Molecular Ions

Molecular Ions PDF Author: Joseph Berkowitz
Publisher: Springer Science & Business Media
ISBN: 1461336643
Category : Science
Languages : en
Pages : 597

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Book Description
The present volume contains contributions presented at the NATO Advanced Study Institute on Molecular Ions held on the island of Kos, Greece, from September 30 to October 10, 1980. The meeting was attended by some 60 participants from 15 different countries. It was the first meeting devoted exclusively to the topic of molecular ions. Its vitality derived from bringing together experts and students from a wide variety of disciplines, whose studies bear upon the structure of molecular ions. The aim of the meeting was to assemble these scientists, representing many countries in Europe and North America, to discuss the advances and capabilities of the various experimental and theoretical approaches and to point out un solved problems and directions for future research. The format, in volving lecturers and students, served as a tutorial. Molecular ions play an important role in very diverse fields of nature such as reactions in the ionosphere, the processes of forma tion of molecules in dense interstellar clouds, and the magnetohydro dynamics of plasmas used for energy generation. Our understanding of the properties of molecular ions, their electronic and geometric structures, has been developing from a variety of sources, as far removed as tickling ions with radiofre quency radiation and smashing them apart at relativistic energies. Various laser techniques are described, and the queen of structural determination, spectroscopy, is well represented. On the instrumen tal side, older techniques have been perfected and new methods have evolved.

Molecular Ions

Molecular Ions PDF Author: Joseph Berkowitz
Publisher: Springer Science & Business Media
ISBN: 1461336643
Category : Science
Languages : en
Pages : 597

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Book Description
The present volume contains contributions presented at the NATO Advanced Study Institute on Molecular Ions held on the island of Kos, Greece, from September 30 to October 10, 1980. The meeting was attended by some 60 participants from 15 different countries. It was the first meeting devoted exclusively to the topic of molecular ions. Its vitality derived from bringing together experts and students from a wide variety of disciplines, whose studies bear upon the structure of molecular ions. The aim of the meeting was to assemble these scientists, representing many countries in Europe and North America, to discuss the advances and capabilities of the various experimental and theoretical approaches and to point out un solved problems and directions for future research. The format, in volving lecturers and students, served as a tutorial. Molecular ions play an important role in very diverse fields of nature such as reactions in the ionosphere, the processes of forma tion of molecules in dense interstellar clouds, and the magnetohydro dynamics of plasmas used for energy generation. Our understanding of the properties of molecular ions, their electronic and geometric structures, has been developing from a variety of sources, as far removed as tickling ions with radiofre quency radiation and smashing them apart at relativistic energies. Various laser techniques are described, and the queen of structural determination, spectroscopy, is well represented. On the instrumen tal side, older techniques have been perfected and new methods have evolved.

Gaseous Molecular Ions

Gaseous Molecular Ions PDF Author: Eugen Illenberger
Publisher: Springer Science & Business Media
ISBN: 9783798508705
Category : Science
Languages : en
Pages : 944

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Book Description
Most of the matter in our solar system, and, probably, within the whole universe, exists in the form of ionized particles. On the other hand, in our natural environ ment, gaseous matter generally consists of neutral atoms and molecules. Only under certain conditions, such as within the path oflightning or in several technical devices (e. g. gas discharges, rocket engines, etc. ) will some of the atoms and molecules be ionized. It is also believed that the chemistry of the earth's troposphere predomi nantly proceeds via reactions between neutral particles. (The complex system of atmospheric chemistry will be treated in one of the forthcoming volumes to this series. ) Why, then, are ions considered so important that hundreds oflaboratories all over the world (including some of the most prestigious) are involved in research pro grams on ions, covering many different facets, from biochemistry to physics? One may obtain as many different answers as there are research groups busy in this field. There is, however, one simple, common feature which makes it attractive to work with ions: since they carry one or more net elementary charges, they can easily be gui ded, focused or separated by appropriate electric and magnetic fields, and, last but not least, they can easily be detected. Apart from these advantages, which are welcome and appreciated by the researcher, the study of molecular ions can provide insight into very fundamental aspects of the general behavior of molecules.

