Polymer Solutions, Blends, and Interfaces

Polymer Solutions, Blends, and Interfaces PDF Author: I. Noda
Publisher: Elsevier
ISBN: 0444600612
Category : Science
Languages : en
Pages : 498

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Book Description
The behaviour of polymers in multi-component and multiphase systems such as solutions, blends and interfaces derived from both natural and synthetic sources and the subsequent influence of this on their physical properties is the theme of this book. Important new material on multiphase polymer systems such as block copolymers and liquid crystalline polymers is provided, and the solution and surface properties of enzymes and surface active polymers is described both theoretically and experimentally. The application of theory to the development of new cellulosic materials is particularly noteworthy. The relationship between end-use properties, such as adhesion, wetting, and colloidal stability, and molecular structure at the interface is addressed. Examples include the capillary pressure of nylon microporous membranes, a new technique for characterizing the adhesion between incompatible polymers, and the influence of the glass transition temperature at the fiber/matrix interface on interfacial shear strength. Characterization of polymer films, both electrochemically and via optical techniques is covered and the interactions of amphiphilic ions with polyacrylate polymer are described. The final two chapters introduce the topic of enzyme mobility at an interface and show how this may affect their role as biological catalysts.

Polymer Solutions, Blends, and Interfaces

Polymer Solutions, Blends, and Interfaces PDF Author: I. Noda
Publisher: Elsevier
ISBN: 0444600612
Category : Science
Languages : en
Pages : 498

Get Book Here

Book Description
The behaviour of polymers in multi-component and multiphase systems such as solutions, blends and interfaces derived from both natural and synthetic sources and the subsequent influence of this on their physical properties is the theme of this book. Important new material on multiphase polymer systems such as block copolymers and liquid crystalline polymers is provided, and the solution and surface properties of enzymes and surface active polymers is described both theoretically and experimentally. The application of theory to the development of new cellulosic materials is particularly noteworthy. The relationship between end-use properties, such as adhesion, wetting, and colloidal stability, and molecular structure at the interface is addressed. Examples include the capillary pressure of nylon microporous membranes, a new technique for characterizing the adhesion between incompatible polymers, and the influence of the glass transition temperature at the fiber/matrix interface on interfacial shear strength. Characterization of polymer films, both electrochemically and via optical techniques is covered and the interactions of amphiphilic ions with polyacrylate polymer are described. The final two chapters introduce the topic of enzyme mobility at an interface and show how this may affect their role as biological catalysts.

Characterization of Polymer Blends

Characterization of Polymer Blends PDF Author: Sabu Thomas
Publisher: John Wiley & Sons
ISBN: 3527331530
Category : Science
Languages : en
Pages : 972

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Book Description
Filling the gap for a reference dedicated to the characterization of polymer blends and their micro and nano morphologies, this book provides comprehensive, systematic coverage in a one-stop, two-volume resource for all those working in the field. Leading researchers from industry and academia, as well as from government and private research institutions around the world summarize recent technical advances in chapters devoted to their individual contributions. In so doing, they examine a wide range of modern characterization techniques, from microscopy and spectroscopy to diffraction, thermal analysis, rheology, mechanical measurements and chromatography. These methods are compared with each other to assist in determining the best solution for both fundamental and applied problems, paying attention to the characterization of nanoscale miscibility and interfaces, both in blends involving copolymers and in immiscible blends. The thermodynamics, miscibility, phase separation, morphology and interfaces in polymer blends are also discussed in light of new insights involving the nanoscopic scale. Finally, the authors detail the processing-morphology-property relationships of polymer blends, as well as the influence of processing on the generation of micro and nano morphologies, and the dependence of these morphologies on the properties of blends. Hot topics such as compatibilization through nanoparticles, miscibility of new biopolymers and nanoscale investigations of interfaces in blends are also addressed. With its application-oriented approach, handpicked selection of topics and expert contributors, this is an outstanding survey for anyone involved in the field of polymer blends for advanced technologies.

