New Solid Acids and Bases

New Solid Acids and Bases PDF Author: K. Tanabe
Publisher: Elsevier
ISBN: 0080887554
Category : Technology & Engineering
Languages : en
Pages : 381

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Book Description
This volume summarises and reviews the enormous progress made over the past two decades in solid acids and bases, with emphasis on fundamental aspects and chemical principles. In recent years many new kinds of solid acids and bases have been found and synthesized. The surface properties (in particular, acidic and basic properties) and the structures of the new solids have been clarified by newly developed measurement methods using modern instruments and techniques. The characterized solid acids and bases have been applied as catalysts for diversified reactions, many good correlations being obtained between the acid-base properties and the catalytic activities or selectivities. Recently, acid-base bifunctional catalysis on solid surfaces is becoming a more and more important and intriguing field of study.It has been recognized that the acidic and basic properties of catalysts and catalyst supports play an important role in oxidation, reduction, hydrogenation, hydrocracking, etc. The effect of the preparation method and the pretreatment conditions of solid acids and bases on the acidic and basic properties, the nature of acidic and basic sites and the mechanism regarding the generation of acidity and basicity have been elucidated experimentally and theoretically. On the basis of the accumulated knowledge of solid acids and bases, it is now possible to design and develop highly active and selective solid acid and base catalysts for particular reactions. The chemistry of solid acids and bases is now being related to and utilized in numerous areas including adsorbents, sensors, cosmetics, fuel cells, sensitized pressed papers, and others. The information presented in this book will therefore be of interest to a wide-ranging readership.

New Solid Acids and Bases

New Solid Acids and Bases PDF Author: K. Tanabe
Publisher: Elsevier
ISBN: 0080887554
Category : Technology & Engineering
Languages : en
Pages : 381

Get Book Here

Book Description
This volume summarises and reviews the enormous progress made over the past two decades in solid acids and bases, with emphasis on fundamental aspects and chemical principles. In recent years many new kinds of solid acids and bases have been found and synthesized. The surface properties (in particular, acidic and basic properties) and the structures of the new solids have been clarified by newly developed measurement methods using modern instruments and techniques. The characterized solid acids and bases have been applied as catalysts for diversified reactions, many good correlations being obtained between the acid-base properties and the catalytic activities or selectivities. Recently, acid-base bifunctional catalysis on solid surfaces is becoming a more and more important and intriguing field of study.It has been recognized that the acidic and basic properties of catalysts and catalyst supports play an important role in oxidation, reduction, hydrogenation, hydrocracking, etc. The effect of the preparation method and the pretreatment conditions of solid acids and bases on the acidic and basic properties, the nature of acidic and basic sites and the mechanism regarding the generation of acidity and basicity have been elucidated experimentally and theoretically. On the basis of the accumulated knowledge of solid acids and bases, it is now possible to design and develop highly active and selective solid acid and base catalysts for particular reactions. The chemistry of solid acids and bases is now being related to and utilized in numerous areas including adsorbents, sensors, cosmetics, fuel cells, sensitized pressed papers, and others. The information presented in this book will therefore be of interest to a wide-ranging readership.

Solid Acids and Bases

Solid Acids and Bases PDF Author: Kozo Tanabe
Publisher: Academic Press
ISBN:
Category : Science
Languages : en
Pages : 192

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Book Description
Solid Acids and Bases: Their Catalytic Properties reviews developments in the studies of acidic and basic properties of solids, including the efficacy and special characteristics of solid acid and base catalysts. This book discusses the determination of basic and acidic properties on solid surfaces and relationship between acid strength and acid amount. The structure and acid-base properties of mixed metal oxides and correlation between acid-base properties and catalytic activity and selectivity are also deliberated. This publication is useful to professional chemists and graduate students in the fields of organic, inorganic and physical chemistry, petroleum chemistry and catalysis, including readers interested in the acidic and basic properties on solid surfaces.

Solid Acids and Bases

Solid Acids and Bases PDF Author: Kozo Tanabe
Publisher: Elsevier
ISBN: 0323160581
Category : Science
Languages : en
Pages : 184

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Book Description
Solid Acids and Bases: Their Catalytic Properties reviews developments in the studies of acidic and basic properties of solids, including the efficacy and special characteristics of solid acid and base catalysts. This book discusses the determination of basic and acidic properties on solid surfaces and relationship between acid strength and acid amount. The structure and acid-base properties of mixed metal oxides and correlation between acid-base properties and catalytic activity and selectivity are also deliberated. This publication is useful to professional chemists and graduate students in the fields of organic, inorganic and physical chemistry, petroleum chemistry and catalysis, including readers interested in the acidic and basic properties on solid surfaces.

