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Author: Juan Carlos Cuevas
Publisher: World Scientific
ISBN: 9814282588
Category : Science
Languages : en
Pages : 724
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Book Description
This book provides a comprehensive overview of the rapidly developing field of molecular electronics. It focuses on our present understanding of the electrical conduction in single-molecule circuits and provides a thorough introduction to the experimental techniques and theoretical concepts. It will also constitute as the first textbook-like introduction to both the experiment and theory of electronic transport through single atoms and molecules. In this sense, this publication will prove invaluable to both researchers and students interested in the field of nanoelectronics and nanoscience in general. Molecular Electronics is self-contained and unified in its presentation. It may be used as a textbook on nanoelectronics by graduate students and advanced undergraduates studying physics and chemistry. In addition, included are previously unpublished material that will help researchers gain a deeper understanding into the basic concepts involved in the field of molecular electronics.
Author: Juan Carlos Cuevas
Publisher: World Scientific
ISBN: 9814282588
Category : Science
Languages : en
Pages : 724
Get Book Here
Book Description
This book provides a comprehensive overview of the rapidly developing field of molecular electronics. It focuses on our present understanding of the electrical conduction in single-molecule circuits and provides a thorough introduction to the experimental techniques and theoretical concepts. It will also constitute as the first textbook-like introduction to both the experiment and theory of electronic transport through single atoms and molecules. In this sense, this publication will prove invaluable to both researchers and students interested in the field of nanoelectronics and nanoscience in general. Molecular Electronics is self-contained and unified in its presentation. It may be used as a textbook on nanoelectronics by graduate students and advanced undergraduates studying physics and chemistry. In addition, included are previously unpublished material that will help researchers gain a deeper understanding into the basic concepts involved in the field of molecular electronics.
Author: James M Tour
Publisher: World Scientific
ISBN: 9814486701
Category : Science
Languages : en
Pages : 385
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Book Description
This book presents an in-depth discussion on molecular electronics in an easy-to-understand manner, aiming at chemists, computer scientists, surface scientists, physicists, and applied mathematicians. Lighter overviews are provided for the science-minded layperson and the high tech entrepreneur in this nanoscale science. The author has included a detailed synthetic chemistry treasure chest, protocols of self-assembling routes for bottom-up fabrication atop silicon platforms, representative current-voltage and memory readouts from molecular devices, and overviews of present architectural and mathematical approaches to programming molecular computing machines. The investment and commercial insertion landscape is painted along with a “Who's Who” in the molecular electronics business space. Advice and forewarnings are provided in a practical yet witty manner for the aspiring academic corporate founder and the business CEO wannabe seeking to establish a high tech company while wading through the idiosyncratic morass of university personalities and university-owned intellectual property.
Author: Trygve Helgaker
Publisher: John Wiley & Sons
ISBN: 1119019559
Category : Science
Languages : en
Pages : 949
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Book Description
Ab initio quantum chemistry has emerged as an important tool in chemical research and is appliced to a wide variety of problems in chemistry and molecular physics. Recent developments of computational methods have enabled previously intractable chemical problems to be solved using rigorous quantum-mechanical methods. This is the first comprehensive, up-to-date and technical work to cover all the important aspects of modern molecular electronic-structure theory. Topics covered in the book include: * Second quantization with spin adaptation * Gaussian basis sets and molecular-integral evaluation * Hartree-Fock theory * Configuration-interaction and multi-configurational self-consistent theory * Coupled-cluster theory for ground and excited states * Perturbation theory for single- and multi-configurational states * Linear-scaling techniques and the fast multipole method * Explicity correlated wave functions * Basis-set convergence and extrapolation * Calibration and benchmarking of computational methods, with applications to moelcular equilibrium structure, atomization energies and reaction enthalpies. Molecular Electronic-Structure Theory makes extensive use of numerical examples, designed to illustrate the strengths and weaknesses of each method treated. In addition, statements about the usefulness and deficiencies of the various methods are supported by actual examples, not just model calculations. Problems and exercises are provided at the end of each chapter, complete with hints and solutions. This book is a must for researchers in the field of quantum chemistry as well as for nonspecialists who wish to acquire a thorough understanding of ab initio molecular electronic-structure theory and its applications to problems in chemistry and physics. It is also highly recommended for the teaching of graduates and advanced undergraduates.
