Thermodynamics of Polymer Blends, Volume I PDF Download
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Author: Anatoly E. Nesterov
Publisher: CRC Press
ISBN: 1000717666
Category : Science
Languages : en
Pages : 465
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Book Description
Thermodynamics is an indispensable tool for developing a large and growing fraction of new polymers and polymer blends. These two volumes show the researcher how thermodynamics can be used to rank polymer pairs in order of immiscibility, including the search for suitable chemical structure of compatibilizers. Because of the great current commercial interest in this most dynamic sector of the polymer industry, there is high interest in studying their physical and mechanical properties, their structures, and the processes of their formation and manufacture. These Books are dedicated to Analysis of the Thermodynamics of Polymer Blends. Thermodynamic behavior of blends determines the compatibility of the components, their morphological features, rheological behavior, and microphase structures. As a result, the most important physical and mechanical characteristics of blends can be identified. The information in these two volumes will be useful to all those involved in polymer research, development, analysis and advanced process engineering.
Author: Anatoly E. Nesterov
Publisher: CRC Press
ISBN: 1000717666
Category : Science
Languages : en
Pages : 465
Get Book Here
Book Description
Thermodynamics is an indispensable tool for developing a large and growing fraction of new polymers and polymer blends. These two volumes show the researcher how thermodynamics can be used to rank polymer pairs in order of immiscibility, including the search for suitable chemical structure of compatibilizers. Because of the great current commercial interest in this most dynamic sector of the polymer industry, there is high interest in studying their physical and mechanical properties, their structures, and the processes of their formation and manufacture. These Books are dedicated to Analysis of the Thermodynamics of Polymer Blends. Thermodynamic behavior of blends determines the compatibility of the components, their morphological features, rheological behavior, and microphase structures. As a result, the most important physical and mechanical characteristics of blends can be identified. The information in these two volumes will be useful to all those involved in polymer research, development, analysis and advanced process engineering.
Author: Donald R Paul
Publisher: Elsevier
ISBN: 0323138896
Category : Technology & Engineering
Languages : en
Pages : 520
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Book Description
Polymer Blends, Volume 1 highlights the importance of polymer blends as a major new branch of macromolecular science. Topics range from polymer-polymer compatibility and the statistical thermodynamics of polymer blends to the phase separation behavior of polymer-polymer mixtures, transport phenomena in polymer blends, and mechanical properties of multiphase polymer blends. The optical behavior, solid state transition behavior, and rheology of polymer blends are also discussed. This book is organized into 10 chapters and begins with an overview of polymer blends, with emphasis on terminology and the effect of molecular weight on the thermodynamics of polymer blends as well as phase equilibria and transitions. The discussion then turns to the miscibility of homopolymers and copolymers, in bulk and in solution, from the experimental and theoretical viewpoints. The chapters that follow explore the statistical thermodynamics of polymer blends, paying particular attention to the Flory and lattice fluid theories, along with the phase relationship in polymer mixtures. The interfacial energy, structure, and adhesion between polymers in relation to the properties of polymer blends are considered. The final chapter examines the phenomena of low molecular weight penetrant transport. Currently accepted models for unsteady-state and steady-state permeation of polymeric materials are presented. A discussion of unsteady-state absorption and desorption behavior observed in a variety of polymer blends complements the treatment of permeation behavior. This book is intended to provide academic and industrial research scientists and technologists with a broad background in current principles and practice concerning mixed polymer systems.
Author: NicholasP. Cheremisinoff
Publisher: Routledge
ISBN: 1351423509
Category : Science
Languages : en
Pages : 456
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Book Description
Addressing the two major unit operations-mixing and extrusion-fundamental toprocessing elastomers and plastic materials, this reference summarizes design equationsthat can be employed effectively in scaling up product performance parameters, andcontains a thorough survey of rheological principles. In addition, the book provides awealth of practical information, relating molecular and compositional properties ofpolymers to processing characteristics and end-use properties so that engineers can selectpolymers suitable for specific equipment as well as products.Polymer Mixing and Extrusion Technology examines viscometric techniquesand demonstrates their importance to product quality assurance ... reviews design-relatedliterature/correlations and calculation procedures for mixing and extrusion ... definesneeds and precision standards for setting up a polymer processing laboratory so thatproduct quality control can be implemented in physical testing and processing research.. . plus more.Illustrated with over 200 diagrams, tables, and photographs that facilitate readers'understanding of the processes, Polymer Mixing and Extrusion Technology isan authoritative source for plastics, polymer, and chemical engineers, manufacturers ofplastics processing equipment, and advanced undergraduate and graduate students in thesedisciplines.
