Numerical Modeling of an All Vanadium Redox Flow Battery PDF Download
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Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 46
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Book Description
We develop a capability to simulate reduction-oxidation (redox) flow batteries in the Sierra Multi-Mechanics code base. Specifically, we focus on all-vanadium redox flow batteries; however, the capability is general in implementation and could be adopted to other chemistries. The electrochemical and porous flow models follow those developed in the recent publication by [28]. We review the model implemented in this work and its assumptions, and we show several verification cases including a binary electrolyte, and a battery half-cell. Then, we compare our model implementation with the experimental results shown in [28], with good agreement seen. Next, a sensitivity study is conducted for the major model parameters, which is beneficial in targeting specific features of the redox flow cell for improvement. Lastly, we simulate a three-dimensional version of the flow cell to determine the impact of plenum channels on the performance of the cell. Such channels are frequently seen in experimental designs where the current collector plates are borrowed from fuel cell designs. These designs use a serpentine channel etched into a solid collector plate.
Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 46
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Book Description
We develop a capability to simulate reduction-oxidation (redox) flow batteries in the Sierra Multi-Mechanics code base. Specifically, we focus on all-vanadium redox flow batteries; however, the capability is general in implementation and could be adopted to other chemistries. The electrochemical and porous flow models follow those developed in the recent publication by [28]. We review the model implemented in this work and its assumptions, and we show several verification cases including a binary electrolyte, and a battery half-cell. Then, we compare our model implementation with the experimental results shown in [28], with good agreement seen. Next, a sensitivity study is conducted for the major model parameters, which is beneficial in targeting specific features of the redox flow cell for improvement. Lastly, we simulate a three-dimensional version of the flow cell to determine the impact of plenum channels on the performance of the cell. Such channels are frequently seen in experimental designs where the current collector plates are borrowed from fuel cell designs. These designs use a serpentine channel etched into a solid collector plate.
Author: Arun K. Saha
Publisher: Springer
ISBN: 8132227433
Category : Technology & Engineering
Languages : en
Pages : 1638
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Book Description
This volume comprises the proceedings of the 42nd National and 5th International Conference on Fluid Mechanics and Fluid Power held at IIT Kanpur in December, 2014.The conference proceedings encapsulate the best deliberations held during the conference. The diversity of participation in the conference, from academia, industry and research laboratories reflects in the articles appearing in the volume. This contributed volume has articles from authors who have participated in the conference on thematic areas such as Fundamental Issues and Perspectives in Fluid Mechanics; Measurement Techniques and Instrumentation; Computational Fluid Dynamics; Instability, Transition and Turbulence; Turbomachinery; Multiphase Flows; Fluid‐Structure Interaction and Flow‐Induced Noise; Microfluidics; Bio‐inspired Fluid Mechanics; Internal Combustion Engines and Gas Turbines; and Specialized Topics. The contents of this volume will prove useful to researchers from industry and academia alike.
Author: Mohammed Abdulkhabeer Ali Al-yasiri
Publisher:
ISBN:
Category :
Languages : en
Pages : 148
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Book Description
"Energy storage is envisioned as a key part of a renewable energy solution incorporated in a grid that overcomes two critical limits of renewable energy: intermittency and uncertainty. Among various technologies, a vanadium redox flow battery (VRFB) offers a promise because of its unique features such as long cycle life, separation of energy and power ratings, and capability of a deep discharge. The remaining challenges, however, include the limited application due to low energy density and complicated geometries. The complex geometry makes it difficult to optimize the performance and can cause a serious concern about leakage of the liquid. The goal of this dissertation is to resolve these challenges through modeling and experimental studies for newly-designed VRFB. The topic can be divided into three main efforts: flow field optimization by optimizing channels, new design for stability improvement and cost reduction, and a new concept of distributed VRFB. First, the effects of channel and length on battery performance were investigated based on 3D electrochemical models validated by experimental measurements. Second, to address the drawbacks of traditional VRFB, a new design has been introduced to increase reliability, reduce costs, and ease assembly. This battery has a small number of parts, which can more effectively prevent electrolyte leakage. Based on PVC (polyvinyl chloride) material, it solves the problem caused by electrolyte penetration by replacing existing graphite plate. Third, the development of a new distributed VRFB for transport systems addresses the problem of insufficient power, one of the main challenges of the flow system. This new technology is more efficient for space utilization, equal weight distribution, and fueling like a gasoline vehicle, reducing charge time"--Abstract, page iv.