Author: Gianaurelio Cuniberti
Publisher: Springer
ISBN: 3540315144
Category : Science
Languages : en
Pages : 526
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Book Description
Klaus von Klitzing Max-Planck-Institut fur ̈ Festk ̈ orperforschung, Heisenbergstraße 1, 70569 Stuttgart, Germany Already many Cassandras have prematurely announced the end of the silicon roadmap and yet, conventional semiconductor-based transistors have been continuously shrinking at a pace which has brought us to nowadays cheap and powerful microelectronics. However it is clear that the traditional scaling laws cannot be applied if unwanted tunnel phenomena or ballistic transport dominate the device properties. It is generally expected, that a combination of silicon CMOS devices with molecular structure will dominate the ?eld of nanoelectronics in 20 years. The visionary ideas of atomic- or molecular-scale electronics already date back thirty years but only recently advanced nanotechnology, including e.g. scanning tunneling methods and mechanically controllable break junctions, have enabled to make distinct progress in this direction. On the level of f- damentalresearch,stateofthearttechniquesallowtomanipulate,imageand probechargetransportthroughuni-molecularsystemsinanincreasinglyc- trolled way. Hence, molecular electronics is reaching a stage of trustable and reproducible experiments. This has lead to a variety of physical and chemical phenomena recently observed for charge currents owing through molecular junctions, posing new challenges to theory. As a result a still increasing n- ber of open questions determines the future agenda in this ?eld.
Author: Juan Carlos Cuevas
Publisher: World Scientific
ISBN: 9814282596
Category : Science
Languages : en
Pages : 724
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Book Description
1. The birth of molecular electronics. 1.1. Why molecular electronics?. 1.2. A brief history of molecular electronics. 1.3. Scope and structure of the book -- 2. Fabrication of metallic atomic-size contacts. 2.1. Introduction. 2.2. Techniques involving the scanning electron microscope (STM). 2.3. Methods using atomic force microscopes (AFM). 2.4. Contacts between macroscopic wires. 2.5. Transmission electron microscope. 2.6. Mechanically controllable break-junctions (MCBJ). 2.7. Electromigration technique. 2.8. Electrochemical methods. 2.9. Recent developments. 2.10. Electronic transport measurements. 2.11. Exercises -- 3. Contacting single molecules: Experimental techniques. 3.1. Introduction. 3.2. Molecules for molecular electronics. 3.3. Deposition of molecules. 3.4. Contacting single molecules. 3.5. Contacting molecular ensembles. 3.6. Exercises -- 4. The scattering approach to phase-coherent transport in nanocontacts. 4.1. Introduction. 4.2. From mesoscopic conductors to atomic-scale junctions. 4.3. Conductance is transmission : heuristic derivation of the Landauer formula. 4.4. Penetration of a potential barrier : tunnel effect. 4.5. The scattering matrix. 4.6. Multichannel Landauer formula. 4.7. Shot noise. 4.8. Thermal transport and thermoelectric phenomena. 4.9. Limitations of the scattering approach. 4.10. Exercises -- 5. Introduction to Green's function techniques for systems in equilibrium. 5.1. The Schrodinger and Heisenberg pictures. 5.2. Green's functions of a noninteracting electron system. 5.3. Application to tight-binding Hamiltonians. 5.4. Green's functions in time domain. 5.5. Exercises -- 6. Green's functions and Feynman diagrams. 6.1. The interaction picture. 6.2. The time-evolution operator. 6.3. Perturbative expansion of causal Green's functions. 6.4. Wick's theorem. 6.5. Feynman diagrams. 6.6. Feynman diagrams in energy space. 6.7. Electronic self-energy and Dyson's equation. 6.8. Self-consistent diagrammatic theory : the Hartree-Fock approximation. 6.9. The Anderson model and the Kondo effect. 6.10. Final remarks. 6.11. Exercises -- 7. Nonequilibrium Green's functions formalism. 7.1. The Keldysh formalism. 7.2. Diagrammatic expansion in the Keldysh formalism. 7.3. Basic relations and equations in the Keldysh formalism. 7.4. Application of Keldysh formalism to simple transport problems. 7.5. Exercises -- 8. Formulas of the electrical current : exploiting the Keldysh formalism. 8.1. Elastic current : microscopic derivation of the Landauer formula. 8.2. Current through an interacting atomic-scale junction. 