Photocatalytic Degradation of Atrazine PDF Download
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Author: David Peter Allen
Publisher:
ISBN:
Category :
Languages : en
Pages :
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Author: David Peter Allen
Publisher:
ISBN:
Category :
Languages : en
Pages :
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Author: Zhonghua Li
Publisher:
ISBN:
Category : Atrazine
Languages : en
Pages : 240
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Author:
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ISBN:
Category :
Languages : en
Pages : 26
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Book Description
TiO2 photocatalysis is investigated is a potential means for the disposal of pesticide rinsate waste at agrochemical dealerships. The focus is an evaluation of parameters that affect the rate and mechanism of atrazine degradation using formulated atrazine (ca. 20-25 ppm), TiO2 mesh, a high-pressure mercury-vapor lamp, and solar irradiation. The UV transmission of a variety of transparent materials was measured and atrazine photocatalysis was carried out using several materials as reactor covers. The pseudo-first-order rate constants were calculated and compared to determine which cover results in the most efficient atrazine degradation. A clear acrylic gave results nearly identical to Pyrex and was chosen for future photocatalytic experiments. UV intensity and photocatalytic rate were studied as a function of different numbers of layers of TiO2 mesh. It was found that five layers give the optimum rate of degradation without employing excess mesh. In order to assess the general effect of impurities present in water on the rate of atrazine degradation, water from five different sources was obtained and each sample was analyzed for purity and used to prepare aqueous atrazine for photocatalytic degradation. The results show that contaminants specific to different locations are likely to inhibit the rate of photocatalysis to different degrees. While working to maximize the rate of atrazine degradation, studies are concurrently in progress to elucidate the mechanism of degradation for the experimental conditions employed herein. Initial results indicate that the overall degradation of atrazine to the reported end product, cyanuric acid, occurs by two distinct pathways of similar importance.
Author:
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Category :
Languages : en
Pages :
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Author:
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Category : Strontium
Languages : en
Pages : 450
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Author: Elvis Fosso-Kankeu
Publisher: John Wiley & Sons
ISBN: 1119631394
Category : Science
Languages : en
Pages : 320
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Book Description
Photocatalysts in Advanced Oxidation Processes for Wastewater Treatment comprehensively covers a range of topics aiming to promote the implementation of photocatalysis at large scale through provision of facile and green methods for catalysts synthesis and elucidation of pollutants degradation mechanisms. This book is divided into two main parts namely “Synthesis of effective photocatalysts” (Part I) and “Mechanisms of the photocatalytic degradation of various pollutants” (Part II). The first part focuses on the exploration of various strategies to synthesize sustainable and effective photocatalysts. The second part of the book provides an insights into the photocatalytic degradation mechanisms and pathways under ultraviolet and visible light irradiation, as well as the challenges faced by this technology and its future prospects.
Author: Suresh C. Pillai
Publisher: Walter de Gruyter GmbH & Co KG
ISBN: 3110668483
Category : Science
Languages : en
Pages : 396
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Book Description
This book is a concise and up-to-date introduction to the topic of photocatalysis. It covers the fundamentals of photocatalysis, design of photoreactors and modelling and simulations for photoreaction. Also, industrial applications such as hydrogen production, water disinfection, degradation of air pollutants, pesticides and pharmaceuticals are described.
Author: I. H. Suffet
Publisher:
ISBN:
Category : Language Arts & Disciplines
Languages : en
Pages : 906
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Book Description
Here is a cohesive compilation of recent research results into the many aspects of water purification. Major sections cover the characterization and environmental impact of aquatic humic substances, their reactions in natural water and sediments, and their influences on water treatment. Topics examined include hazardous waste chemicals, water solubility enhancement, sorption, metal speciation, and photochemistry. Specific types of treatment processes are also described.
Author: Martin M. Halmann
Publisher: CRC Press
ISBN: 1040286240
Category : Technology & Engineering
Languages : en
Pages : 319
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Book Description
Photodegradation of Water Pollutants, the only complete survey available of current photocatalytic methods for treating water pollutants, covers all aspects of light-stimulated detoxification. Ideal for researchers and students, this new book explains methods for pollution treatment that have proven more effective than conventional biodegradation. Photodegradation of Water Pollutants examines advanced oxidation processes that have been successful in treating the chemical substances produced by industrial effluents and intensive agriculture. These oxidation processes include irradiation with ultraviolet or visible light, the use of homogenous sensitizers, such as dyes, and the use of heterogeneous photocatalysts, such as dispersed semiconductors. In addition, Photodegradation of Water Pollutants addresses the naturally occurring self-cleaning of some pollutants in sunlit surface waters, as well as several alternative non-photochemical approaches to water treatment. Available treatment options are discussed for the main groups of water pollutants, including toxic inorganic ions (cyanides, heavy metals), hydrocarbon derivatives (oil spills, surfactants, pulp and paper wastes), halocarbons, organo-N, organo-P, and organo-S compounds. The text also contains a unique section on the economics of advanced oxidation pollution treatments.
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ISBN:
Category :
Languages : en
Pages : 29
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The Tennessee Valley Authority's Environmental Research Center has been developing a means of detoxifying atrazine waste waters using TiO2 photocatalysis. The toxicity and physical properties of atrazine and its degradation products will probably be required information in obtaining permits from the United States Environmental Protection Agency for the demonstration of any photocatalytic treatment of atrazine waste waters. The following report is a literature survey of the toxicological and physical properties of atrazine and its degradation products.
