Microwave and Diode Laser Spectroscopy in Discharge and Flame Plasma

Microwave and Diode Laser Spectroscopy in Discharge and Flame Plasma PDF Author: Vysoká škola báňská - Technická univerzita Ostrava. Katedra požární ochrany a ochrany obyvatelstva
Publisher:
ISBN: 9788024822686
Category :
Languages : cs
Pages : 23

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Microwave and Diode Laser Spectroscopy in Discharge and Flame Plasma

Microwave and Diode Laser Spectroscopy in Discharge and Flame Plasma PDF Author: Vysoká škola báňská - Technická univerzita Ostrava. Katedra požární ochrany a ochrany obyvatelstva
Publisher:
ISBN: 9788024822686
Category :
Languages : cs
Pages : 23

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Inferred Microwave Plasma Temperature Using Tunable Diode Laser Absorption Spectroscopy

Inferred Microwave Plasma Temperature Using Tunable Diode Laser Absorption Spectroscopy PDF Author: Mark Maximillian Poppler
Publisher:
ISBN:
Category : Plasma spectroscopy
Languages : en
Pages : 146

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Spectroscopy of Low Temperature Plasma

Spectroscopy of Low Temperature Plasma PDF Author: Vladimir N. Ochkin
Publisher: John Wiley & Sons
ISBN: 3527627510
Category : Science
Languages : en
Pages : 630

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Book Description
Written by a distinguished plasma scientist and experienced author, this up-to-date work comprehensively covers current methods and new developments and techniques, including non-equilibrium atomic and molecular plasma states, as well as such new applications as gas lasers. Containing numerous appendices with reference data indispensable for plasma spectroscopy, such as statistical weights and partition sums and diatomic molecules. For plasmaphysicists, spectroscopists, materials scientists and physical chemists. Appendix H is only available online.

Optical and Laser Spectroscopic Study of Microwave Plasma-assisted Combustion

Optical and Laser Spectroscopic Study of Microwave Plasma-assisted Combustion PDF Author: Wei Wu
Publisher:
ISBN:
Category :
Languages : en
Pages : 225

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Book Description
Nonthermal plasma-assisted combustion (PAC) has been demonstrated to be a promising potential method to enhance combustion performance and reduce the pollutant emissions. To better understand the mechanism in PAC, we have conducted a series of studies on the combustion enhancement by plasma using a home-developed PAC platform which employs a nonthermal microwave argon plasma and a suit of optical diagnostic tools including optical imaging, optical emission spectroscopy, and cavity ringdown spectroscopy. A new PAC system in which a continuous atmospheric argon microwave plasma jet is employed to enhance combustion of methane/air mixtures was reported. Reactive species in PAC were characterized in a state-resolved manner including the simultaneously measurements of OH(A) and OH(X) radicals in the PAC flames. Roles of the state-resolved OH(A) and OH(X) radicals in microwave PAC of premixed methane/air mixture were explored. It was concluded that if both OH(A) and OH(X) radicals assisted the ignition and flame stabilization processes, then we may hypothesize that the role of OH(A) was more dominant in the ignition enhancement but the role of OH(X) was more dominant in the flame stabilization. The effect of fuel injection configurations was investigated in the comparative study between PAC of the premixed and nonpremixed methane/air mixtures. It was found that emissions from the CH (A-X) and C2 Swan systems only exist in the nonpremixed PAC which suggest that the reaction pathways are different between premixed and nonpremixed PAC. The PAC of premixed methane/oxygen/argon mixtures was investigated. A Ushaped dual-layer curve of fuel ignition/flame stabilization limit showing the effects of the plasma power on the fuel ignition and flame stabilization was observed and reported. A parametric study of the microwave PAC of the premixed ethylene/air mixtures was conducted. Behavior of the OH, CH, and C2 radicals and their dependence on plasma power, argon flow rate, and total ethylene/air mixture flow rate were also studied.

Absorption Spectroscopy Studies in Low Pressure Non Equilibrium Molecular Plasmas Using Tunable Infrared Diode Lasers

Absorption Spectroscopy Studies in Low Pressure Non Equilibrium Molecular Plasmas Using Tunable Infrared Diode Lasers PDF Author: Frank Hempel
Publisher:
ISBN: 9783832502621
Category :
Languages : en
Pages : 0

