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Author: Gennadiĭ Efremovich Zaikov
Publisher: Nova Publishers
ISBN: 9781594542169
Category : Science
Languages : en
Pages : 192
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Book Description
Polymer Analysis, Degradation & Stabilization
Author: Gennadiĭ Efremovich Zaikov
Publisher: Nova Publishers
ISBN: 9781594542169
Category : Science
Languages : en
Pages : 192
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Book Description
Polymer Analysis, Degradation & Stabilization
Author: W. L. Hawkins
Publisher: Springer Science & Business Media
ISBN: 3642693768
Category : Technology & Engineering
Languages : en
Pages : 129
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Book Description
The development of polymers as an important class of material was inhibited at the first by the premature failure of these versatile compounds in many applications. The deterioration of important properties of both natural and synthetic polymers is the result of irreversible changes in composition and structure of polymers molecules. As a result of these reactions, mechanical, electrical and/or aesthetic properties are degraded beyond acceptable limits. It is now generally recognized that stabilization against degradation is necessary if the useful life of polymers is to be extended sufficiently to meet design requirements for long-term applications. Polymers degrade by a wide variety of mechanisms, several of which affect all polymers through to varying degree. This monograph will concentrate on those degradation mechanisms which result from reactions of polymers with oxygen in its various forms and which are accelerated by heat and/or radiation. Those stabilization mechanisms are discussed which are based on an understanding of degradation reaction mechanisms that are reasonably well established. The stabilization of polymers is still undergoing a transition from an art to a science as mechanisms of degradation become more fully developed. A scientific approach to stabilization can only be approached when there is an understanding of the reactions that lead to degradation. Stabilization against biodegradation and burning will not be discussed since there is not a clear understanding of how polymers degrade under these conditions.
Author: G. Scott
Publisher: Springer Science & Business Media
ISBN: 9401138389
Category : Technology & Engineering
Languages : en
Pages : 336
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Book Description
The purpose of this publication is two-fold. In the first place it is intended to review progress in the development of practical stabilising systems for a wide range of polymers and applications. A complemen tary and ultimately more important objective is to accommodate these practical developments within the framework of antioxidant theory, since there can be little question that further major advances in the practice of stabilisation technology will only be possible on a firm mechanistic foundation. With the continual increase in the number of commercial anti oxidants and stabilisers, often functioning by mechanisms not even considered ten years ago, there is a need for a general theory which will allow the potential user to predict the performance of a particular antioxidant structure under specific practical conditions. Any such predictive tool must involve a simplified kinetic approach to inhibited oxidation and, in Chapter 1, Denisov outlines a possible mechanistic approach with the potential to predict the most useful antioxidant to use and the limits of its usefulness. In Chapter 2, Schwetlick reviews the current state of knowledge on the antioxidant mechanisms of the phosphite esters with particular emphasis on their catalytic peroxidolytic activity. Dithiophosphate v vi PREFACE derivatives show a similar behaviour but for quite different reasons and, in Chapter 3, AI-Malaika reviews information available from analytical studies, particularly using 31p_NMR spectroscopy, to elucid ate the complex chemistry that leads to the formation of the antioxidant -active agents.
Author: N.S. Allen
Publisher: Springer Science & Business Media
ISBN: 9781851667734
Category : Technology & Engineering
Languages : en
Pages : 218
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Book Description
During the past decade, the field of polymer degradation and stabilization has become a subject of central importance in polymer science and technology. This book provides a fundamental source of information designed for those with only a basic understanding of the background of the field.
Author: Norman Grassie
Publisher: CUP Archive
ISBN: 9780521357975
Category : Science
Languages : en
Pages : 236
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Book Description
The study of polymer degradation and stabilisation is of considerable practical importance as the industrial uses of polymeric materials continue to expand. In this book, the authors lucidly relate technological phenomena to the chemistry and physics of degradation and stabilisation processes. Degradation embraces a variety of technologically important phenomena ranging from relatively low temperature processes such as 'weathering' of plastics, 'fatigue' of rubbers through the processing of polymers in shearing mixers to very high temperature processes such as flammability and ablation. All these technological phenomena have in common certain basic chemical reactions. Thus 'weathering' has its roots in photo-oxidation, 'fatigue' and melt-degradation in mechano-oxidation and flammability, and ablation in ablation in pyrolysis and vapour phase oxidation.
Author: Krzysztof Pielichowski
Publisher: iSmithers Rapra Publishing
ISBN: 9781859574980
Category : Science
Languages : en
Pages : 324
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Book Description
Understanding the thermal degradation of polymers is of paramount importance for developing a rational technology of polymer processing and higher-temperature applications. Controlling degradation requires understanding of many different phenomena, including chemical mechanisms, the influence of polymer morphology, the complexities of oxidation chemistry, and the effects of stabilisers, fillers and other additives. This book offers a wealth of information for polymer researchers and processors requiring an understanding of the implications of thermal degradation on material and product performance.