8.3. Time-dependent transport in nanoscale junctions. 8.4. Exercises -- 9. Electronic structure I: Tight-binding approach. 9.1. Basics of the tight-binding approach. 9.2. The extended Huckel method. 9.3. Matrix elements in solid state approaches. 9.4. Slater-Koster two-center approximation. 9.5. Some illustrative examples. 9.6. The NRL tight-binding method. 9.7. The tight-binding approach in molecular electronics. 9.8. Exercises -- 10. Electronic structure II : density functional theory. 10.1. Elementary quantum mechanics. 10.2. Early density functional theories. 10.3. The Hohenberg-Kohn theorems. 10.4. The Kohn-Sham approach. 10.5. The exchange-correlation functionals. 10.6. The basic machinery of DFT. 10.7. DFT performance. 10.8. DFT in molecular electronics. 10.9. Exercises -- 11. The conductance of a single atom. 11.1. Landauer approach to conductance: brief reminder. 11.2. Conductance of atomic-scale contacts. 11.3. Conductance histograms. 11.4. Determining the conduction channels. 11.5. The chemical nature of the conduction channels of oneatom contacts. 11.6. Some further issues. 11.7. Conductance fluctuations. 11.8. Atomic chains : parity oscillations in the conductance. 11.9. Concluding remarks. 11.10. Exercises -- 12. Spin-dependent transport in ferromagnetic atomic contacts. 12.1. Conductance of ferromagnetic atomic contacts. 12.2. Magnetoresistance of ferromagnetic atomic contacts. 12.3. Anisotropic magnetoresistance in atomic contacts. 12.4. Concluding remarks and open problems -- 13. Coherent transport through molecular junctions I : basic concepts. 13.1. Identifying the transport mechanism in single-molecule junctions. 13.2. Some lessons from the resonant tunneling model. 13.3. A two-level model. 13.4. Length dependence of the conductance. 13.5. Role of conjugation in [symbol]-electron systems. 13.6. Fano resonances. 13.7. Negative differential resistance. 13.8. Final remarks. 13.9. Exercises -- 14. Coherent transport through molecular junctions II : test-bed molecules. 14.1. Coherent transport through some test-bed molecules. 14.2. Metal-molecule contact : the role of anchoring groups. 14.3. Tuning chemically the conductance : the role of side-groups. 14.4. Controlled STM-based single-molecule experiments. 14.5. Conclusions and open problems -- 15. Single-molecule transistors : Coulomb blockade and Kondo physics. 15.1. Introduction. 15.2. Charging effects in transport through nanoscale devices. 15.3. Single-molecule three-terminal devices. 15.4. Coulomb blockade theory : constant interaction model. 15.5. Towards a theory of Coulomb blockade in molecular transistors. 15.6. Intermediate coupling : cotunneling and Kondo effect. 15.7. Single-molecule transistors : experimental results. 15.8. Exercises -- 16. Vibrationally-induced inelastic current I : experiment. 16.1. Introduction. 16.2. Inelastic electron tunneling spectroscopy (IETS). 16.3. Highly conductive junctions : point-contact spectroscopy (PCS). 16.4. Crossover between PCS and IETS. 16.5. Resonant inelastic electron tunneling spectroscopy (RIETS). 16.6. Summary of vibrational signatures -- 17. Vibrationally-induced inelastic current II : theory. 17.1. Weak electron-phonon coupling regime. 17.2. Intermediate electron-phonon coupling regime. 17.3. Strong electron-phonon coupling regime. 17.4. Concluding remarks and open problems. 17.5. Exercises -- 18. The hopping regime and transport through DNA molecules. 18.1. Signatures of the hopping regime. 18.2. Hopping transport in molecular junctions : experimental examples. 18.3. DNA-based molecular junctions. 18.4. Exercises -- 19. Beyond electrical conductance : shot noise and thermal transport. 19.1. Shot noise in atomic and molecular junctions. 19.2. Heating and heat conduction. 19.3. Thermoelectricity in molecular junctions -- 20. Optical properties of current-carrying molecular junctions. 20.1. Surface-enhanced Raman spectroscopy of molecular junctions. 20.2. Transport mechanisms in irradiated molecular junctions. 20.3. Theory of photon-assisted tunneling. 20.4. Experiments on radiation-induced transport in atomic and molecular junctions. 20.5. Resonant current amplification and other transport phenomena in ac driven molecular junctions. 20.6. Fluorescence from current-carrying molecular junctions. 20.7. Molecular optoelectronic devices. 20.8. Final remarks. 20.9. Exercises -- 21. What is missing in this book?