Polymer Blends Volume 1

Polymer Blends Volume 1 PDF Author: Donald R Paul
Publisher: Elsevier
ISBN: 0323138896
Category : Technology & Engineering
Languages : en
Pages : 520

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Book Description
Polymer Blends, Volume 1 highlights the importance of polymer blends as a major new branch of macromolecular science. Topics range from polymer-polymer compatibility and the statistical thermodynamics of polymer blends to the phase separation behavior of polymer-polymer mixtures, transport phenomena in polymer blends, and mechanical properties of multiphase polymer blends. The optical behavior, solid state transition behavior, and rheology of polymer blends are also discussed. This book is organized into 10 chapters and begins with an overview of polymer blends, with emphasis on terminology and the effect of molecular weight on the thermodynamics of polymer blends as well as phase equilibria and transitions. The discussion then turns to the miscibility of homopolymers and copolymers, in bulk and in solution, from the experimental and theoretical viewpoints. The chapters that follow explore the statistical thermodynamics of polymer blends, paying particular attention to the Flory and lattice fluid theories, along with the phase relationship in polymer mixtures. The interfacial energy, structure, and adhesion between polymers in relation to the properties of polymer blends are considered. The final chapter examines the phenomena of low molecular weight penetrant transport. Currently accepted models for unsteady-state and steady-state permeation of polymeric materials are presented. A discussion of unsteady-state absorption and desorption behavior observed in a variety of polymer blends complements the treatment of permeation behavior. This book is intended to provide academic and industrial research scientists and technologists with a broad background in current principles and practice concerning mixed polymer systems.

Polymer Surfaces and Interfaces

Polymer Surfaces and Interfaces PDF Author: Manfred Stamm
Publisher: Springer
ISBN: 9783642093111
Category : Technology & Engineering
Languages : en
Pages : 0

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Book Description
In what is an extremely practical and applicable new work, experts provide concise explanations, with examples and illustrations, of the key techniques in this important field. In each case, after basic principles have been reviewed, applications of the experimental techniques are discussed and illustrated with specific examples. Scientists and engineers in research and development will benefit from an application-oriented book that helps them to find solutions to both fundamental and applied problems. They will know that the surfaces and interfaces of polymers play an important role in most of the application areas of polymers, from moulds, foils, and composites, to biomaterials and applications in micro- and nanotechnology.

Polymer Interface and Adhesion

Polymer Interface and Adhesion PDF Author: Wu
Publisher: CRC Press
ISBN: 9780824715335
Category : Technology & Engineering
Languages : en
Pages : 654

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Book Description
Poly mer Interface and Adhesion provides the critical basis for further advancement in thisfield. Combining the principles of interfacial science, rheology, stress analysis, and fracturemechanics, the book teaches a new approach to the analysis of long standing problemssuch as: how is the interface formed; what are its physical and mechanical properties;and how does the interface modify the stress field and fracture strength of the material.The book offers many outstanding features, including extensive listings of pertinent references, exhaustive tabulations of the interfacial properties of polymers, critical reviews ofthe many conflicting theories, and complete discussions of coupling agents, adhesion promotion, and surface modifications. Emphasis is placed on physical concepts and mechanisms, using clear, understandable mathematics.Polymer Interface and Adhesion promotes a more thorough understanding of the physical, mechanical, and adhesive properties of multiphase, polymer systems. Polymer scientistsand engineers, surface chemists, materials scientists, rheologists, as well as chemical andmechanical engineers interested in the research, development or industrial applications ofpolymers, plastics, fibers, coatings, adhesives, and composites need this important newsource b

Polymers and Other Advanced Materials

Polymers and Other Advanced Materials PDF Author: Ting Joo Fai
Publisher: Springer Science & Business Media
ISBN: 1489905022
Category : Science
Languages : en
Pages : 770

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Book Description
Proceedings of the Third International Conference on Frontiers of Polymers and Advanced Materials held in Kuala Lumpur, Malaysia, January 16-20, 1995

Polymer Blends Handbook

Polymer Blends Handbook PDF Author: L. A. Utracki
Publisher:
ISBN: 9789400760653
Category : Polymer engineering
Languages : en
Pages : 1800

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Book Description
Written by an international group of highly respected contributors, this fundamental reference work covers all aspects of polymer blends: science, engineering, technology and applications.