Author: G. Scott
Publisher: Springer Science & Business Media
ISBN: 9401105715
Category : Technology & Engineering
Languages : en
Pages : 284
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Book Description
Few scientific developments in recent years have captured the popular imagination like the subject of'biodegradable' plastics. The reasons for this are complex and lie deep in the human subconscious. Discarded plastics are an intrusion on the sea shore and in the countryside. The fact that nature's litter abounds in the sea and on land is acceptable because it is biodegradable - even though it may take many years to be bioassimilated into the ecosystem. Plastics litter is not seen to be biodegradable and is aesthetically unacceptable because it does not blend into the natural environment. To the environmentally aware but often scientifically naive, biodegradation is seen to be the ecologically acceptable solution to the problem of plastic packaging waste and litter and some packaging manufacturers have exploited the 'green' consumer with exaggerated claims to 'environmentally friendly' biodegradable packaging materials. The principles underlying environmental degradation are not understood even by some manufacturers of 'biodegradable' materials and the claims made for them have been categorized as 'deceptive' by USA legislative authorities. This has set back the acceptance of plastics with controlled biodegradability as part of the overall waste and litter control strategy. At the opposite end of the commercial spectrum, the polymer manufactur ing industries, through their trade associations, have been at pains to discount the role of degradable materials in waste and litter management. This negative campaign has concentrated on the supposed incompatibility of degradable plastics with aspects of waste management strategy, notably materials recycling.
Author: Shulamith Schlick
Publisher: John Wiley & Sons
ISBN: 1119196051
Category : Science
Languages : en
Pages : 300
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Book Description
Examines the important topic of fuel cell science by way of combining membrane design, chemical degradation mechanisms, and stabilization strategies This book describes the mechanism of membrane degradation and stabilization, as well as the search for stable membranes that can be used in alkaline fuel cells. Arranged in ten chapters, the book presents detailed studies that can help readers understand the attack and degradation mechanisms of polymer membranes and mitigation strategies. Coverage starts from fundamentals and moves to different fuel cell membrane types and methods to profile and analyze them. The Chemistry of Membranes Used in Fuel Cells: Degradation and Stabilization features chapters on: Fuel Cell Fundamentals: The Evolution of Fuel Cells and their Components; Degradation Mechanism of Perfluorinated Membranes; Ranking the Stability of Perfluorinated Membranes Used in Fuel Cells to Attack by Hydroxyl Radicals; Stabilization Mechanism of Perfluorinated Membranes by Ce(III) and Mn(II); Hydrocarbon Proton Exchange Membranes; Stabilization of Perfluorinated Membranes Using Nanoparticle Additives; Degradation Mechanism in Aquivion Perfluorinated Membranes and Stabilization Strategies; Anion Exchange Membrane Fuel Cells: Synthesis and Stability; In-depth Profiling of Degradation Processes in Nafion Due to Pt Dissolution and Migration into the Membrane; and Quantum Mechanical Calculations of the Degradation Mechanism in Perfluorinated Membranes. Brings together aspects of membrane design, chemical degradation mechanisms and stabilization strategies Emphasizes chemistry of fuel cells, which is underemphasized in other books Includes discussion of fuel cell performance and behavior, analytical profiling methods, and quantum mechanical calculations The Chemistry of Membranes Used in Fuel Cells is an ideal book for polymer scientists, chemists, chemical engineers, electrochemists, material scientists, energy and electrical engineers, and physicists. It is also important for grad students studying advanced polymers and applications.
Author: J. Owen
Publisher: Springer Science & Business Media
ISBN: 9400956185
Category : Technology & Engineering
Languages : en
Pages : 325
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Book Description
Polyvinyl chloride has played a key role in the development of the plastics industry over the past 40 years and continues to be a polymer of major importance. The reasons for its enormous versatility and range of application derive from a combination of the basic structure which gives rise to a relatively tough and rigid material and its ability to accept a range of plasticisers and other additives which can modify its physical characteristics to produce a range of flexible products. Two major problems, however, have tested the skill and ingenuity of PVC technologists since earliest times. One is the thermal instability of the material at the temperatures required for melt processing and fabrication, and the second is the photochemical instability which until recently has limited the potentially large range of outdoor applications. Both problems have been handled in a commercially satisfactory way by the gradual development of a range of stabilisers, lubricants and other processing aids and the high quality material which has resulted has led to massive utilisation of PVC by industry. Totally adequate stabilisation requires a detailed understanding of the mechanisms by which degradation processes are initiated and propagated. Although great advances have been made in this respect in recent years the problem remains incompletely understood. This book presents an account of the present position and the problems which remain to be solved.
Author: Hans Zweifel
Publisher: Springer Science & Business Media
ISBN: 3642803059
Category : Science
Languages : en
Pages : 225
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Book Description
Plastics are used worldwide in everyday life, e.g. as food packaging, electronics, construction, automotive parts, and household appliances. To produce these products with the desired service lifetimes the use of suitable stabilizers is necessary. This book provides a concise and comprehensive overview of the basic mechanisms of plastic degradation processes caused by heat and light. At its core is a detailed description of the stabilization of different polymers, including an explanation of stabilization mechanisms and the influence of commonly used additives such as fillers, flame retardents and pigments on the stability of plastic. Every polymer scientist, material technologist, or application engineer dealing with the design of the properties of plastics will benefit from this new overview.
