Simultaneous Infrared and Kinetic Studies of the Palladium Catalyzed Carbon Monoxide Oxidation PDF Download
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Author: Robert Landau Goldsmith
Publisher:
ISBN:
Category : Adsorption
Languages : en
Pages : 408
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Author: Robert Landau Goldsmith
Publisher:
ISBN:
Category : Adsorption
Languages : en
Pages : 408
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Author: Ronald Alan Sills
Publisher:
ISBN:
Category : Oxidation
Languages : en
Pages : 482
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Author: Kwang-Ho Park
Publisher:
ISBN:
Category : Carbon monoxide
Languages : en
Pages : 0
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Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 6
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Book Description
The oxidation of carbon monoxide on a Pd(100) single-crystal catalyst was studied using an elevated-pressure IR cell/ultrahigh vacuum surface analysis system. The kinetics of the reaction was followed by monitoring the total pressure change during the course of the reaction. Simultaneously, the surface concentration of adsorbed CO was measured using IR reflection absorption spectroscopy. An activation energy of 29.4 + or - 0.3 kcal/mol was found between 500 and 575 K at a total pressure of 1.50 Torr and CO/O2 = 2. The IR data obtained under reaction conditions show the CO coverage to vary between 0.45 and 0.55 monolayers (ML). For this coverage regime, the CO heat of adsorption was determined to be 29 + or - kcal/mol, corresponding closely to the apparent activation energy. Between 0.5 and 10.0 Torr, negative first-order CO and positive first-order oxygen pressure dependencies were measured, yielding a zero-order total pressure dependence of the reaction rate. No change in CO coverage was observed with a change in the oxygen pressure, while the CO coverage increased from 0.50 ML at P sub co = 0.50 Torr to 0.55 ML at P sub co = 8.0 Torr.
Author: Jack Warren London
Publisher:
ISBN:
Category :
Languages : en
Pages : 296
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Author: Massachusetts Institute of Technology
Publisher:
ISBN:
Category : Dissertations, Academic
Languages : en
Pages : 358
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Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 12
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Author: John E. Turner
Publisher:
ISBN:
Category : Carbon monoxide
Languages : en
Pages : 334
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Author: Massachusetts Institute of Technology. Center for Materials Science and Engineering
Publisher:
ISBN:
Category : Materials
Languages : en
Pages : 1092
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Author: P. Henry
Publisher: Springer Science & Business Media
ISBN: 9789027709868
Category : Science
Languages : en
Pages : 458
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Book Description
The field of organometallic chemistry has emerged over the last twenty-five years or so to become one of the most important areas of chemistry, and there are no signs of abatement in the intense current interest in the subject, particularly in terms of its proven and potential application in catalytic reactions involving hydrocarbons. The development of the organometallic/ catalysis area has resulted in no small way from many contributions from researchers investigating palladium systems. Even to the well-initiated, there seems a bewildering and diverse variety of organic reactions that are promoted by palladium(II) salts and complexes. Such homogeneous reactions include oxidative and nonoxidative coupling of substrates such as olefins, dienes, acetylenes, and aromatics; and various isomerization, disproportionation, hydrogenation, dehydrogenation, car bonylation and decarbonylation reactions, as well as reactions involving formation of bonds between carbon and halogen, nitrogen, sulfur, and silicon. The books by Peter M. Maitlis - The Organic Chemistry of Palladium, Volumes I, II, Academic Press, 1971 - serve to classify and identify the wide variety of reactions, and access to the vast literature is available through these volumes and more recent reviews, including those of J. Tsuji [Accounts Chem. Res. , 6, 8 (1973); Adv. in Organometal. , 17, 141 (1979)], R. F. Heck [Adv. in Catat. , 26, 323 (1977)], and ones by Henry [Accounts Chem. Res. , 6, 16 (1973); Adv. in Organometal. , 13, 363 (1975)]. F. R. Hartley's book - The Chemistry of Platinum and Palladium, App!. Sci. Pub!.
