Relative Apparent Molal Heat Contents and Related Thermodynamic Properties of Some Rare Earth Nitrates and Perchlorates at 25°C PDF Download
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Author: John Lucas Derer
Publisher:
ISBN:
Category :
Languages : en
Pages : 498
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Author: John Lucas Derer
Publisher:
ISBN:
Category :
Languages : en
Pages : 498
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Book Description
Author:
Publisher:
ISBN:
Category :
Languages : en
Pages :
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Author: Robert Eugene Eberts
Publisher:
ISBN:
Category : Heat of solution
Languages : en
Pages : 162
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Author: David Andrew Csejka
Publisher:
ISBN:
Category : Heat of solution
Languages : en
Pages : 148
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Author: James LeRoy Baker
Publisher:
ISBN:
Category : Heat of solution
Languages : en
Pages : 256
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Author: George William Pepple
Publisher:
ISBN:
Category :
Languages : en
Pages : 122
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Author: George William Pepple
Publisher:
ISBN:
Category : Heat of solution
Languages : en
Pages : 244
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Author: United States. Energy Research and Development Administration
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ISBN:
Category : Medicine
Languages : en
Pages :
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Author:
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Category :
Languages : en
Pages : 47
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Relative densities and relative massic heat capacities have been measured for acidified solutions (prepared at University of Lethbridge) of Y(NO3)3(aq), Pr(NO3)3(aq), and Gd(NO3)3(aq) at T = (288.15, 298.15, 313.15, and 328.15) K and p = 0.1 MPa. In addition, relative densities and massic heat capacities have been measured at the same temperatures and pressure for Y(NO3)3(aq) and Ho(NO3)3(aq) solutions which were supplied from the Lawrence Livermore National Laboratory (LLNL) (n.b. measurements at T = 328.15 K for Ho(NO3)3(aq) were not performed due to the limited volume of solution available). Apparent molar volumes and apparent molar heat capacities for the aqueous salt solutions have been calculated from the experimental apparent molar properties of the acidified salt solutions using Young's Rule whereas the apparent molar properties of the LLNL solutions were calculated directly from the measured densities and massic heat capacities. The two sets of data for the Y(NO3)3(aq) systems provide a check of the internal consistency of the Young's Rule approach we have utilized. The concentration dependences of the apparent molar volumes and heat capacities of the aqueous salt solutions have been modeled at each investigated temperature using the Pitzer ion interaction equations to yield apparent molar properties at infinite dilution. Complex formation within the aqueous rare earth nitrate systems is discussed and is qualitatively explored by probing the concentration dependence of apparent molar volumes and heat capacities. It is also shown that in spite of the complex formation within the aqueous rare earth nitrate systems there remains a high degree of self-consistency between the apparent molar volumes and heat capacities at infinite dilution reported in this manuscript and those previously reported for aqueous rare earth perchlorate salt systems.
Author: John Philip Walters
Publisher:
ISBN:
Category : Heat of solution
Languages : en
Pages : 186
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