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Author: Nico M. van Os
Publisher: CRC Press
ISBN: 9780824799977
Category : Science
Languages : en
Pages : 322
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Book Description
Discusses the laboratory and industrial synthesis of nonionic surfactants. Furnishes exhaustive coverage of the most recent advances in nonionic surfactant organic chemistry. Analyzes a novel class of catalysts for the production of surfactants with highly narrow distributions.
Author: Nico M. van Os
Publisher: CRC Press
ISBN: 9780824799977
Category : Science
Languages : en
Pages : 322
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Book Description
Discusses the laboratory and industrial synthesis of nonionic surfactants. Furnishes exhaustive coverage of the most recent advances in nonionic surfactant organic chemistry. Analyzes a novel class of catalysts for the production of surfactants with highly narrow distributions.
Author: Martin J. Schick
Publisher: CRC Press
ISBN: 9780824775308
Category : Science
Languages : en
Pages : 1166
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Book Description
Author: Vaughn Nace
Publisher: CRC Press
ISBN: 9780824797003
Category : Science
Languages : en
Pages : 286
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Book Description
Focuses on copolymers made from sequential block polymerizations of ethylene oxide, propylene oxide and 1, 2-butylene oxide. This text presents the latest applications of polyoxyalkylene block copolymers in areas such as medicine, coal and petroleum, plastics, emulsion polymerization, paper, photography, personal care and cleaner systems. It offers in-depth coverage of the subject from synthesis and analysis to toxicology and environmental impact.
Author: Dieter Balzer
Publisher: CRC Press
ISBN: 9780824793906
Category : Science
Languages : en
Pages : 560
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Book Description
This volume provides a comprehensive overview for recognizing and producing the characteristics of successful special surfactant agents. It highlights one of the most versatile and effective surface-active surfactant agents, detailing the synthesis and production, chemical properties and behaviours, and application for alkyl polyglucosides.
Author: Thomas M. Schmitt
Publisher: CRC Press
ISBN: 9780203908556
Category : Science
Languages : en
Pages : 662
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Book Description
In the tradition of the popular first edition, Analysis of Surfactants, Second Edition offers a comprehensive and practical account of analysis methods for determining and understanding commercially important surfactants-individually and in compounds. Combining a complete review of the literature with a variety of evaluation procedures and the specifications for commercial products, this useful reference explores the key stages and latest developments for surfactant applications. This edition has been thoroughly expanded and features new sections on capillary electrophoresis, ether carboxylates, and ester quats. It is also more globally accessible with foreign language citations and SI units. Containing over 2400 references, drawings, tables, and equations, Analysis of Surfactants, Second Edition is an recommended reference for physical, surface, colloid, and oil chemists; analytical, research, and quality assurance chemists working in the soap and detergent, pharmaceuticals, and cosmetic industries; regulatory and food scientists; and upper-level undergraduate and graduate students in these disciplines.
Author: N.M. van Os
Publisher: Elsevier
ISBN: 0444600280
Category : Technology & Engineering
Languages : en
Pages : 627
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Book Description
The number of physico-chemical investigations of surfactants in solution, whether aqueous or nonaqueous, has dramatically increased in recent years. However, literature reports on surfactants in solutions are scattered over a plethora of scientific journals and books which differ widely in scope and readership. Such data are often difficult to retrieve because there have been no systematic compilations, with the exception of those for CMCs and for micelle aggregation numbers. The present compilation meets that need by covering, as completely as possible, the physico-chemical properties of selected series of homologous surfactants. These surfactants are in most cases isomerically pure, are well-known, and have been used in numerous academic and industrial studies. The properties include aggregation number, cloud point, CMC, 13C-NMR, correlation length, counterion binding, density, enthalpy of micelle formation, entropy of micelle formation, Gibbs' free energy of micelle formation, head group area, 1H-NMR, hydration number, Krafft temperature, melting point, micelle radius, microscopic viscosity, miscibility curve, partial molar volume, phase inversion temperature, refractive index, self-diffusion coefficient, surface tension, and upper critical temperature. The book also contains two- and three-component phase diagrams of many nonionic surfactants. The solvent is water in most cases; however, some data refer to properties in D2O, electrolyte solutions, and nonaqueous solvents. The variables are temperature and concentration. Where possible, the method of measurement is given. Data on the purity of the compounds and the accuracy of the measurement methods are not included, as these can easily be found in the original sources, which mostly date from the period 1970-1991 and are given at the end of each chapter. The Index section contains a compound index, a property index, a symbol index and a cross index which facilitate easy access to the data. This valuable collection of data will be of great use to anyone involved in Colloid and Surface Science, academics as well as industrial workers, and will stimulate further work.