Author: Michael M. Coleman
Publisher: CRC Press
ISBN: 9780877628231
Category : Technology & Engineering
Languages : en
Pages : 530
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Book Description
This book with software provides powerful tools for the analysis, prediction and creation of new polymer blends, an area of significant commercial potential. The R&D approaches and methods described in the book have attracted the interest of polymer R&D leaders in industry, and have been put into use in several major chemical companies. The companion set of computer programs speeds and facilitates work in this area. FROM THE AUTHORS' PREFACE: During the 1980's a steadily increasing number of compatible systems [polymer blends] have been reported. We believe that miscible mixtures will prove to be fairly common and the purpose of this book is to explore the circumstances in which single phase materials can be obtained. We will also describe a model for the phase behavior of these mixtures which we believe to have a predictive value, or be used as a practical guide to polymer miscibility. Our approach is based on the use of association models which have until recently been largely ignored in treating hydrogen bonding in polymer mixtures. They have most frequently been applied to mixtures of alcohols with simple hydrocarbons, where the equilibrium constants used to describe association have most frequently been determined by a fit to thermodynamic data (e.g., vapor pressures, heat of mixing). In our work we have sought to, first, adapt this approach to a description of the phase behavior of polymer mixtures; second, develop spectroscopic methods that provide an independent measurement of the equilibrium constants. Our purpose in this book is to explore and describe this approach and illustrate its broad utility. We address two overlapping yet different audiences. One would be primarily interested in the broad nature of this approach and the practical applications of a simple model. The second would be more interested in the derivations of the equations and some of the fundamental aspects of the spectroscopy of these systems. Accordingly this book is in the form of a sandwich. We begin with a brief introduction to theories of mixing and the phase behavior of polymeric mixtures, followed by a practical guide to polymer miscibility. This chapter also serves to identify the types of systems in which, by copolymerization or other means, one might introduce the appropriate hydrogen bonding functional groups and obtain a miscible system. The [main substance] of this book is in [the] chapters where fundamental aspects of hydrogen bonds, spectroscopy and the application of association models are described. We also offer [separately] computer programs that calculate and display many of the important quantities described in this book (e.g., the stoichiometry of hydrogen bonding and its relationship to infrared measurements, phase behavior, etc.). In our view one can obtain a good feel for the miscibility of many systems with these programs.
Author: Ajitha A. R
Publisher: Elsevier
ISBN: 0128162880
Category : Technology & Engineering
Languages : en
Pages : 642
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Book Description
Compatibilization of Polymer Blends: Micro and Nano Scale Phase Morphologies, Interphase Characterization and Properties offers a comprehensive approach to the use of compatibilizers in polymer blends, examining both fundamental and advanced knowledge in the field. The book begins by introducing polymer blends, describing thermodynamics, miscibility, and phase separation, and explaining the main concepts of compatibilization. Other sections cover theoretical approaches for nearly compatible blends, incompatible blends, nanofillers, physical compatibilization, reactive compatibilization, morphological and structural characterization, and physico-mechanical characterization. Finally, key application areas are covered, including biomedical applications, packaging and automobile engineering. While this book will be a highly valuable reference source for academics, researchers and postgraduate students interested in polymer blends, it will also be ideal for anyone involved in the fields of polymer science, polymer chemistry, polymer physics, materials science, scientists, R&D professionals, and engineers in involved in the development or engineering of polymer products. - Offers detailed and systematic coverage of essential and advanced topics relating to the compatibilization of polymer blends - Presents a critical analysis of the effect of compatibilization on morphology and thermal, mechanical, electrical and viscoelastic properties of polymer blends - Draws on novel studies and state-of-the-art research, discussing the latest issues and developments
Author: NicholasP. Cheremisinoff
Publisher: Routledge
ISBN: 1351423495
Category : Science
Languages : en
Pages : 472
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Book Description
Addressing the two major unit operations-mixing and extrusion-fundamental toprocessing elastomers and plastic materials, this reference summarizes design equationsthat can be employed effectively in scaling up product performance parameters, andcontains a thorough survey of rheological principles. In addition, the book provides awealth of practical information, relating molecular and compositional properties ofpolymers to processing characteristics and end-use properties so that engineers can selectpolymers suitable for specific equipment as well as products.Polymer Mixing and Extrusion Technology examines viscometric techniquesand demonstrates their importance to product quality assurance ... reviews design-relatedliterature/correlations and calculation procedures for mixing and extrusion ... definesneeds and precision standards for setting up a polymer processing laboratory so thatproduct quality control can be implemented in physical testing and processing research.. . plus more.Illustrated with over 200 diagrams, tables, and photographs that facilitate readers'understanding of the processes, Polymer Mixing and Extrusion Technology isan authoritative source for plastics, polymer, and chemical engineers, manufacturers ofplastics processing equipment, and advanced undergraduate and graduate students in thesedisciplines.
Author: Karl Freed
Publisher: Springer Science & Business Media
ISBN: 9783540256809
Category : Technology & Engineering
Languages : en
Pages : 224
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Book Description
Author: A. K. Kulshreshtha
Publisher: iSmithers Rapra Publishing
ISBN: 9781859572788
Category : Technology & Engineering
Languages : en
Pages : 448
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Book Description
Author: D.R. Paul
Publisher: Elsevier
ISBN: 0323149774
Category : Technology & Engineering
Languages : en
Pages : 454
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Book Description
Polymer Blends, Volume 2 aims to show the importance of mixed polymer systems as a major branch of macromolecular science and provides a broad background of principles and practices in this field. Starting from where the first volume left off, the book covers topics in the area of polymer blends in Chapters 11-23. Areas of coverage include interpenetrating polymer networks; interfacial agents for polymer blends; rubber modification of plastics; fracture phenomena; coextruded multilayer polymer films and sheets; polymeric plasticizers; and polyolefin blends and their applications. The book is recommended for scientists, technologists, and engineers in the academe, research, and related industry, especially those who wish to be updated with its advances as a science.
Author: Long Yu
Publisher: John Wiley & Sons
ISBN: 0470391553
Category : Technology & Engineering
Languages : en
Pages : 400
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Book Description
Biodegradable Polymer Blends and Composites from Renewable Resources provides a comprehensive, current overview of biopolymeric blends and composites and their applications in various industries. The book is organized according to the type of blend or composite. For each topic, the relationship between the structure of the blends/composites and their respective properties is explored, with particular focus on interface, compatibility, mechanical, and thermal properties. Real-life applications and potential markets are discussed. This is a premier reference for graduate students and researchers in polymer science, chemical and bio engineering, and materials science.
