Phase Field Modeling of Tetragonal to Monoclinic Phase Transformation in Zirconia PDF Download
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Author: Mahmood Mamivand
Publisher:
ISBN:
Category :
Languages : en
Pages : 176
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Book Description
Zirconia based ceramics are strong, hard, inert, and smooth, with low thermal conductivity and good biocompatibility. Such properties made zirconia ceramics an ideal material for different applications form thermal barrier coatings (TBCs) to biomedicine applications like femoral implants and dental bridges. However, this unusual versatility of excellent properties would be mediated by the metastable tetragonal (or cubic) transformation to the stable monoclinic phase after a certain exposure at service temperatures. This transformation from tetragonal to monoclinic, known as LTD (low temperature degradation) in biomedical application, proceeds by propagation of martensite, which corresponds to transformation twinning. As such, tetragonal to monoclinic transformation is highly sensitive to mechanical and chemomechanical stresses. It is known in fact that this transformation is the source of the fracture toughening in stabilized zirconia as it occurs at the stress concentration regions ahead of the crack tip. This dissertation is an attempt to provide a kinetic-based model for tetragonal to monoclinic transformation in zirconia. We used the phase field technique to capture the temporal and spatial evolution of monoclinic phase. In addition to morphological patterns, we were able to calculate the developed internal stresses during tetragonal to monoclinic transformation. The model was started form the two dimensional single crystal then was expanded to the two dimensional polycrystalline and finally to the three dimensional single crystal. The model is able to predict the most physical properties associated with tetragonal to monoclinic transformation in zirconia including: morphological patterns, transformation toughening, shape memory effect, pseudoelasticity, surface uplift, and variants impingement. The model was benched marked with several experimental works. The good agreements between simulations results and experimental data, make the model a reliable tool for predicting tetragonal to monoclinic transformation in the cases we lack experimental observations.
Author: Mahmood Mamivand
Publisher:
ISBN:
Category :
Languages : en
Pages : 176
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Book Description
Zirconia based ceramics are strong, hard, inert, and smooth, with low thermal conductivity and good biocompatibility. Such properties made zirconia ceramics an ideal material for different applications form thermal barrier coatings (TBCs) to biomedicine applications like femoral implants and dental bridges. However, this unusual versatility of excellent properties would be mediated by the metastable tetragonal (or cubic) transformation to the stable monoclinic phase after a certain exposure at service temperatures. This transformation from tetragonal to monoclinic, known as LTD (low temperature degradation) in biomedical application, proceeds by propagation of martensite, which corresponds to transformation twinning. As such, tetragonal to monoclinic transformation is highly sensitive to mechanical and chemomechanical stresses. It is known in fact that this transformation is the source of the fracture toughening in stabilized zirconia as it occurs at the stress concentration regions ahead of the crack tip. This dissertation is an attempt to provide a kinetic-based model for tetragonal to monoclinic transformation in zirconia. We used the phase field technique to capture the temporal and spatial evolution of monoclinic phase. In addition to morphological patterns, we were able to calculate the developed internal stresses during tetragonal to monoclinic transformation. The model was started form the two dimensional single crystal then was expanded to the two dimensional polycrystalline and finally to the three dimensional single crystal. The model is able to predict the most physical properties associated with tetragonal to monoclinic transformation in zirconia including: morphological patterns, transformation toughening, shape memory effect, pseudoelasticity, surface uplift, and variants impingement. The model was benched marked with several experimental works. The good agreements between simulations results and experimental data, make the model a reliable tool for predicting tetragonal to monoclinic transformation in the cases we lack experimental observations.
Author: Mark F. Horstemeyer
Publisher: John Wiley & Sons
ISBN: 1119018366
Category : Technology & Engineering
Languages : en
Pages : 712
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Book Description
Focuses entirely on demystifying the field and subject of ICME and provides step-by-step guidance on its industrial application via case studies This highly-anticipated follow-up to Mark F. Horstemeyer’s pedagogical book on Integrated Computational Materials Engineering (ICME) concepts includes engineering practice case studies related to the analysis, design, and use of structural metal alloys. A welcome supplement to the first book—which includes the theory and methods required for teaching the subject in the classroom—Integrated Computational Materials Engineering (ICME) For Metals: Concepts and Case Studies focuses on engineering applications that have occurred in industries demonstrating the ICME methodologies, and aims to catalyze industrial diffusion of ICME technologies throughout the world. The recent confluence of smaller desktop computers with enhanced computing power coupled with the emergence of physically-based material models has created the clear trend for modeling and simulation in product design, which helped create a need to integrate more knowledge into materials processing and product performance. Integrated Computational Materials Engineering (ICME) For Metals: Case Studies educates those seeking that knowledge with chapters covering: Body Centered Cubic Materials; Designing An Interatomic Potential For Fe-C Alloys; Phase-Field Crystal Modeling; Simulating Dislocation Plasticity in BCC Metals by Integrating Fundamental Concepts with Macroscale Models; Steel Powder Metal Modeling; Hexagonal Close Packed Materials; Multiscale Modeling of Pure Nickel; Predicting Constitutive Equations for Materials Design; and more. Presents case studies that connect modeling and simulation for different materials' processing methods for metal alloys Demonstrates several practical engineering problems to encourage industry to employ ICME ideas Introduces a new simulation-based design paradigm Provides web access to microstructure-sensitive models and experimental database Integrated Computational Materials Engineering (ICME) For Metals: Case Studies is a must-have book for researchers and industry professionals aiming to comprehend and employ ICME in the design and development of new materials.
