Author: Michael M. Coleman
Publisher: CRC Press
ISBN: 9780877628231
Category : Technology & Engineering
Languages : en
Pages : 530
Get Book Here
Book Description
This book with software provides powerful tools for the analysis, prediction and creation of new polymer blends, an area of significant commercial potential. The R&D approaches and methods described in the book have attracted the interest of polymer R&D leaders in industry, and have been put into use in several major chemical companies. The companion set of computer programs speeds and facilitates work in this area. FROM THE AUTHORS' PREFACE: During the 1980's a steadily increasing number of compatible systems [polymer blends] have been reported. We believe that miscible mixtures will prove to be fairly common and the purpose of this book is to explore the circumstances in which single phase materials can be obtained. We will also describe a model for the phase behavior of these mixtures which we believe to have a predictive value, or be used as a practical guide to polymer miscibility. Our approach is based on the use of association models which have until recently been largely ignored in treating hydrogen bonding in polymer mixtures. They have most frequently been applied to mixtures of alcohols with simple hydrocarbons, where the equilibrium constants used to describe association have most frequently been determined by a fit to thermodynamic data (e.g., vapor pressures, heat of mixing). In our work we have sought to, first, adapt this approach to a description of the phase behavior of polymer mixtures; second, develop spectroscopic methods that provide an independent measurement of the equilibrium constants. Our purpose in this book is to explore and describe this approach and illustrate its broad utility. We address two overlapping yet different audiences. One would be primarily interested in the broad nature of this approach and the practical applications of a simple model. The second would be more interested in the derivations of the equations and some of the fundamental aspects of the spectroscopy of these systems. Accordingly this book is in the form of a sandwich. We begin with a brief introduction to theories of mixing and the phase behavior of polymeric mixtures, followed by a practical guide to polymer miscibility. This chapter also serves to identify the types of systems in which, by copolymerization or other means, one might introduce the appropriate hydrogen bonding functional groups and obtain a miscible system. The [main substance] of this book is in [the] chapters where fundamental aspects of hydrogen bonds, spectroscopy and the application of association models are described. We also offer [separately] computer programs that calculate and display many of the important quantities described in this book (e.g., the stoichiometry of hydrogen bonding and its relationship to infrared measurements, phase behavior, etc.). In our view one can obtain a good feel for the miscibility of many systems with these programs.
Author: L. A. Utracki
Publisher:
ISBN: 9789400760653
Category : Polymer engineering
Languages : en
Pages : 1800
Get Book Here
Book Description
Written by an international group of highly respected contributors, this fundamental reference work covers all aspects of polymer blends: science, engineering, technology and applications.
Author: Olagoke Olabis
Publisher: Elsevier
ISBN: 0323153070
Category : Science
Languages : en
Pages : 383
Get Book Here
Book Description
Polymer–Polymer Miscibility discusses miscibility of polymeric mixtures. This book explains the theoretical and practical aspects of polymer miscibility, which has become a considerable area of research in many academic and industrial laboratories. Comprised of seven chapters, this book starts with an overview of the physical nature of the variations of the basic polymer structure. This monograph then discusses the two cases of miscible polymer blends, namely, poly(vinyl chloride) (PVC)–butadiene/acrylonitrile copolymer (NBR) and polystyrene–poly(2,6-dimethyl-1,4-phenylene oxide) (PPO) blends. This text explores the useful and unique properties of blends of poly(vinyl chloride) and butadiene/acrylonitrile copolymer rubber. Other chapters discuss the thermodynamic theories for the phase separation of block copolymers. The reader is also introduced to other variations of chemical structure, which can result in the permanent attachment of polymers to each other through block and graft copolymers. This text also explores the feasibility of covalent bonding of polymer components. This book is intended for chemical engineers and materials scientists.
Author: Sabu Thomas
Publisher: John Wiley & Sons
ISBN: 3527331530
Category : Science
Languages : en
Pages : 972
Get Book Here
Book Description
Filling the gap for a reference dedicated to the characterization of polymer blends and their micro and nano morphologies, this book provides comprehensive, systematic coverage in a one-stop, two-volume resource for all those working in the field. Leading researchers from industry and academia, as well as from government and private research institutions around the world summarize recent technical advances in chapters devoted to their individual contributions. In so doing, they examine a wide range of modern characterization techniques, from microscopy and spectroscopy to diffraction, thermal analysis, rheology, mechanical measurements and chromatography. These methods are compared with each other to assist in determining the best solution for both fundamental and applied problems, paying attention to the characterization of nanoscale miscibility and interfaces, both in blends involving copolymers and in immiscible blends. The thermodynamics, miscibility, phase separation, morphology and interfaces in polymer blends are also discussed in light of new insights involving the nanoscopic scale. Finally, the authors detail the processing-morphology-property relationships of polymer blends, as well as the influence of processing on the generation of micro and nano morphologies, and the dependence of these morphologies on the properties of blends. Hot topics such as compatibilization through nanoparticles, miscibility of new biopolymers and nanoscale investigations of interfaces in blends are also addressed. With its application-oriented approach, handpicked selection of topics and expert contributors, this is an outstanding survey for anyone involved in the field of polymer blends for advanced technologies.