Dissociative Recombination of Molecular Ions with Electrons

Dissociative Recombination of Molecular Ions with Electrons PDF Author: Steven L. Guberman
Publisher: Springer
ISBN: 9781461349150
Category : Science
Languages : en
Pages : 0

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Book Description
Dissociative Recombination of Molecular Ions with Electrons is a comprehensive collection of refereed papers describing the latest developments in dissociative recombination research. The papers are written by the leading researchers in the field. The topics covered include the use of microwave afterglows, merged beams and storage rings to measure rate coefficients and to identify the products and their yields. The molecules studied range in size from the smallest, H2+, to bovine insulin ions. The theoretical papers cover the important role of Rydberg states and the use of wave packets and quantum defect theory to deduce cross sections, rate constants and quantum yields. Several theoretical and experimental papers address the controversial topic of H3+ dissociative recombination and its importance in the interstellar medium. Dissociative recombination studies of other molecular ions in the interstellar medium and in cometary and planetary atmospheres are covered. Ionization is an important competitive process to dissociative recombination and its competition with predissociation and its role in the reverse process of the association of neutral species is presented. Dissociative attachment, in which an electron attaches to a neutral molecule, has many similarities to dissociative recombination. The topics covered include the accurate calculation of electron affinities, attachment to molecules, clusters, and to species absorbed on solid surfaces and electron scattering by a molecular anion.

Reference Data on Atoms, Molecules, and Ions

Reference Data on Atoms, Molecules, and Ions PDF Author: A.A. Radzig
Publisher: Springer Science & Business Media
ISBN: 3642820484
Category : Science
Languages : en
Pages : 475

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Book Description
This reference book contains information about the structure and properties of atomic and molecular particles, as well as some of the nuclear parameters. It includes data which can be of use when studying atomic and molecular processes in the physics of gases, chemistry of gases and gas optics, in plasma physics and plasma chemistry, in physical chemistry and radiation chemistry, in geophysics, astrophysics, solid-state physics and a variety of cross-discipli nary fields of science and technology. Our aim was to collect carefully selected and estimated numerical values for a wide circle of microscopic parameters in a relatively "not thick" book. These values are of constant use in the work of practical investigators. In essence, the book represents a substantially revised and extended edi tion of our reference book published in Russian in 1980. Two main reasons made it necessary to rework the material. On the one hand, a great deal of new high-quality data has appeared in the past few years and furthermore we have enlisted many sources of information previously inaccessible to us. On the other hand, we have tried to insert extensive information on new, rapidly progressing branches of physical research, such as multiply charged ions, Rydberg atoms, van der Waals and excimer molecules, complex ions, etc. All this brings us to the very edge of studies being carried out in the field.

Molecular Biology of the Cell

Molecular Biology of the Cell PDF Author:
Publisher:
ISBN: 9780815332183
Category : Cells
Languages : en
Pages : 0

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Book Description


Plasma Physics and Engineering

Plasma Physics and Engineering PDF Author: Alexander Fridman
Publisher: CRC Press
ISBN: 9781560328483
Category : Science
Languages : en
Pages : 888

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Book Description
Plasma engineering is a rapidly expanding area of science and technology with increasing numbers of engineers using plasma processes over a wide range of applications. An essential tool for understanding this dynamic field, Plasma Physics and Engineering provides a clear, fundamental introduction to virtually all aspects of modern plasma science and technology, including plasma chemistry and engineering, combustion, chemical physics, lasers, electronics, methods of material treatment, fuel conversion, and environmental control. The book contains an extensive database on plasma kinetics and thermodynamics, many helpful numerical formulas for practical calculations, and an array of problems and concept questions.

Cold-Ion Populations and Cold-Electron Populations in the Earth’s Magnetosphere and Their Impact on the System, 2nd edition

Cold-Ion Populations and Cold-Electron Populations in the Earth’s Magnetosphere and Their Impact on the System, 2nd edition PDF Author: Joseph E. Borovsky
Publisher: Frontiers Media SA
ISBN: 2832522491
Category : Science
Languages : en
Pages : 223

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Book Description
Cold-ion populations and cold-electron populations are extremely difficult to measure in the Earth’s magnetosphere, and their properties, evolutions, and controlling factors are poorly understood. They are sometimes referred to as the “hidden populations”. But they are known to have multiple impacts on the behavior of the global magnetospheric system. These impacts include (a) the reduction of the dayside reconnection rate and consequently the reduction of solar-wind/magnetosphere coupling, (b) alteration of the growth rate and saturation amplitudes of plasma waves resulting in alterations of the energization rates of the radiation belts, (c) changes in plasma-wave properties resulting in changes in the loss rates of the ring current and radiation belts, (d) changes in the mass density of the magnetosphere resulting in changes in the radial diffusion of the radiation belts, (e) spatial and temporal structuring of the aurora, (f) altering magnetotail reconnection, (g) changing spacecraft charging, and (h) acting as sources for warm and hot magnetospheric populations. A recent workshop on the cold-particle populations of the magnetosphere inspired new work on the outstanding problems caused by a lack of understanding of those cold populations. This Research Topic will collect reports of that new work and will stimulate the formation of author teams to write review articles on what is known and what needs to be known. Commentaries assessing the present situation and guiding the research field into the future will be solicited from the community. Methods articles describing new measurement techniques and new spaceflight mission concepts will be welcomed.