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Tunable infrared diode laser absorption spectroscopy (TDLAS) has been applied to investigate the chemical kinetics in reactive discharges. It was used to detect the methyl radical and nine stable molecules, CH4, CH3OH, C2H2, C2H4, C2H6, NH3, HCN, CH2O and C2N2, in H2-Ar-N2 microwave plasmas containing up to 7.2 % of methane or methanol, under both flowing and static conditions. The degree of dissociation of the hydrocarbon precursor molecules varied between 20 and 97 %. The methyl radical concentration was found to be in the range 1012 to 1013 molecules cm-3. By analysing the temporal development of molecular concentrations under static conditions it was found that HCN and NH3 are the final products of plasma chemical conversion. The fragmentation rates of methane and methanol and the respective conversion rates to methane, hydrogen cyanide and ammonia have been determined for different hydrogen to nitrogen concentration ratios. An extensive model of the chemical reactions involved in the H2-N2-Ar-CH4 plasma has been developed. Model calculations were performed by including 22 species, 145 chemical reactions and appropriate electron impact dissociation rate coefficients. The results of the model calculations showed satisfactory agreement between calculated and measured concentrations. The most likely main chemical pathways involved in these plasmas are discussed and an appropriate reaction scheme is proposed. Based on the model calculations the concentrations of non-measured species like CH2 or NH2 have been predicted.In addition, spectroscopic investigations of P- and R-branch lines of the fundamental bands of 12C14N and 13C14N in their ground electronic state have been performed at high resolution by tunable diode laser absorption spectroscopy. The radicals were generated in microwave plasmas containing methane with varying proportions of N2 and H2. From a fit to the spectra the origins of the fundamental bands of the two isotopomers were determined to be 2042.42104(84) cm-1 and 2000.08470(30) cm-1. The main product detected in the plasma was HCN. It showed concentrations which are about three orders of magnitude higher than that of CN.Moreover, the time and spatial dependence of the chemical conversion of CO2 to CO were studied in a closed glow discharge reactor (p = 50 Pa, I = 2 and 30 mA) consisting of a small plasma zone and an extended stationary afterglow. Tunable infrared diode laser absorption spectroscopy has been applied to determine the absolute ground state concentrations of CO and CO2. After a certain discharge time the concentrations of both species were observed to come into equilibrium. The spatial dependence of the equilibrium CO concentration in the afterglow was found to vary by less than 10 %. The feed gas was converted to CO more predominantly between 45 % and 60 % with increasing discharge current. The formation time of the stable gas composition decreased with increasing current too. For currents higher than 10 mA the conversion rate of CO2 to CO was estimated to be 1 x 1013 molecules J-1. Based on the experimental results a model of the CO2 conversion chemistry has also been established for this type of discharge. The calculated and measured temporal developments of species concentrations showed a satisfactory agreement for various discharge currents.Lastly, infrared tunable diode laser absorption spectroscopy has been used to analyse the fragmentation of TiCl4 into HCl in pulsed H2-Ar-N2 dc plasmas (p= 2 mbar). At small TiCl4 admixtures (0.04-0.31 %) HCl concentrations of 2-5 x 1014 molecules cm-3 were measured (current density: 0.6-1.15 mA cm2). A nearly complete conversion of Cl into HCl was found at TiCl4 admixtures below 0.2 %.

Encyclopedia of Plasma Technology - Two Volume Set

Encyclopedia of Plasma Technology - Two Volume Set PDF Author: J. Leon Shohet
Publisher: CRC Press
ISBN: 1000031705
Category : Technology & Engineering
Languages : en
Pages : 1654

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Book Description
Technical plasmas have a wide range of industrial applications. The Encyclopedia of Plasma Technology covers all aspects of plasma technology from the fundamentals to a range of applications across a large number of industries and disciplines. Topics covered include nanotechnology, solar cell technology, biomedical and clinical applications, electronic materials, sustainability, and clean technologies. The book bridges materials science, industrial chemistry, physics, and engineering, making it a must have for researchers in industry and academia, as well as those working on application-oriented plasma technologies. Also Available Online This Taylor & Francis encyclopedia is also available through online subscription, offering a variety of extra benefits for researchers, students, and librarians, including: Citation tracking and alerts Active reference linking Saved searches and marked lists HTML and PDF format options Contact Taylor and Francis for more information or to inquire about subscription options and print/online combination packages. US: (Tel) 1.888.318.2367; (E-mail) [email protected] International: (Tel) +44 (0) 20 7017 6062; (E-mail) [email protected]

The Development of Diode Laser Infrared Absorption Spectroscopy as a Plasma Diagnostic

The Development of Diode Laser Infrared Absorption Spectroscopy as a Plasma Diagnostic PDF Author: Robert Leslie McClain
Publisher:
ISBN:
Category :
Languages : en
Pages : 494

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Optical Emission Spectroscopy and Effects of Plasma in High Power Microwave Pulse Shortening Experiments

Optical Emission Spectroscopy and Effects of Plasma in High Power Microwave Pulse Shortening Experiments PDF Author: William Erwin Cohen
Publisher:
ISBN:
Category :
Languages : en
Pages : 240

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Spectroscopic Temperature Determinations in a Laminar Flow Microwave-induced Plasma Discharge

Spectroscopic Temperature Determinations in a Laminar Flow Microwave-induced Plasma Discharge PDF Author: John M. Workman
Publisher:
ISBN:
Category : Plasma spectroscopy
Languages : en
Pages : 218

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Scientific and Technical Aerospace Reports

Scientific and Technical Aerospace Reports PDF Author:
Publisher:
ISBN:
Category : Aeronautics
Languages : en
Pages : 456

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Book Description
Lists citations with abstracts for aerospace related reports obtained from world wide sources and announces documents that have recently been entered into the NASA Scientific and Technical Information Database.