Author: D.R. Karsa
Publisher: Springer Science & Business Media
ISBN: 0751402060
Category : Technology & Engineering
Languages : en
Pages : 278
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Book Description
The awareness and development of 'biodegradable' surfactants pre-dates current pressures by the environmental movement by nearly three decades, wherein a responsible industry mutually agreed to replace 'hard', non-biodegradable com ponents of household detergents by 'soft', biodegradable alternatives, without course to legislation. The only requirement at that time was for surfactants used in detergents to exhibit a 'primary biodegradability' in excess of 80%; this referring to the disap pearance or removal from solution of the intact surface active material as de tected by specified analytical techniques. This proved useful, as observed environmental impacts of surfactants, e.g. visible foam on rivers, are associated with the intact molecule. Test methods for 'primary biodegradability' were eventually enshrined in EU legislation for nonionic surfactants (Directive 821242/EEC, amended 73/404IEEC) and for anionic surfactants (Directive 8212431EEC, amended 73/405IEEC). No approved test methods and resultant legislation have been developed for cationic and amphoteric surfactants to date. The environmental classification of chemical substances, which of course includes surfactants, and associated risk assessment utilises a second criterion 'ready biodegradability'. This may be assessed by a number of methods which monitor oxygen uptake (BOD), carbon dioxide production or removal of dis solved organic carbon (DOC). Some surfactants which comply with the above Detergents Directive are borderline when it comes to 'ready biodegradability'.
Author: Scot Philip Sandoval
Publisher:
ISBN:
Category : Chalcopyrite
Languages : en
Pages : 362
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Book Description
Author: Ash Michael
Publisher: Routledge
ISBN: 0429603509
Category : Social Science
Languages : en
Pages : 2532
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Book Description
Originally published in 1993, over 16,000 tradename surface-active agents for industrial applications, manufactured worldwide, are contained in this edition. General-use surfactants, such as emulsifiers, wetting agents, foaming agents, detergents, dispersants, and solubilizers are included, as well as detergent raw materials, defoamers, and antifoaming agents. The types and quantities of surfactants available commercially are numerous and the difficulty in making choices between products may become overwhelming. It is the purpose of this book to guide those who are involved in the selection of these materials through the procecss of identifying, classifying, and selecting the most appropriate products for their requirements. Therefore, this reference is organized so that the user can search for and locate products based on a variety of essential distinguishing attributes.
Author: Sylvia S. Talmage
Publisher: CRC Press
ISBN: 0429610629
Category : Political Science
Languages : en
Pages : 387
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Book Description
The book summarizes and reviews the environmental and human safety of two classes of nonionic surfactants-alcohol ethoxylates (AE) and alkylphenol ethoxylates (APE). This unique resource contains critical data from published sources as well as from unpublished studies submitted by Soap and Detergent Association member companies. It reviews information on product chemistry and analysis, biodegradation, environmental levels (including fate and distribution), aquatic toxicity, and human safety. Recently developed analytical techniques for the extraction, separation, detection, and measurement of nonionic surfactants and their metabolites in environmental samples are described. Results of biodegradation studies performed with a variety of test systems are tabulated, as are results of field studies at wastewater treatment plants. Reported comparisons of environmental levels with results of acute and chronic aquatic toxicity tests are provided. The information on the toxicity and irritation potential of AE and APE surfactants includes data from in vitro, mammalian, and human studies.