Author: Huamin Zhang
Publisher: CRC Press
ISBN: 1351648721
Category : Science
Languages : en
Pages : 409
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Book Description
Flow batteries have received attention in large-scale energy storage due to their flexible design, high safety, high energy efficiency, and environmental friendliness. In recent years, they have been rapidly developed and tested in a variety of scales that prove their feasibility and advantages of use. As energy becomes a global focus, it is important to consider flow battery systems. This book offers a detailed introduction to the function of different kinds of redox flow batteries, including vanadium flow batteries, as well as the electrochemical processes for their development, materials and components, applications, and near future prospects. Redox Flow Batteries: Fundamentals and Applications will give readers a full understanding of flow batteries from fundamentals to commercial applications.
Author: Akeel A. Shah
Publisher: Springer Nature
ISBN: 981992524X
Category : Technology & Engineering
Languages : en
Pages : 389
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Book Description
This book provides a comprehensive review of the latest modelling developments in flow batteries, as well as some new results and insights. Flow batteries have long been considered the most flexible answer to grid scale energy storage, and modelling is a key component in their development. Recent modelling has moved beyond macroscopic methods, towards mesoscopic and smaller scales to select materials and design components. This is important for both fundamental understanding and the design of new electrode, catalyst and electrolyte materials. There has also been a recent explosion in interest in machine learning for electrochemical energy technologies. The scope of the book includes these latest developments and is focused on advanced techniques, rather than traditional modelling paradigms. The aim of this book is to introduce these concepts and methods to flow battery researcher, but the book would have a much broader appeal since these methods also employed in other battery and fuel cell systems and far beyond. The methods will be described in detail (necessary fundamental material in Appendices). The book appeals to graduate students and researchers in academia/industry working in electrochemical systems, or those working in computational chemistry/machine learning wishing to seek new application areas.
Author: Maik Becker
Publisher: Cuvillier Verlag
ISBN: 373696210X
Category : Science
Languages : en
Pages : 150
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Book Description
Redox-Flow batteries can play a crucial role in the future electricity supply in order to balance the time lag between the generation of electrical energy from photovoltaics or wind power and the demand for electrical energy. However, to deploy the technology on a large scale, significant cost reductions are required. A thorough knowledge of the reactions and processes taking place within a redox-flow battery is very helpful for this task and this knowledge can be significantly improved by using a suitable mathematical model to describe the processes in a single cell of a redox-flow battery. Nevertheless, this requires a valid model that has been compared with experimental data and that can reproduce these data plausibly and validly. In this thesis, the validation of a two-dimensional model for the description of potential and current density distributions in the porous electrodes of a vanadium redox-flow battery is presented, taking into account effects of kinetics and mass transport. Newly developed potential probes are used for in-situ measurement of solid and liquid phase potentials within a single cell of a vanadium redox-flow battery. The description of the measured cell voltage and potential probe signals by the model reveals a good congruence between the model and the experimental data, so the model can be regarded as valid. Additional suggestions for improvements of the model and the implementation of further models describing membrane crossover effects or electrolyte properties are given.
