Author: V.V. Brazhkin
Publisher: Springer Science & Business Media
ISBN: 9781402008252
Category : Medical
Languages : en
Pages : 686
Book Description
Proceedings of the NATO Advanced Research Workshop, held in Volga River, Russia, 24-28 May 2001
New Kinds of Phase Transitions: Transformation in Disordered Substances
Author: V.V. Brazhkin
Publisher: Springer Science & Business Media
ISBN: 9781402008252
Category : Medical
Languages : en
Pages : 686
Book Description
Proceedings of the NATO Advanced Research Workshop, held in Volga River, Russia, 24-28 May 2001
Publisher: Springer Science & Business Media
ISBN: 9781402008252
Category : Medical
Languages : en
Pages : 686
Book Description
Proceedings of the NATO Advanced Research Workshop, held in Volga River, Russia, 24-28 May 2001
New Kinds of Phase Transitions: Transformations in Disordered Substances
Author: V.V. Brazhkin
Publisher: Springer
ISBN: 9781402008269
Category : Science
Languages : en
Pages : 649
Book Description
Phase transitions are involved in phenomena ranging from the initial stages of the creation of the Universe to the existence of biological objects. It is natural to as whether any phenomena analogous to phase transitions are possible in disordered substances like liquids and glasses. The possibility of such transitions is still very much a matter of debate. Neither the nature nor the features of transformations in liquids and glasses are yet clear, nor is the nature of the order parameters. Investigations in recent years have shown that transformations in liquids and glasses lead to a drastic change of their physical properties and short-range order structure. The papers collected here contribute to a better understanding of the physics of disordered systems and phase transformations in them. An unambiguous identification of transitions in liquids and glasses requires further high-precision experimental study of the thermodynamic and structural properties in the vicinity of transitions in order to test existing theoretical models and develop new, more accurate ones.
Publisher: Springer
ISBN: 9781402008269
Category : Science
Languages : en
Pages : 649
Book Description
Phase transitions are involved in phenomena ranging from the initial stages of the creation of the Universe to the existence of biological objects. It is natural to as whether any phenomena analogous to phase transitions are possible in disordered substances like liquids and glasses. The possibility of such transitions is still very much a matter of debate. Neither the nature nor the features of transformations in liquids and glasses are yet clear, nor is the nature of the order parameters. Investigations in recent years have shown that transformations in liquids and glasses lead to a drastic change of their physical properties and short-range order structure. The papers collected here contribute to a better understanding of the physics of disordered systems and phase transformations in them. An unambiguous identification of transitions in liquids and glasses requires further high-precision experimental study of the thermodynamic and structural properties in the vicinity of transitions in order to test existing theoretical models and develop new, more accurate ones.
Reconstructive Phase Transitions
Author: Pierre Toldano
Publisher: World Scientific
ISBN: 9789810223649
Category : Science
Languages : en
Pages : 424
Book Description
This book deals with the phenomenological theory of first-order structural phase transitions, with a special emphasis on reconstructive transformations in which a group-subgroup relationship between the symmetries of the phases is absent. It starts with a unified presentation of the current approach to first-order phase transitions, using the more recent results of the Landau theory of phase transitions and of the theory of singularities. A general theory of reconstructive phase transitions is then formulated, in which the structures surrounding a transition are expressed in terms of density-waves, providing a natural definition of the transition order-parameters, and a description of the corresponding phase diagrams and relevant physical properties. The applicability of the theory is illustrated by a large number of concrete examples pertaining to the various classes of reconstructive transitions: allotropic transformations of the elements, displacive and order-disorder transformations in metals, alloys and related structures, crystal-quasicrystal transformations.
Publisher: World Scientific
ISBN: 9789810223649
Category : Science
Languages : en
Pages : 424
Book Description
This book deals with the phenomenological theory of first-order structural phase transitions, with a special emphasis on reconstructive transformations in which a group-subgroup relationship between the symmetries of the phases is absent. It starts with a unified presentation of the current approach to first-order phase transitions, using the more recent results of the Landau theory of phase transitions and of the theory of singularities. A general theory of reconstructive phase transitions is then formulated, in which the structures surrounding a transition are expressed in terms of density-waves, providing a natural definition of the transition order-parameters, and a description of the corresponding phase diagrams and relevant physical properties. The applicability of the theory is illustrated by a large number of concrete examples pertaining to the various classes of reconstructive transitions: allotropic transformations of the elements, displacive and order-disorder transformations in metals, alloys and related structures, crystal-quasicrystal transformations.
