Organometallic Reaction Mechanisms Of The Nontransition Elements PDF Download
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Author: Donald Matteson
Publisher: Elsevier
ISBN: 0323141226
Category : Science
Languages : en
Pages : 366
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Book Description
Organometallic Reaction Mechanisms of the Nontransition Elements provides selected significant developments in organometallic reaction mechanisms and outlines a self-consistent set of interpretations of these mechanisms. This book is organized into eight chapters and begins with discussions on bonding in theoretically important types of organometallic compounds and the potential surfaces and their relation to mechanisms. This is followed by significant chapters on electrophilic displacement reactions. Polar 1,2-addition and elimination reactions are covered in a separate chapter. Radical and photochemical reactions are described in the concluding chapters of the book, including the reverse reaction involving incorporation of a free metal and an organic halide into an organometallic compound. Organic chemists and researchers will find this book invaluable.
Author: Donald Matteson
Publisher: Elsevier
ISBN: 0323141226
Category : Science
Languages : en
Pages : 366
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Book Description
Organometallic Reaction Mechanisms of the Nontransition Elements provides selected significant developments in organometallic reaction mechanisms and outlines a self-consistent set of interpretations of these mechanisms. This book is organized into eight chapters and begins with discussions on bonding in theoretically important types of organometallic compounds and the potential surfaces and their relation to mechanisms. This is followed by significant chapters on electrophilic displacement reactions. Polar 1,2-addition and elimination reactions are covered in a separate chapter. Radical and photochemical reactions are described in the concluding chapters of the book, including the reverse reaction involving incorporation of a free metal and an organic halide into an organometallic compound. Organic chemists and researchers will find this book invaluable.
Author: Donald Stephen Matteson
Publisher:
ISBN:
Category : Chemical reaction, Conditions and laws of
Languages : en
Pages : 353
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Book Description
Author: Richard A. Henderson
Publisher: Oxford University Press on Demand
ISBN: 9780198557463
Category : Science
Languages : en
Pages : 87
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Book Description
Understanding the mechanisms of the reactions at transition metal sites is a key component in designing synthetic methods, developing industrial homogeneous catalysts, and investigating metalloenzymes. These mechanisms are therefore an essential part of undergraduate chemistry courses. This primer provides a broad-based, systematic guide to the fundamentals of transition-metal mechanistic chemistry, including substitution, electron transfer, and reactions of ligands. It serves as an ideal text for undergraduate students with a foundation in basic inorganic chemistry but who are new to inorganic reaction mechanisms.
Author: Valentin P. Ananikov
Publisher: John Wiley & Sons
ISBN: 3527678220
Category : Science
Languages : en
Pages : 483
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Book Description
Exploring and highlighting the new horizons in the studies of reaction mechanisms that open joint application of experimental studies and theoretical calculations is the goal of this book. The latest insights and developments in the mechanistic studies of organometallic reactions and catalytic processes are presented and reviewed. The book adopts a unique approach, exemplifying how to use experiments, spectroscopy measurements, and computational methods to reveal reaction pathways and molecular structures of catalysts, rather than concentrating solely on one discipline. The result is a deeper understanding of the underlying reaction mechanism and correlation between molecular structure and reactivity. The contributions represent a wealth of first-hand information from renowned experts working in these disciplines, covering such topics as activation of small molecules, C-C and C-Heteroatom bonds formation, cross-coupling reactions, carbon dioxide converison, homogeneous and heterogeneous transition metal catalysis and metal-graphene systems. With the knowledge gained, the reader will be able to improve existing reaction protocols and rationally design more efficient catalysts or selective reactions. An indispensable source of information for synthetic, analytical, and theoretical chemists in academia and industry.
Author: Jim D. Atwood
Publisher: John Wiley & Sons
ISBN: 0471188972
Category : Science
Languages : en
Pages : 327
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Book Description
Jetzt in neuer Auflage: Das erfolgreiche Lehrwerk über Kinetik und Mechanismen anorganischer und organometallischer Reaktionen für fortgeschrittene Studenten! Hervorragend geeignet als Begleiter eines Vorlesungssemesters. Mit zahlreichen Übungsaufgaben; für eine bessere Übersicht sorgen Zusammenfassungen am Ende jedes Kapitels.
Author: M.V. Twigg
Publisher: Springer Science & Business Media
ISBN: 1461324793
Category : Social Science
Languages : en
Pages : 521
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Book Description
The purpose of this series is to provide a continuing critical review of the literature concerned with mechanistic aspects of inorganic and organo metallic reactions in solution, with coverage being complete in each volume. The papers discussed are selected on the basis of relevance to the elucidation of reaction mechanisms and many include results of a nonkinetic nature when useful mechanistic information can be deduced. The period of literature covered by this volume is July 1982 through December 1983, and in some instances papers not available for inclusion in the previous volume are also included. Numerical results are usually reported in the units used by the original authors, except where data from different papers are com pared and conversion to common units is necessary. As in previous volumes material included covers the major areas of redox processes, reactions of the nonmetallic elements, reaction of inert and labile metal complexes and the reactions of organometallic compounds. While maintaining the space devoted to other areas, that given to the nonmetallic elements has been increased. In recognition of the increasing importance of the determination of volumes of activation in understanding the mechanisms of both inorganic and organometallic reactions a special reference section giving tabulated Ll V* values has been included and this extensive compilation will be updated in future volumes.