Author: Sergey Edward Lyshevski
Publisher: CRC Press
ISBN: 1420008145
Category : Technology & Engineering
Languages : en
Pages : 931
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Book Description
There are fundamental and technological limits of conventional microfabrication and microelectronics. Scaling down conventional devices and attempts to develop novel topologies and architectures will soon be ineffective or unachievable at the device and system levels to ensure desired performance. Forward-looking experts continue to search for new paradigms to carry the field beyond the age of microelectronics, and molecular electronics is one of the most promising candidates. The Nano and Molecular Electronics Handbook surveys the current state of this exciting, emerging field and looks toward future developments and opportunities. Molecular and Nano Electronics Explained Explore the fundamentals of device physics, synthesis, and design of molecular processing platforms and molecular integrated circuits within three-dimensional topologies, organizations, and architectures as well as bottom-up fabrication utilizing quantum effects and unique phenomena. Technology in Progress Stay current with the latest results and practical solutions realized for nanoscale and molecular electronics as well as biomolecular electronics and memories. Learn design concepts, device-level modeling, simulation methods, and fabrication technologies used for today's applications and beyond. Reports from the Front Lines of Research Expert innovators discuss the results of cutting-edge research and provide informed and insightful commentary on where this new paradigm will lead. The Nano and Molecular Electronics Handbook ranks among the most complete and authoritative guides to the past, present, and future of this revolutionary area of theory and technology.
Author: Michael C. Petty
Publisher: John Wiley & Sons
ISBN: 0470723882
Category : Technology & Engineering
Languages : en
Pages : 549
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Book Description
This consistent and comprehensive text is unique in providing an informed insight into molecular electronics by contrasting the prospects for molecular scale electronics with the continuing development of the inorganic semiconductor industry. Providing a wealth of information on the subject from background material to possible applications, Molecular Electronics contains all the need to know information in one easily accessible place. Speculation about future developments has also been included to give the whole picture of this increasingly popular and important topic.
Author: F.T. Hong
Publisher: Springer Science & Business Media
ISBN: 146157482X
Category : Science
Languages : en
Pages : 441
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Book Description
The dream of developing a biocomputer should not be dismissed as a sheer fantasy. Although there is naturally some doubt as to whether it is possible to design a computer using carbon-based components as in living organisms, instead of silicon-based components as in existing computers, the fact that an average brain often outperforms the most sophisticated computer in terms of the complexity of tasks, if not in terms of speed, is a living testimony to this possibility. The remaining question is to what extent a biocomputer can mimic a living organism and whether it is possible to design and fabri cate such a biocomputer within the foreseeable future. This volume does not attempt to provide immediate and exact answers to these questions but instead attempts to provide a vision and a progress report of the initial efforts. This volume is mainly a collection of papers presented at the Symposium on Molecular Electronics - Biosensors and Biocomputers, sponsored by the Divi sion of Biotechnology, Health and Environment of the Fine Particle Society, held from July 19-22, 1989 at the Society's 19th Annual Meeting in Santa Clara, California. Also included are articles contributed by those who planned to attend the conference but were unable to do so. The emergence of the field of molecular electronics is largely the consequence of one person's crusade, that of Forrest L. Carter.
Author: Mahler
Publisher: CRC Press
ISBN: 1000105253
Category : Science
Languages : en
Pages : 413
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Book Description
Integrating molecular physics and information theory, this work presents molecular electronics as a method for information storage and retrieval that incorporates nanometer-scaled systems, uses microscopic particles and exploits the laws of quantum mechanics. It furnishes application examples employing properties of distinct molecules joined together to a macroscopic ensemble of virtually identical units.
Author: Krzysztof Iniewski
Publisher: McGraw Hill Professional
ISBN: 0071664491
Category : Technology & Engineering
Languages : en
Pages : 559
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Book Description
The latest advances in nanoelectronics This definitive volume addresses the state of the art in nanoelectronics, covering nanowires, molecular electronics, and nanodevices. Written by global experts in the field, Nanoelectronics discusses cutting-edge techniques and emerging materials, such as carbon nanotubes and quantum dots. This pioneering work offers a comprehensive survey of nanofabrication options for use in next-generation technologies. Nanoelectronics covers: Electrical properties of metallic nanowires Electromigration defect nucleation in damascene copper interconnect lines Carbon nanotube interconnects in CMOS integrated circuits Printed organic electronics One-dimensional nanostructure-enabled chemical sensing Cross-section fabrication and analysis of nanoscale device structures and complex organic electronics Microfabrication and applications of nanoparticle-doped conductive polymers Single-electron conductivity in organic nanostructures for transistors and memories Synthesis of molecular bioelectronic nanostructures Nanostructured electrode materials for advanced Li-ion batteries Quantum-dot devices based on carbon nanotubes Carbon nanotubes as electromechanical actuators Low-level nanoscale electrical measurements and ESD Nanopackaging