Fundamentals of Solid-State Phase Transitions, Ferromagnetism and Ferroelectricity
Author: Yuri Mnyukh
Publisher: Directscientific Press
ISBN: 9780615339726
Category : Technology & Engineering
Languages : en
Pages : 338
Book Description
The author's experimental discoveries in the field of solid-state phase transitions have brought about a thorough explanation of this phenomenon, including the puzzling nature of "lamda-anomalies." These phase transitions are found to be always a nucleation and crystal growth in a solid medium, while "second (or higher) order" phase transitions are a misconception: they do not exist. Ramifications of this new understanding are substatial. In this book the reader will find the first unified account for fundamentals of the three great areas of solid-state physics? Phase transitions, ferromagnetism and ferroelectricity, free of the inconsistencies of the conventional theories.
Publisher: Directscientific Press
ISBN: 9780615339726
Category : Technology & Engineering
Languages : en
Pages : 338
Book Description
The author's experimental discoveries in the field of solid-state phase transitions have brought about a thorough explanation of this phenomenon, including the puzzling nature of "lamda-anomalies." These phase transitions are found to be always a nucleation and crystal growth in a solid medium, while "second (or higher) order" phase transitions are a misconception: they do not exist. Ramifications of this new understanding are substatial. In this book the reader will find the first unified account for fundamentals of the three great areas of solid-state physics? Phase transitions, ferromagnetism and ferroelectricity, free of the inconsistencies of the conventional theories.
Liquid Polymorphism, Volume 152
Author: H. Eugene Stanley
Publisher: John Wiley & Sons
ISBN: 1118540379
Category : Science
Languages : en
Pages : 544
Book Description
The Advances in Chemical Physics series the cutting edge of research in chemical physics The Advances in Chemical Physics series provides the chemical physics and physical chemistry fields with a forum for critical, authoritative evaluations of advances in every area of the discipline. Filled with cutting-edge research reported in a cohesive manner not found elsewhere in the literature, each volume of the Advances in Chemical Physics series presents contributions from internationally renowned chemists and serves as the perfect supplement to any advanced graduate class devoted to the study of chemical physics. This volume explores: Electron Spin Resonance Studies of Supercooled Water Water-like Anomalies of Core-Softened Fluids: Dependence on the Trajectories in (P, ρ, T) Space Water Proton Environment: A New Water Anomaly at Atomic Scale? Polymorphism and Anomalous Melting in Isotropic Fluids Computer Simulations of Liquid Silica: Water-Like Thermodynamic and Dynamic Anomalies, and the Evidence for Polyamorphism
Publisher: John Wiley & Sons
ISBN: 1118540379
Category : Science
Languages : en
Pages : 544
Book Description
The Advances in Chemical Physics series the cutting edge of research in chemical physics The Advances in Chemical Physics series provides the chemical physics and physical chemistry fields with a forum for critical, authoritative evaluations of advances in every area of the discipline. Filled with cutting-edge research reported in a cohesive manner not found elsewhere in the literature, each volume of the Advances in Chemical Physics series presents contributions from internationally renowned chemists and serves as the perfect supplement to any advanced graduate class devoted to the study of chemical physics. This volume explores: Electron Spin Resonance Studies of Supercooled Water Water-like Anomalies of Core-Softened Fluids: Dependence on the Trajectories in (P, ρ, T) Space Water Proton Environment: A New Water Anomaly at Atomic Scale? Polymorphism and Anomalous Melting in Isotropic Fluids Computer Simulations of Liquid Silica: Water-Like Thermodynamic and Dynamic Anomalies, and the Evidence for Polyamorphism
Pressure-Induced Phase Transitions in AB2X4 Chalcogenide Compounds
Author: Francisco Javier Manjon
Publisher: Springer Science & Business Media
ISBN: 3642403670
Category : Technology & Engineering
Languages : en
Pages : 248
Book Description
This book on pressure-induced phase transitions in AB2X4 chalcogenide compounds deals with one important AmBnXp material. The interest in these materials is caused by their properties. The results are discussed for three main groups of structural families: cubic-spinel structures, defective tetragonal structures, and other structures like layered and wurtzite-type modifications. A systematic analysis of the behavior of cubic (spinel), tetragonal (defect chalcopyrites and stannites) and other crystal modifications of AB2X4 compounds under hydrostatic pressure is performed. The behavior of AIIAl2S4, AIIGa2S4, AIIAl2Se4 and AIIGa2Se4 compounds with defective tetragonal structures, compounds with layered and wurtzite structures under hydrostatic pressure and the pressure dependence of the band gap, lattice parameters, interatomic distances, vibrational modes and pressure-induced phase transitions is discussed. Many of these compounds, except oxide spinels, undergo a pressure-induced phase transition towards the rocksalt-type structure. The phase transition is preceded by disorder in the cation sublattice. The dependence of the transition pressure to the rocksalt-type structure as a function of the compound ionicity and the size criterion is analyzed. At high pressures, all ordered-vacancy compounds are found to exhibit a band anticrossing between several conduction bands that leads to a strong decrease of its pressure coefficient and consequently to a strong non-linear pressure dependence of the direct bandgap energy. Theoretical studies of phase transitions in several ordered-vacancy compounds reveal that the existence of ordered vacancies alter the cation-anion bond distances and their compressibilities. The book is written for students, Ph D. students and specialists in materials science, phase transitions and new materials.
