Author: Glenn A. Burney
Publisher:
ISBN:
Category : Extraction (Chemistry)
Languages : en
Pages : 20

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Author: E. R. Irish
Publisher:
ISBN:
Category : Reactor fuel reprocessing
Languages : en
Pages : 72

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Author:
Publisher:
ISBN:
Category :
Languages : en
Pages :

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Labcratory data which indicate that the recovery of Pu and U and decontamination from fission products are feasible in a solvent extraction process using tributyl phosphate are given. The procedure consists of extracting Pu(IV) and U with 15% TBP--85% Varsol using 5.0 N HNO/sub 3/ as a salting agent. (J.R.D.).

Author: E. R. Irish
Publisher:
ISBN:
Category : Fission products
Languages : en
Pages : 18

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The Purex process is a continuous solvent extraction process for irradiated uranium for the separation and decontamination of plutonium and uranium from each other and from fission products.

Author:
Publisher:
ISBN:
Category :
Languages : en
Pages :

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The Purex process is the solvent extraction system that uses tributyl phosphate as the extractant for separating uranium and plutonium from irradiated reactor fuels. Since the first flowsheet was proposed at Oak Ridge National Laboratory in 1950, the process has endured for over 30 years with only minor modifications. The spread of the technology was rapid, and worldwide use or research on Purex-type processes was reported by the time of the 1955 Geneva Conference. The overall performance of the process has been so good that there are no serious contenders for replacing it soon. This paper presents: process description; equipment performance (mixer-settlers, pulse columns, rapid contactors); fission product decontamination; solvent effects (solvent degradation products); and partitioning of uranium and plutonium.

Author: R. G. Geier
Publisher:
ISBN:
Category : Extraction (Chemistry)
Languages : en
Pages : 70

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Author: Kenneth L Nash
Publisher: Elsevier
ISBN: 0857092278
Category : Technology & Engineering
Languages : en
Pages : 513

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Book Description
Advanced separations technology is key to closing the nuclear fuel cycle and relieving future generations from the burden of radioactive waste produced by the nuclear power industry. Nuclear fuel reprocessing techniques not only allow for recycling of useful fuel components for further power generation, but by also separating out the actinides, lanthanides and other fission products produced by the nuclear reaction, the residual radioactive waste can be minimised. Indeed, the future of the industry relies on the advancement of separation and transmutation technology to ensure environmental protection, criticality-safety and non-proliferation (i.e., security) of radioactive materials by reducing their long-term radiological hazard. Advanced separation techniques for nuclear fuel reprocessing and radioactive waste treatment provides a comprehensive and timely reference on nuclear fuel reprocessing and radioactive waste treatment. Part one covers the fundamental chemistry, engineering and safety of radioactive materials separations processes in the nuclear fuel cycle, including coverage of advanced aqueous separations engineering, as well as on-line monitoring for process control and safeguards technology. Part two critically reviews the development and application of separation and extraction processes for nuclear fuel reprocessing and radioactive waste treatment. The section includes discussions of advanced PUREX processes, the UREX+ concept, fission product separations, and combined systems for simultaneous radionuclide extraction. Part three details emerging and innovative treatment techniques, initially reviewing pyrochemical processes and engineering, highly selective compounds for solvent extraction, and developments in partitioning and transmutation processes that aim to close the nuclear fuel cycle. The book concludes with other advanced techniques such as solid phase extraction, supercritical fluid and ionic liquid extraction, and biological treatment processes. With its distinguished international team of contributors, Advanced separation techniques for nuclear fuel reprocessing and radioactive waste treatment is a standard reference for all nuclear waste management and nuclear safety professionals, radiochemists, academics and researchers in this field. A comprehensive and timely reference on nuclear fuel reprocessing and radioactive waste treatment Details emerging and innovative treatment techniques, reviewing pyrochemical processes and engineering, as well as highly selective compounds for solvent extraction Discusses the development and application of separation and extraction processes for nuclear fuel reprocessing and radioactive waste treatment

Author: Burton P. Dennis
Publisher:
ISBN:
Category : Extraction (Chemistry)
Languages : en
Pages : 36

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Book Description
Forty-nine hydrocarbon products were evaluated in the laboratory in a search for a highly stable diluent for the organic extractant used in a radiochemical separations plant. The formation of zirconium ligands during chemical and radiolytic degradation increased with boiling point for isoparaffinic products but was approximately constant for n-paraffins. Of those materials that met the local flash point specification, the n-paraffins were superior.

Author:
Publisher:
ISBN:
Category :
Languages : en
Pages :

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Book Description
The following aspects of the Purex Process are discussed: head end dissolution, first solvent extraction cycle, second plutonium solvent extraction cycle, second uranium solvent extraction cycle, solvent recovery systems, primary recovery column for high activity waste, low activity waste, laboratory waste evaporation, vessel vent system, airflow and filtration, acid recovery unit, fume recovery, and discharges to seepage basin. (LK).

Author: Henry Pollock
Publisher:
ISBN:
Category : Extraction (Chemistry)
Languages : en
Pages : 12

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