Organometallic Derivatives of the Main Group Elements PDF Download
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Author: B. J. Aylett
Publisher:
ISBN: 9780839110101
Category : Science
Languages : en
Pages : 432
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Author: B. J. Aylett
Publisher:
ISBN: 9780839110101
Category : Science
Languages : en
Pages : 432
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Book Description
Author: Glen Berenger Deacon
Publisher:
ISBN:
Category : Organometallic compounds
Languages : en
Pages :
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Author: H. J. Emeleus
Publisher:
ISBN:
Category :
Languages : en
Pages : 412
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Author: B. J. Aylett
Publisher: Springer Science & Business Media
ISBN: 9400957297
Category : Science
Languages : en
Pages : 532
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A very large number of organo derivatives is formed by the Group IV ele ments silicon, germanium, tin, and lead. In comparing the general properties of these elements, Table 1. 1 shows that the first ionization energies decrease (though not in a regular way) with increase in size and atomic number, con sistent with the general increase in metallic character of the elements. Electro negativity values (which have been the subject of considerable controversy) show no clear trend. Although purely inorganic compounds of tin(n) and leaden) are well known, almost all organo Group IV derivatives show an oxidation state of IV. Bonds to carbon become weaker on passing from silicon to lead, as do the element-element bonds themselves. With any particular element M (M = Si, Ge, Sn, or Pb), there is a small decrease in bond energy in the order: M-Ph > M - Me > M - Et. Although accurate data for organo derivatives are lacking, strengths of bonds to other elements probably decrease in the order: M-F> M-O > M-CI > M-H ~ M-N ~ M-S ~ M-Br > M-I, while for a particular element X, the order is: Si-X > Ge-X > Sn-X > Pb-X. It is therefore understandable that reactions leading to Si-F, Si-O, or Si-CI bonds are especially favoured in a thermodynamic sense.
Author:
Publisher: Academic Press
ISBN: 0080580408
Category : Science
Languages : en
Pages : 429
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This widely acclaimed serial contains authoritative reviews that address all aspects of organometallic chemistry, a field which has expanded enormously since the publication of Volume 1 in 1964. Almost all branchesof chemistry now interface with organometallic chemistry--the study of compounds containing carbon metal bonds. Organometallic compounds range from species which are so reactive that they only have a transient existence at ambient temperatures to species which are thermally very stable. Organometallics are used extensively in the synthesis of useful compounds on both large and small scales. Industrial processes involving plastics, polymers, electronic materials, and pharmaceuticals all depend on advancements in organometallic chemistry. In basic research, organometallics have contributed inter alia to: Metal cluster chemistry Surface chemistry The stabilization of highly reactive species by metal coordination Chiral synthesis The formulation of multiple bonds between carbon and the other elements and between the elements themselves
Author: H.J. Emeléus
Publisher:
ISBN:
Category :
Languages : en
Pages :
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Author:
Publisher:
ISBN:
Category : Chemistry, Inorganic
Languages : en
Pages : 0
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Author: Harry Julius Emeléus
Publisher:
ISBN: 9780839102007
Category : Chemistry, Inorganic
Languages : en
Pages :
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Author:
Publisher:
ISBN:
Category :
Languages : en
Pages :
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Author: Harry Julius Emeléus
Publisher:
ISBN:
Category : Chemistry, Inorganic
Languages : en
Pages :
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