chemical industry. Indeed, this area of industrial catalysis has an extremely long history which stretches back well into the last century. The development and growth of catalytic oxi dation processes for the manufacture of commodities such as sulfuric acid and nitric acid can be viewed as indicators for the growth of the early and middle years of the entire inorganic chemical industry, and in an analogous fashion the manufacture of products such as phthalic anhydride, maleic anhydride and ethylene oxide has been central to the development of an organic chemical industry. We should all be able" to learn from history, and present-day scientists and technologists will find considerable benefit in following the account of the historical development of catalytic oxidation processes presented in Chapter I by Drs. G. Chinchen, P. Davies and R. J. Sampson. Alkenes are important intermediates in many processes in organic chemical industry. Being mostly petroleum derived, the alkene availability pattern does not necessar ily match consumption requirements and an alkene inter conversion process such as metathesis is clearly of in dustrial importance. In fact alkene metathesis, in addi tion to its industrial significance, poses an interesting mechanistic problem. upon which considerable effort has been expended in recent years and which is now fairly well understood.

Introduction to Catalysis and Industrial Catalytic Processes

Introduction to Catalysis and Industrial Catalytic Processes PDF Author: Robert J. Farrauto
Publisher: John Wiley & Sons
ISBN: 111845460X
Category : Technology & Engineering
Languages : en
Pages : 340

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Book Description
Introduces major catalytic processes including products from the petroleum, chemical, environmental and alternative energy industries Provides an easy to read description of the fundamentals of catalysis and some of the major catalytic industrial processes used today Offers a rationale for process designs based on kinetics and thermodynamics Alternative energy topics include the hydrogen economy, fuels cells, bio catalytic (enzymes) production of ethanol fuel from corn and biodiesel from vegetable oils Problem sets of included with answers available to faculty who use the book Review: "In less than 300 pages, it serves as an excellent introduction to these subjects whether for advanced students or those seeking to learn more about these subjects on their own time...Particularly useful are the succinct summaries throughout the book...excellent detail in the table of contents, a detailed index, key references at the end of each chapter, and challenging classroom questions..." (GlobalCatalysis.com, May 2016)

Deactivation and Regeneration of Zeolite Catalysts

Deactivation and Regeneration of Zeolite Catalysts PDF Author: M. Guisnet
Publisher: World Scientific
ISBN: 1848166370
Category : Science
Languages : en
Pages : 359

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Book Description
In chemical processes, the progressive deactivation of solid catalysts is a major economic concern and mastering their stability has become as essential as controlling their activity and selectivity. For these reasons, there is a strong motivation to understand the mechanisms leading to any loss in activity and/or selectivity and to find out the efficient preventive measures and regenerative solutions that open the way towards cheaper and cleaner processes. This book covers in a comprehensive way both the fundamental and applied aspects of solid catalyst deactivation and encompasses the state-of-the-art in the field of reactions catalyzed by zeolites. This particular choice is justified by the widespread use of molecular sieves in refining, petrochemicals and organic chemicals synthesis processes, by the large variety in the nature of their active sites (acid, base, acid-base, redox, bifunctional) and especially by their peculiar features, in terms of crystallinity, structural order and textural properties, which make them ideal models for heterogeneous catalysis. The aim of this book is to be a critical review in the field of zeolite deactivation and regeneration, by collecting a series of contributions by experts in the field which describe the factors, explain the techniques to study the causes and suggest methods to prevent (or limit) catalyst deactivation. At the same time, an anthology of commercial processes and exemplar cases provides the reader with theoretical insights and practical hints on the deactivation mechanisms and draws attention to the key role played by the loss of activity on process design and industrial practice.

Hydrogen Effects in Catalysis

Hydrogen Effects in Catalysis PDF Author: Paal
Publisher: CRC Press
ISBN: 9780824777746
Category : Science
Languages : en
Pages : 778

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Book Description
This book covers hydrogen effects in catalysis in the broadest sense, from surface science to industrial applications. It draws the attention of the catalysis community to the importance of the phenomena of hydrogen effects both in the science and technology of catalysis.