Publisher: Springer Science & Business Media
ISBN: 3642403670
Category : Technology & Engineering
Languages : en
Pages : 248
Book Description
This book on pressure-induced phase transitions in AB2X4 chalcogenide compounds deals with one important AmBnXp material. The interest in these materials is caused by their properties. The results are discussed for three main groups of structural families: cubic-spinel structures, defective tetragonal structures, and other structures like layered and wurtzite-type modifications. A systematic analysis of the behavior of cubic (spinel), tetragonal (defect chalcopyrites and stannites) and other crystal modifications of AB2X4 compounds under hydrostatic pressure is performed. The behavior of AIIAl2S4, AIIGa2S4, AIIAl2Se4 and AIIGa2Se4 compounds with defective tetragonal structures, compounds with layered and wurtzite structures under hydrostatic pressure and the pressure dependence of the band gap, lattice parameters, interatomic distances, vibrational modes and pressure-induced phase transitions is discussed. Many of these compounds, except oxide spinels, undergo a pressure-induced phase transition towards the rocksalt-type structure. The phase transition is preceded by disorder in the cation sublattice. The dependence of the transition pressure to the rocksalt-type structure as a function of the compound ionicity and the size criterion is analyzed. At high pressures, all ordered-vacancy compounds are found to exhibit a band anticrossing between several conduction bands that leads to a strong decrease of its pressure coefficient and consequently to a strong non-linear pressure dependence of the direct bandgap energy. Theoretical studies of phase transitions in several ordered-vacancy compounds reveal that the existence of ordered vacancies alter the cation-anion bond distances and their compressibilities. The book is written for students, Ph D. students and specialists in materials science, phase transitions and new materials.
FlexPDE and Finite Element Method Applications in Thermal Energy Storage and Cavities
Author: Hosseinzadeh, Khashayar
Publisher: IGI Global
ISBN:
Category : Technology & Engineering
Languages : en
Pages : 389
Book Description
Academic scholars are increasingly confronted with the complex challenges of understanding and optimizing heat transfer processes, particularly in the areas of cavities and Phase Change Materials (PCM). These issues are central to a range of crucial applications, including building systems, electronic equipment, and the harnessing of solar energy. The need for innovative solutions to enhance heat transfer efficiency is more pressing than ever, and a comprehensive resource to guide scholars through these complexities is essential. FlexPDE and Finite Element Method Applications in Thermal Energy Storage and Cavities is research book specifically designed to provide scholars with the knowledge and expertise necessary to navigate the complexities of heat transfer issues. With a strong emphasis on practical application, the book leverages the capabilities of the Finite Element Method (FEM) through the FLEXPDE software, making it a valuable resource for those seeking innovative solutions to problems in heat transfer.
Publisher: IGI Global
ISBN:
Category : Technology & Engineering
Languages : en
Pages : 389
Book Description
Academic scholars are increasingly confronted with the complex challenges of understanding and optimizing heat transfer processes, particularly in the areas of cavities and Phase Change Materials (PCM). These issues are central to a range of crucial applications, including building systems, electronic equipment, and the harnessing of solar energy. The need for innovative solutions to enhance heat transfer efficiency is more pressing than ever, and a comprehensive resource to guide scholars through these complexities is essential. FlexPDE and Finite Element Method Applications in Thermal Energy Storage and Cavities is research book specifically designed to provide scholars with the knowledge and expertise necessary to navigate the complexities of heat transfer issues. With a strong emphasis on practical application, the book leverages the capabilities of the Finite Element Method (FEM) through the FLEXPDE software, making it a valuable resource for those seeking innovative solutions to problems in heat transfer.
Carbon at High Temperatures
Author: Alexander Savvatimskiy
Publisher: Springer
ISBN: 3319213504
Category : Technology & Engineering
Languages : en
Pages : 257
Book Description
This book deals with the properties and behavior of carbon at high temperatures. It presents new methods and new ways to obtain the liquid phase of carbon. Melting of graphite and the properties of liquid carbon are presented under stationary heat and pulse methods. Metal like properties of molten graphite at high initial density are indicated. A new possible transition of liquid carbon from metal to nonmetal behavior much above the melting point is mentioned. Methodical questions of pulse heating, in particular the role of pinch-pressure in receiving a liquid state of carbon, are discussed. The reader finds evidence about the necessity of applying high pressure (higher than 100 bar) to melt graphite (melting temperature 4800±100 K). The reader can verify the advantage of volume pulse electrical heating before surface laser heating to study the physical properties of carbon, including enthalpy, heat capacity, electrical resistivity and temperature. The advantages of fast heating of graphite by pulsed electric current during a few microseconds are shown. The data obtained for the heat capacity of liquid carbon under constant pressure and constant volume were used to estimate the behavior at temperatures much higher 5000 K.