Author: Mark T. DeMeuse
Publisher: Elsevier
ISBN: 0857099019
Category : Technology & Engineering
Languages : en
Pages : 233
Get Book Here
Book Description
Polymer blends offer properties not easily obtained through the use of a single polymer, including the ability to withstand high temperatures. High Temperature Polymer Blends outlines the characteristics, developments, and use of high temperature polymer blends. The first chapter introduces high temperature polymer blends, their general principles, and thermodynamics. Further chapters go on to deal with the characterization of high temperature polymer blends for specific uses, such as fuel cells and aerospace applications. The book discusses different types of high temperature polymer blends, including liquid crystal polymers, polysulfones, and polybenzimidazole polymer blends and their commercial applications. High Temperature Polymer Blends provides a key reference for material scientists, polymer scientists, chemists, and plastic engineers, as well as academics in these fields. - Reviews characterization methods and analysis of the thermodynamic properties of high temperature polymer blends - Reviews the use of materials such as liquid crystals as reinforcements as well as applications in such areas as energy and aerospace engineering
Author: Donald R Paul
Publisher: Elsevier
ISBN: 0323138896
Category : Technology & Engineering
Languages : en
Pages : 520
Get Book Here
Book Description
Polymer Blends, Volume 1 highlights the importance of polymer blends as a major new branch of macromolecular science. Topics range from polymer-polymer compatibility and the statistical thermodynamics of polymer blends to the phase separation behavior of polymer-polymer mixtures, transport phenomena in polymer blends, and mechanical properties of multiphase polymer blends. The optical behavior, solid state transition behavior, and rheology of polymer blends are also discussed. This book is organized into 10 chapters and begins with an overview of polymer blends, with emphasis on terminology and the effect of molecular weight on the thermodynamics of polymer blends as well as phase equilibria and transitions. The discussion then turns to the miscibility of homopolymers and copolymers, in bulk and in solution, from the experimental and theoretical viewpoints. The chapters that follow explore the statistical thermodynamics of polymer blends, paying particular attention to the Flory and lattice fluid theories, along with the phase relationship in polymer mixtures. The interfacial energy, structure, and adhesion between polymers in relation to the properties of polymer blends are considered. The final chapter examines the phenomena of low molecular weight penetrant transport. Currently accepted models for unsteady-state and steady-state permeation of polymeric materials are presented. A discussion of unsteady-state absorption and desorption behavior observed in a variety of polymer blends complements the treatment of permeation behavior. This book is intended to provide academic and industrial research scientists and technologists with a broad background in current principles and practice concerning mixed polymer systems.
Author: Sabu Thomas
Publisher: Elsevier
ISBN: 0128169567
Category : Technology & Engineering
Languages : en
Pages : 326
Get Book Here
Book Description
Rheology of Polymer Blends and Nanocomposites: Theory, Modelling and Applications focuses on rheology in polymer nanocomposites. It provides readers with a solid grounding in the fundamentals of rheology, with an emphasis on recent advancements. Chapters explore potential future applications for nanocomposites and polymer blends, giving readers a thorough understanding of the specific features derived from rheology as a tool for the study of polymer blends and nanocomposites. This book is ideal for industrial and academic researchers in the field of polymer blends and nanocomposites, but is also a great resource for anyone who wants to learn about the applications of rheology. - Sets out the principles of rheology as it is applied to polymer blends and nanocomposites - Demonstrates how rheological techniques are best applied to different classes of nanocomposites - Assesses the opportunities and major challenges of rheological approaches to polymer blends and nanocomposites
Author: Ajitha A. R
Publisher: Elsevier
ISBN: 0128162880
Category : Technology & Engineering
Languages : en
Pages : 642
Get Book Here
Book Description
Compatibilization of Polymer Blends: Micro and Nano Scale Phase Morphologies, Interphase Characterization and Properties offers a comprehensive approach to the use of compatibilizers in polymer blends, examining both fundamental and advanced knowledge in the field. The book begins by introducing polymer blends, describing thermodynamics, miscibility, and phase separation, and explaining the main concepts of compatibilization. Other sections cover theoretical approaches for nearly compatible blends, incompatible blends, nanofillers, physical compatibilization, reactive compatibilization, morphological and structural characterization, and physico-mechanical characterization. Finally, key application areas are covered, including biomedical applications, packaging and automobile engineering. While this book will be a highly valuable reference source for academics, researchers and postgraduate students interested in polymer blends, it will also be ideal for anyone involved in the fields of polymer science, polymer chemistry, polymer physics, materials science, scientists, R&D professionals, and engineers in involved in the development or engineering of polymer products. - Offers detailed and systematic coverage of essential and advanced topics relating to the compatibilization of polymer blends - Presents a critical analysis of the effect of compatibilization on morphology and thermal, mechanical, electrical and viscoelastic properties of polymer blends - Draws on novel studies and state-of-the-art research, discussing the latest issues and developments
Author: Michael M. Coleman
Publisher: DEStech Publications, Inc
ISBN: 193207855X
Category : Science
Languages : en
Pages : 40
Get Book Here
Book Description
The accompanying CD-ROM contains a set of original programs that allow one to calculate solubility parameters, provide a guide to polymer miscibility, and allow the calculation of the phase behavior of hydrogen-bonded polymer systems. The book is divided into two parts. In the first part, the authors describe the principles underlying the simple guide to polymer blend miscibility, which are the basis of the programs Miscibility Checker and Miscibility Guide. The second part is more rigorous and pertains to hydrogen bonded polymer blends and forms the basis of the program Phase Calculator.
Author: Vikas Mittal
Publisher: CRC Press
ISBN: 1439856702
Category : Technology & Engineering
Languages : en
Pages : 345
Get Book Here
Book Description
With their broad range of properties, polymer blends are widely used in adhesion, colloidal stability, the design of composite and biocompatible materials, and other areas. As the science and technology of polymer blends advances, an increasing number of polymer blend systems and applications continue to be developed. Functional Polymer Blends: Syn