Author: Mayank Kale
Publisher: GRIN Verlag
ISBN: 3346228320
Category : Science
Languages : en
Pages : 73
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Book Description
Master's Thesis from the year 2020 in the subject Engineering - Power Engineering, grade: 9.0, Indian Institute of Technology, Bombay, language: English, abstract: There is a drastic capacity increase in the ocean, solar, and wind power based energy generation in recent years. Moreover, a larger increase is predicted in future years. Hence, we need a reliable, efficient, and cost-effective energy storage system to match up with the intermittent nature of renewable energy sources. Vanadium redox flow batteries are a promising option and are fast approaching commercialization owing to their unique characteristics like including independent scaling of power and energy density. However, there are various losses associated with the membrane, electrodes, and also due to mass transfer which limit its performance and further decrease battery capacity and efficiency. The first part of this study focusses on membrane thickness, mass transfer coefficients, electrode morphology, and current density to analyze the performance of the battery. The latter part describes the effect of flow rate on concentration overpotential, pressure losses, and pumping power to come up with an optimal variable flow rate strategy to maximize the battery capacity and system efficiency.
Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 5
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Book Description
Vanadium redox flow batteries (VRBs) are competitive for large energy storage systems due to low manufacture and maintenance costs and high design flexibility. Electrolyte flow rates have significant influence on the performance and efficiencies of the batteries. High electrolyte flow rates improve energy efficiency while degrade the battery efficiency due to high pump power losses. Thus, flow rates are necessary to be optimized for battery efficiency improvement. In this paper, an electrochemical model is firstly proposed to describe the charge-discharge characteristics based on the experimental data. Then, an empirical method is introduced to analyze the energy consumption of pumps under various flow rates. The optimal flow rates are obtained by applying new criteria. The results show that VRBs obtain peak battery efficiencies at the optimal flow rates around 90cm3s−1 with respect to the proposed battery configuration. The optimal flow rates are provided as a reference for battery operations and control.
Author: Sebastian König
Publisher: Cuvillier Verlag
ISBN: 3736986157
Category : Technology & Engineering
Languages : en
Pages : 182
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Book Description
In this work, a holistic approach is used to develop a multi-physical model of the Vanadium Redox Flow Battery on a system level. The model is validated with experimental data from three flow battery manufacturers and is then deployed in an extensive parameter study for designing a flow battery cell. Using finite element analysis (FEA), twenty-four different cell designs are derived, which vary in electrode area and the design of the electrolyte inlet and outlet supply channels. The performance of the designs is then simulated in a single-stack and a three-stack string system. The presented model is also deployed in a flow rate optimization study. Here, a novel strategy involving the model-based optimization of operation-points defined by state-of-charge and charging or discharging current is presented and compared to conventional flow rate control strategies. Finally, a stack voltage controller is introduced, which prevents the violation of cell voltage limits as long as the pump capacity is not fully utilized.
Author: Ryan O'Hayre
Publisher: John Wiley & Sons
ISBN: 1119113806
Category : Science
Languages : en
Pages : 612
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Book Description
A complete, up-to-date, introductory guide to fuel cell technology and application Fuel Cell Fundamentals provides a thorough introduction to the principles and practicalities behind fuel cell technology. Beginning with the underlying concepts, the discussion explores fuel cell thermodynamics, kinetics, transport, and modeling before moving into the application side with guidance on system types and design, performance, costs, and environmental impact. This new third edition has been updated with the latest technological advances and relevant calculations, and enhanced chapters on advanced fuel cell design and electrochemical and hydrogen energy systems. Worked problems, illustrations, and application examples throughout lend a real-world perspective, and end-of chapter review questions and mathematical problems reinforce the material learned. Fuel cells produce more electricity than batteries or combustion engines, with far fewer emissions. This book is the essential introduction to the technology that makes this possible, and the physical processes behind this cost-saving and environmentally friendly energy source. Understand the basic principles of fuel cell physics Compare the applications, performance, and costs of different systems Master the calculations associated with the latest fuel cell technology Learn the considerations involved in system selection and design As more and more nations turn to fuel cell commercialization amidst advancing technology and dropping deployment costs, global stationary fuel cell revenue is expected to grow from $1.4 billion to $40.0 billion by 2022. The sector is forecasted to explode, and there will be a tremendous demand for high-level qualified workers with advanced skills and knowledge of fuel cell technology. Fuel Cell Fundamentals is the essential first step toward joining the new energy revolution.