New Solid Acids and Bases

New Solid Acids and Bases PDF Author: Kōzō Tanabe
Publisher:
ISBN: 9784062043946
Category : Acids
Languages : en
Pages : 365

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Book Description


Solid Base Catalysis

Solid Base Catalysis PDF Author: Yoshio Ono
Publisher: Springer Science & Business Media
ISBN: 3642183395
Category : Science
Languages : en
Pages : 431

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Book Description
The importance of solid base catalysts has come to be recognized for their environmentally benign qualities, and much significant progress has been made over the past two decades in catalytic materials and solid base-catalyzed reactions. The book is focused on the solid base. Because of the advantages over liquid bases, the use of solid base catalysts in organic synthesis is expanding. Solid bases are easier to dispose than liquid bases, separation and recovery of products, catalysts and solvents are less difficult, and they are non-corrosive. Furthermore, base-catalyzed reactions can be performed without using solvents and even in the gas phase, opening up more possibilities for discovering novel reaction systems. Using numerous examples, the present volume describes the remarkable role solid base catalysis can play, given the ever increasing worldwide importance of "green" chemistry. The reader will obtain an overall view of solid base catalysis and gain insight into the versatility of the reactions to which solid base catalysts can be utilized. The concept and significance of solid base catalysis are discussed, followed by descriptions of various methods for the characterization of solid bases, including spectroscopic methods and test reactions. The preparation and properties of base materials are presented in detail, with the two final chapters devoted to surveying the variety of reactions catalyzed by solid bases.

New Solid Acids and Bases

New Solid Acids and Bases PDF Author:
Publisher:
ISBN: 9780444418012
Category : Acids
Languages : en
Pages : 365

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Book Description


Solid Acid Catalysis

Solid Acid Catalysis PDF Author: Hideshi Hattori
Publisher: CRC Press
ISBN: 9814463299
Category : Science
Languages : en
Pages : 511

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Book Description
Solids that possess acidic properties on their surfaces function as catalysts just like liquid acids, such as sulfuric acid and hydrochloric acid. By using solid acid catalysts, chemical processes become more productive and more environmentally friendly. In fact, solid acids are being used in many industrial chemical processes from the largest chem

Catalysis by Acids and Bases

Catalysis by Acids and Bases PDF Author: B. Imelik
Publisher: Elsevier
ISBN: 0080960545
Category : Technology & Engineering
Languages : en
Pages : 461

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Book Description
Because of the great importance of acid catalysis in the petrochemical industry, extensive research has been carried out during the last 30 years concerning the fundamental and applied aspects of catalysis by acids. In contrast, base-catalyzed reactions have received little attention in heterogeneous catalysis. The aim of this symposium was to evaluate our knowledge of the important area of acid and base catalysis and to cover a broad range of solids, zeolite chemistry being only one aspect of heterogeneous catalysis.

Solid Superacids

Solid Superacids PDF Author: Kazushi Arata
Publisher:
ISBN: 9781612096490
Category : Superacids
Languages : en
Pages : 0

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Book Description
An acid that is stronger than the acid strength of 100% sulphuric acid is known as a superacid. Environmental concerns about the use of toxic liquid superacids and liquid inorganic acids in the transformation of hydrocarbons provide an impetus for a search of stable and more environmentally friendly solid acid catalysts. This book examines an important opportunity related to green chemistry where solid superacids lead to new gas- and liquid-solid phase reactions, which are environmentally benign processes in the chemical industry.

Solid Base Catalysts

Solid Base Catalysts PDF Author: K. K. Pant
Publisher: John Wiley & Sons
ISBN: 3527353763
Category : Science
Languages : en
Pages : 386

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Book Description
Foundational knowledge and practical approaches of an interesting catalyst class for greener and cleaner chemical synthesis Solid Base Catalysts provides insights and information on cutting-edge heterogeneous catalysis technologies and approaches of non-corrosive and easy-to-use solid catalysts that can replace conventional liquid catalysts that are known to pose operational problems. Edited by three highly qualified authors with contributions from experts in industry and academia, Solid Base Catalysts includes: Latest and most advanced studies in the characterization of solid catalysts, with applications in various organic transformations Versatile reaction types where solid catalysts can be used as well as the multidisciplinary nature of solid base catalyst research and its connections to other fields Multicomponent reactions for eco-compatible heterocyclic synthesis over solid catalysts and synthesis routes, experimental protocols, and other considerations for optimizing catalyst properties Advanced methodologies and applications for analyzing solid catalysts and challenges and future prospects in the field Solid Base Catalysts is a complete reference on the subject for researchers and professionals in materials science, green chemistry, surface chemistry, and chemical engineering.