Author: Thomas J. Lucas
Publisher:
ISBN:
Category : Body temperature
Languages : en
Pages : 92
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Book Description
This investigation addresses the issue that yttria stabilized zirconia is being used as a dental biomaterial without substantial evidence of its long-term viability. Furthermore, stabilized zirconia (SZ) undergoes low temperature degradation (LTD), which can lead to roughening of the surface. A rougher exterior can lead to increased wear of the antagonist in the oral environment. Despite the LTD concerns, SZ is now widely used in restorative dentistry, including full contour crowns. A comparison of aging methods to determine the role of artificial aging on inducing the transformation has not been extensively studied. Therefore, simulations of the transformation process were investigated by comparing different methods of accelerated aging. The rejected null hypothesis is that the temperature of aging treatment will not affect the time required to cause measurable monoclinic transformation of yttria stabilized zirconia.The transformation of SZ starts at the surface and progresses inward; however, it is unclear whether the progression is constant for different aging conditions. This investigation analyzed the depth of transformation as a function of aging conditions for stabilized zirconia in the top 5-6 micrometers from the surface. The rejected null hypothesis is that the transformation amount is constant throughout the first six micrometers from the surface. The effects of grain size on the amount of monoclinic transformation were also investigated. This study aimed to determine if the grain size of partially stabilized zirconia affects the amount of monoclinic transformation, surface roughness, and property degradation due to aging. The rejected null hypothesis is that the grain size will not affect the amount of monoclinic transformation, thus have no effect on surface roughening or property degradation. The final part of this study addresses the wear of enamel when opposing zirconia by observing how grain size and aging affected the wear rate of an enamel antagonist. The rejected null hypothesis is that neither zirconia grain size, nor aging condition affects the wear of an enamel antagonist.
Author: Neville Sonnenberg
Publisher:
ISBN:
Category : Zirconium oxide
Languages : en
Pages : 342
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Author: Girraj Kishore Bansal
Publisher:
ISBN:
Category : Crystals
Languages : en
Pages : 124
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Author: Clark F. Grain
Publisher:
ISBN:
Category : Zirconium oxide
Languages : en
Pages : 28
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Author: Sergej-Tomislav V. Buljan
Publisher:
ISBN:
Category : Solid state physics
Languages : en
Pages : 382
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Author: S. Meriani
Publisher: Springer Science & Business Media
ISBN: 9400911394
Category : Science
Languages : en
Pages : 371
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Book Description
This meeting, ZIRCONIA 'SS - Advances in Zirconia Science and Technology, was held within the framework of the 7tb SIMCER - International Symposium on Ceramics (Bologna, December 14-17, 1988) organized by the Italian Ceramic Center of Bologna, with the sponsorship of ENEA and Agip and the endorsement of the American Ceramic Society, and under the auspices of the European Ceramic Society. In the year 1988, the University of Bologna celebrated its 900th Anniversary. ZIRCONIA '88 was one of the celebration events which brought together academics and researchers from allover the world. Under the chairmanship of Prof. C. Palmonari, Director of the Italian Ceramic Center of the University of Bologna, the Organizing Committee consisting of J. Castaing (C.N.R.S. Meudon, France), S. Meriani (University of Trieste, Italy), V. Prodi (Un-iversity of Bologna, Italy) and J. Routbort (U.S. Dept. of Energy, Washington, USA) conducted a conference program of 47 contributions presented to the 220 enrolled Zirconia participants, out of the 775 enlisted within the main SIMCER framework. The aim of ZIRCONIA '88 was to follow the stream of the well known International Conferences on the Science and Technology of zj rconia held in Cleveland, Ohio (1980), Stuttgart, Federal Republic of Germany (1983) and Tokyo, Japan (1986). SIMCER's goal was to bring together not only scientists and engineers directly involved with "advanced" ceramics but also a larger audience connected to the nearby Italian Ceramic District of Sassuolo.
Author: Zenji Nishiyama
Publisher: Elsevier
ISBN: 0323148816
Category : Technology & Engineering
Languages : en
Pages : 480
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Book Description
Martensitic Transformation examines martensitic transformation based on the known crystallographical data. Topics covered range from the crystallography of martensite to the transformation temperature and rate of martensite formation. The conditions for martensite formation and stabilization of austenite are also discussed, along with the crystallographic theory of martensitic transformations. Comprised of six chapters, this book begins with an introduction to martensite and martensitic transformation, with emphasis on the basic properties of martensite in steels such as carbon steels. The next two chapters deal with the crystallography of martensite and discuss the martensitic transformation behavior of the second-order transition; lattice imperfections in martensite; and close-packed layer structures of martensites produced from ? phase in noble-metal-base alloys. Thermodynamical problems and kinetics are also analysed, together with conditions for the nucleation of martensite and problems concerning stabilization of austenite. The last chapter discusses the theory of the mechanism underlying martensitic transformation. This monograph will be of interest to metallurgists and materials scientists.
Author: David J. Bergman
Publisher: Springer Science & Business Media
ISBN: 1402023162
Category : Technology & Engineering
Languages : en
Pages : 407
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Book Description
Proceedings of the NATO ARW, Shoresh, Israel, from 30 June to 4 July 2003