Publisher: Springer
ISBN: 3319213504
Category : Technology & Engineering
Languages : en
Pages : 257
Book Description
This book deals with the properties and behavior of carbon at high temperatures. It presents new methods and new ways to obtain the liquid phase of carbon. Melting of graphite and the properties of liquid carbon are presented under stationary heat and pulse methods. Metal like properties of molten graphite at high initial density are indicated. A new possible transition of liquid carbon from metal to nonmetal behavior much above the melting point is mentioned. Methodical questions of pulse heating, in particular the role of pinch-pressure in receiving a liquid state of carbon, are discussed. The reader finds evidence about the necessity of applying high pressure (higher than 100 bar) to melt graphite (melting temperature 4800±100 K). The reader can verify the advantage of volume pulse electrical heating before surface laser heating to study the physical properties of carbon, including enthalpy, heat capacity, electrical resistivity and temperature. The advantages of fast heating of graphite by pulsed electric current during a few microseconds are shown. The data obtained for the heat capacity of liquid carbon under constant pressure and constant volume were used to estimate the behavior at temperatures much higher 5000 K.
High-Pressure Physics
Author: John Loveday
Publisher: CRC Press
ISBN: 1439814295
Category : Science
Languages : en
Pages : 342
Book Description
High-pressure science has undergone a revolution in the last 15 years. The development of intense new x-ray and neutron sources, improved detectors, new instrumentation, greatly increased computation power, and advanced computational algorithms have enabled researchers to determine the behavior of matter at static pressures in excess of 400 GPa. Sh
Publisher: CRC Press
ISBN: 1439814295
Category : Science
Languages : en
Pages : 342
Book Description
High-pressure science has undergone a revolution in the last 15 years. The development of intense new x-ray and neutron sources, improved detectors, new instrumentation, greatly increased computation power, and advanced computational algorithms have enabled researchers to determine the behavior of matter at static pressures in excess of 400 GPa. Sh
New Developments in Glassy Nuclear Wasteforms
Author: Michael I. Ojovan
Publisher: Nova Publishers
ISBN: 9781600217838
Category : Science
Languages : en
Pages : 152
Book Description
Based on the authors' recent investigations, this book describes the application of glassy and polyphase composite materials for nuclear waste immobilisation. It introduces immobilisation issues beginning with a short description of nuclear waste types and compositions. Sources of nuclear waste are described including the nuclear fuel cycle, operational and spent nuclear fuel reprocessing waste streams. The glassy waste forms currently being used for high-, intermediate- and low level radioactive waste immobilisation are described. Problems related to immobilisation capacity, process efficiency and long-term radionucleide retention are highlighted. Scientific and technical problems in nuclear waste immobilisation are emphasised in particular long-term waste form stability and durability. Recent developments in advanced nuclear waste forms are described such as glass composite materials (GCM) with higher versatility and waste loading. New immobilisation approaches and technologies are described including advanced cold crucible induction melting (CCM), self sustaining thermochemical immobilisation (SSI), and in-situ self-sintering in deep underground repositories. Long-term durability tests of nuclear waste glasses are outlined and the role of ion-exchange phase in glass corrosion is described in detail.
Publisher: Nova Publishers
ISBN: 9781600217838
Category : Science
Languages : en
Pages : 152
Book Description
Based on the authors' recent investigations, this book describes the application of glassy and polyphase composite materials for nuclear waste immobilisation. It introduces immobilisation issues beginning with a short description of nuclear waste types and compositions. Sources of nuclear waste are described including the nuclear fuel cycle, operational and spent nuclear fuel reprocessing waste streams. The glassy waste forms currently being used for high-, intermediate- and low level radioactive waste immobilisation are described. Problems related to immobilisation capacity, process efficiency and long-term radionucleide retention are highlighted. Scientific and technical problems in nuclear waste immobilisation are emphasised in particular long-term waste form stability and durability. Recent developments in advanced nuclear waste forms are described such as glass composite materials (GCM) with higher versatility and waste loading. New immobilisation approaches and technologies are described including advanced cold crucible induction melting (CCM), self sustaining thermochemical immobilisation (SSI), and in-situ self-sintering in deep underground repositories. Long-term durability tests of nuclear waste glasses are outlined and the role of ion-exchange phase in glass corrosion is described in detail.