Modern Polymer Spectroscopy

Modern Polymer Spectroscopy PDF Author: Giuseppe Zerbi
Publisher: John Wiley & Sons
ISBN: 3527613935
Category : Science
Languages : en
Pages : 303

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Book Description
Modern Polymer Spectroscopy provides a 'guided tour' to the state of the art in polymer analysis by vibrational spectroscopy. Five renowned experts describe new experimental and theoretical techniques. Areas of focus include: - two-dimensional infrared spectroscopy - segmental mobility of liquid crystalline polymers under external fields - dynamics and structure of polymers with chemical and structural disorder - spectra of polyconjugated conducting polymers - theoretical calculations on biopolymers. Readers learn experimental techniques and theoretical tools essential for obtaining more valuable information from their vibrational spectra, in order too solve problems that would otherwise be impossible. An essential reference for all professionals who need to keep abreast at the latest developments in the field, graduate students in polymer science, material science and the biosciences using spectroscopic techniques will profit from the wealth of information provided in this state-of-the-art guide.

Preparation and Properties of Monomers, Polymers and Composite Materials

Preparation and Properties of Monomers, Polymers and Composite Materials PDF Author: Antonio Ballada
Publisher: Nova Publishers
ISBN: 9781600215575
Category : Science
Languages : en
Pages : 228

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Book Description
Preface; Enhancement of miscibility in multi-component solutions on the basis of three polymers and common solvents; Reinforcement of the Interface in Drawn Polymer Blends PS/PA-12; Quantum chemical calculation linear olefins and not conjugate diolefins; Technology computers search of new more effective catalysts cationic polymerisation olefins; Quantum chemical calculation and an estimation of acid force linear and ramified connected diens; Magnetic rectal suppositories for medical application: Investigation of their physical and chemical properties; Studying of a magnetic resonance in contrasting agents on the basis of biodecomposed magnetic fluids; Investigation of Micellisation at Non-ionic Surfactants in their solutions; Association of molecules and formation of micelles in solutions ionic surfactants; The interaction of surfactants with Ion Polymeric Sorbents; How the structure of sulphuryl amides influences the light stabilising properties; Of complex aerohydrodynamic research and the effectiveness of arresting dispersed particles for barbotage-rotation; The mechanism of selective oxidation of ethylbenzene with dioxygen into phenylethylhydroperoxide at catalysis by Fe(III)(acac)3, activated with additives of 18-crown-6 as ligand-modifier; Enhanced photo and thermal oxidative stability of charge-transfer complexes of conjugated polymers; Preparation and investigation of physical and chemical properties of ionic magnetic fluids on the basis of cobalt ferrite; Immunomagnetic separation of human hematopoietic cells: Physical -- chemical bases and medical -- biologic investigation; Emulsion polymerisation of (meth)acrylates: Characteristics of kinetics and mechanism; Behaviour of composite materials under micro-organisms of soil; New technologies for fast liquid-phase chemical processes; Index.

Polymer Blends

Polymer Blends PDF Author: D.R. Paul
Publisher: Elsevier
ISBN: 0323149774
Category : Technology & Engineering
Languages : en
Pages : 454

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Book Description
Polymer Blends, Volume 2 aims to show the importance of mixed polymer systems as a major branch of macromolecular science and provides a broad background of principles and practices in this field. Starting from where the first volume left off, the book covers topics in the area of polymer blends in Chapters 11-23. Areas of coverage include interpenetrating polymer networks; interfacial agents for polymer blends; rubber modification of plastics; fracture phenomena; coextruded multilayer polymer films and sheets; polymeric plasticizers; and polyolefin blends and their applications. The book is recommended for scientists, technologists, and engineers in the academe, research, and related industry, especially those who wish to be updated with its advances as a science.