Author: Florian P. Pruchnik
Publisher: Springer Science & Business Media
ISBN: 0306431920
Category : Science
Languages : en
Pages : 780
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Book Description
Organometallic chemistry belongs to the most rapidly developing area of chemistry today. This is due to the fact that research dealing with the structure of compounds and chemical bonding has been greatly intensified in recent years. Additionally, organometallic compounds have been widely utilized in catalysis, organic synthesis, electronics, etc. This book is based on my lectures concerning basic organometallic chemistry for fourth and fifth year chemistry students and on my lectures concerning advanced organometallic chemistry and homogeneous catalysis for Ph.D. graduate students. Many recent developments in the area of organometallic chemistry as weIl as homogeneous catalysis are presented. Essential research results dealing with a given class of organometallic compounds are discussed briefly. Results of physicochemical research methods of various organometallic compounds as weIl as their synthesis, properties, structures, reactivities, and applications are discussed more thoroughly. The selection of tabulated data is arbitrary because, often, it has been impossible to avoid omissions. Nevertheless, these data can be very helpful in understanding properties of organometaIlic compounds and their reactivities. All physical data are given in SI units; the interatomic distances are given in pm units in figures and tables. I am indebted to Professor S. A. Duraj for translating and editing this book. His remarks, discussions, and suggestions are greatly appreciated. I also express gratitude to Virginia E. Duraj for editing and proofreading.
Author: Robert H. Crabtree
Publisher: John Wiley & Sons
ISBN: 0471718750
Category : Science
Languages : en
Pages : 600
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Book Description
Fully updated and expanded to reflect recent advances, this Fourth Edition of the classic text provides students and professional chemists with an excellent introduction to the principles and general properties of organometallic compounds, as well as including practical information on reaction mechanisms and detailed descriptions of contemporary applications.
Author: Shay Beck
Publisher: Scientific e-Resources
ISBN: 1839472022
Category :
Languages : en
Pages : 396
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Book Description
Organometallic Chemistry is the study of chemical compounds containing bonds between carbon and metal. The term "e;Metal"e; is defined deliberately broadly in this context and may include elements, such as silicon or boron, which are not metallic but are considered to be metalloids. Almost all branches of chemistry and material science now interface with organometallic chemistry. Organometallics find practical uses in stoichiometric and catalytic processes, especially processes involving carbon monoxide and alkene-derived polymers. Organometallic (OM) chemistry is the study of compounds containing, and reactions involving, metal-carbon bonds. The metal-carbon bond may be transient or temporary, but if one exists during a reaction or in a compound of interest, we're squarely in the domain of organometallic chemistry. Despite the denotational importance of the M-C bond, bonds between metals and the other common elements of organic chemistry also appear in OM chemistry: metal-nitrogen, metal-oxygen, metal-halogen, and even metal-hydrogen bonds all play a role. Metals cover a vast swath of the periodic table and include the alkali metals (group 1), alkali earth metals (group 2), transition metals (groups 3-12), the main group metals (groups 13-15, "e;under the stairs"e;), and the lanthanides and actinides. The principal idea of this book is to offer a comprehensive coverage of unconventional and thought-provoking topics in organometallic chemistry. It also supplies practical information about reaction mechanisms, along with the descriptions of contemporary applications to organic synthesis, organized by mechanism and kinetic. It will serve as a valuable reference tool for students and professional of organic and post organic chemistry, who need to become better acquainted with the subject.
Author: Ralph G. Wilkins
Publisher: Wiley-VCH
ISBN: 9783527282531
Category : Science
Languages : en
Pages : 480
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Book Description
This thoroughly revised and updated edition of one of the classics of kinetics text books continues the successful concept of the 1974 edition: In its first part, a simplified approach to the determination of rate laws and mechnisms is given steadily working up to complex situations. In the following chapters the principles developed there are extensively used in a comprehensive account of reactions of transition metal complexes, including reactions of biological signifacance. The text is illustrated by numerous figures and tables. Points of further interest are highlighted in special insets. 140 problems, taken from the original literature, enable the student to apply and deepen his newly acquired knowledge and make the book highly useful for courses in inorganic and organometallic reaction mechanisms. Furthermore, a wealth of over 1700 references renders it an indispensable work for the active researcher.