Molecular Astrophysics

Molecular Astrophysics PDF Author: Geerd H.F. Diercksen
Publisher: Springer Science & Business Media
ISBN: 9400954328
Category : Science
Languages : en
Pages : 741

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Book Description
and In the IAU Symposium of 1979 devoted to interstellar molecules [8]. Excellent relevant monographs [ 9. 10] . related timely proceedings [ 11] . and recently published elementary textbooks [12. 13] further help to define the pedagogical scope of molecular astrophysics. A significant financial investment has been made in the establishment of ground- and satellite-based observationai facilities for molecuiar astrophysical studies. In the coming years. a wealth of experimental data is bound to accumulate. in which connection close interactions between observers. astrophysical modeliers. and molecular physicists and chemists can play a helpful role in analysis and interpretation. In view of the increasing pace of activity in the field of molecular astrophysics. and in the apparent absence of relevant international meetings since the Liege 1977 and IAU 1979 Symposia. it was deemed appropriate and timely by the organizers to hold a workshop in 1984. Consequently. the NATO Advanced Research Workshop. "Molecular Astrophysics State of the Art and Future Directions". was organized and held at Bad Wlndshelm. West Germany. from 8 to 14 July 1984. The choice of speakers and subject matter of the Workshop was largely subjective. but designed to include most of the generally accepted areas of molecular astrophysical study. Workers from the fields of radio. infrared. and uv-optlcal observations. astrophysical modelling. laboratory spectroscopy. reaction chemistry. collision physics. and theoretical molecular physics and chemistry. were Invited to present survey lectures In their areas of speciality. In addition.

Measurement of the Dissociation Rate of Molecular Ions

Measurement of the Dissociation Rate of Molecular Ions PDF Author: Ch Ottinger
Publisher:
ISBN:
Category : Dissociation
Languages : en
Pages : 52

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Book Description
The time interval between the ionization of a molecule by electron impact and its dissociation was determined from the kinetic energy of the fragment ions. This technique allows a direct differential sampling of the dissociation rate at various times, in contrast to previous, integral methods. The use of disc-shaped molecular beam of 28 micrometers half-width and a draw-out field of 10,000 V/cm in the ionization region resulted in a minimum measured time interval of 7.4 nonoseconds. The longest times measured were between 5 and 6 microseconds. The time dependence of the decomposition rate was measured for two decompositions in butane, five in heptane, three in benzene, one in CD4 and one in CO2(++), with rather similar results. It was established that the decay is not exponential. All decay curves, plotted semi-logarithmically, were found to have an increasing slope towards shorter times, indicating contributions from a variety of rate constants in agreement with the predictions of the statistical theory of ion decompositions.

Mass Spectrometry

Mass Spectrometry PDF Author: Edmond de Hoffmann
Publisher: John Wiley & Sons
ISBN: 047003310X
Category : Science
Languages : en
Pages : 502

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Book Description
The latest edition of a highly successful textbook, Mass Spectrometry, Third Edition provides students with a complete overview of the principles, theories and key applications of modern mass spectrometry. All instrumental aspects of mass spectrometry are clearly and concisely described: sources, analysers and detectors. Tandem mass spectrometry is introduced early on and then developed in more detail in a later chapter. Emphasis is placed throughout the text on optimal utilisation conditions. Various fragmentation patterns are described together with analytical information that derives from the mass spectra. This new edition has been thoroughly revised and updated and has been redesigned to give the book a more contemporary look. As with previous editions it contains numerous examples, references and a series of exercises of increasing difficulty to encourage student understanding. Updates include: Increased coverage of MALDI and ESI, more detailed description of time of flight spectrometers, new material on isotope ratio mass spectrometry, and an expanded range of applications. Mass Spectrometry, Third Edition is an invaluable resource for all undergraduate and postgraduate students using this technique in departments of chemistry, biochemistry, medicine, pharmacology, agriculture, material science and food science. It is also of interest for researchers looking for an overview of the latest techniques and developments.