Method of Producing Exfoliated Graphite Composite Compositions for Fuel Cell Flow Field Plates PDF Download
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Languages : en
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A method of producing an electrically conductive composite composition, which is particularly useful for fuel cell bipolar plate applications. The method comprises: (a) providing a supply of expandable graphite powder; (b) providing a supply of a non-expandable powder component comprising a binder or matrix material; (c) blending the expandable graphite with the non-expandable powder component to form a powder mixture wherein the non-expandable powder component is in the amount of between 3% and 60% by weight based on the total weight of the powder mixture; (d) exposing the powder mixture to a temperature sufficient for exfoliating the expandable graphite to obtain a compressible mixture comprising expanded graphite worms and the non-expandable component; (e) compressing the compressible mixture at a pressure within the range of from about 5 psi to about 50,000 psi in predetermined directions into predetermined forms of cohered graphite composite compact; and (f) treating the so-formed cohered graphite composite to activate the binder or matrix material thereby promoting adhesion within the compact to produce the desired composite composition. Preferably, the non-expandable powder component further comprises an isotropy-promoting agent such as non-expandable graphite particles. Further preferably, step (e) comprises compressing the mixture in at least two directions. The method leads to composite plates with exceptionally high thickness-direction electrical conductivity.
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Languages : en
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Book Description
A method of producing an electrically conductive composite composition, which is particularly useful for fuel cell bipolar plate applications. The method comprises: (a) providing a supply of expandable graphite powder; (b) providing a supply of a non-expandable powder component comprising a binder or matrix material; (c) blending the expandable graphite with the non-expandable powder component to form a powder mixture wherein the non-expandable powder component is in the amount of between 3% and 60% by weight based on the total weight of the powder mixture; (d) exposing the powder mixture to a temperature sufficient for exfoliating the expandable graphite to obtain a compressible mixture comprising expanded graphite worms and the non-expandable component; (e) compressing the compressible mixture at a pressure within the range of from about 5 psi to about 50,000 psi in predetermined directions into predetermined forms of cohered graphite composite compact; and (f) treating the so-formed cohered graphite composite to activate the binder or matrix material thereby promoting adhesion within the compact to produce the desired composite composition. Preferably, the non-expandable powder component further comprises an isotropy-promoting agent such as non-expandable graphite particles. Further preferably, step (e) comprises compressing the mixture in at least two directions. The method leads to composite plates with exceptionally high thickness-direction electrical conductivity.
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Languages : en
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Book Description
A process of continuously producing a more isotropic, electrically conductive composite composition is provided. The process comprises: (a) continuously supplying a compressible mixture comprising exfoliated graphite worms and a binder or matrix material, wherein the binder or matrix material is in an amount of between 3% and 60% by weight based on the total weight of the mixture; (b) continuously compressing the compressible mixture at a pressure within the range of from about 5 psi or 0.035 MPa to about 50,000 psi or 350 MPa in at least a first direction into a cohered graphite composite compact; and (c) continuously compressing the composite compact in a second direction, different from the first direction, to form the composite composition in a sheet or plate form. The process leads to composite plates with exceptionally high thickness-direction electrical conductivity.
Author: Sharmila M. Mukhopadhyay
Publisher: John Wiley & Sons
ISBN: 1118114051
Category : Technology & Engineering
Languages : en
Pages : 397
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Book Description
A multidisciplinary approach that explores the diverse properties, functions, and applications of nanomaterials Drawing together the many scientific and engineering disciplines underlying the development of nanomaterials, Nanoscale Multifunctional Materials provides a multidisciplinary review of the diverse properties, functions, and applications of nanomaterials. The book examines both nanoparticles, which have larger-scale equivalents, and uniquely assembled nanomaterials, which do not have larger-scale equivalents. Readers will gain a tremendous appreciation of the versatility of nanomaterials as well as an understanding of how the same nanomaterial can have several distinct applications across a broad range of fields and industries. Nanoscale Multifunctional Materials is divided into three sections: Section I, Overview, describes the scientific phenomena underlying the special properties of nanomaterials, making them desirable as novel materials and different from conventional solids. Next, readers will learn about the effect of nanomaterials on contemporary society as well as future trends in nanomaterials production and use. Section II, Processing and Analysis, explores several experimental approaches in nanomaterial fabrication and characterization as well as in theoretical approaches in modeling and simulation. Section III, Applications, offers detailed examples of nanomaterial applications in alternative energy, thermal management, environmental cleanup, water treatment, and biomedicine. Each chapter has been written by one or more leading experts in the science, engineering, and application of nanomaterials. Within each chapter, readers will find a thorough review of the current literature, with references to facilitate further investigation of individual topics. Underscoring the multidisciplinary and multifunctional characteristics of nanomaterials, this book is recommended for students and professionals in science and engineering who need a broad perspective on both the nature and application of nanomaterials. The text also sets the stage for the development of new nanomaterials and new applications.
Author:
Publisher: USPTO
ISBN:
Category :
Languages : en
Pages : 1000
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Author: M Gasik
Publisher: Elsevier
ISBN: 184569483X
Category : Technology & Engineering
Languages : en
Pages : 513
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Book Description
A fuel cell is an electrochemical device that converts the chemical energy of a reaction (between fuel and oxidant) directly into electricity. Given their efficiency and low emissions, fuel cells provide an important alternative to power produced from fossil fuels. A major challenge in their use is the need for better materials to make fuel cells cost-effective and more durable. This important book reviews developments in materials to fulfil the potential of fuel cells as a major power source. After introductory chapters on the key issues in fuel cell materials research, the book reviews the major types of fuel cell. These include alkaline fuel cells, polymer electrolyte fuel cells, direct methanol fuel cells, phosphoric acid fuel cells, molten carbonate fuel cells, solid oxide fuel cells and regenerative fuel cells. The book concludes with reviews of novel fuel cell materials, ways of analysing performance and issues affecting recyclability and life cycle assessment. With its distinguished editor and international team of contributors, Materials for fuel cells is a valuable reference for all those researching, manufacturing and using fuel cells in such areas as automotive engineering. Examines the key issues in fuel cell materials research Reviews the major types of fuel cells such as direct methanol and regenerative fuel cells Further chapters explore ways of analysing performance and issues affecting recyclability and life cycle assessment
Author: Jürgen Garche
Publisher: Newnes
ISBN: 0444527451
Category : Science
Languages : en
Pages : 4532
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Book Description
The Encyclopedia of Electrochemical Power Sources is a truly interdisciplinary reference for those working with batteries, fuel cells, electrolyzers, supercapacitors, and photo-electrochemical cells. With a focus on the environmental and economic impact of electrochemical power sources, this five-volume work consolidates coverage of the field and serves as an entry point to the literature for professionals and students alike. Covers the main types of power sources, including their operating principles, systems, materials, and applications Serves as a primary source of information for electrochemists, materials scientists, energy technologists, and engineers Incorporates nearly 350 articles, with timely coverage of such topics as environmental and sustainability considerations
Author: Jiujun Zhang
Publisher: Newnes
ISBN: 0444536892
Category : Technology & Engineering
Languages : en
Pages : 391
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Book Description
PEM Fuel Cell Testing and Diagnosis covers the recent advances in PEM (proton exchange membrane) fuel cell systems, focusing on instruments and techniques for testing and diagnosis, and the application of diagnostic techniques in practical tests and operation. This book is a unique source of electrochemical techniques for researchers, scientists and engineers working in the area of fuel cells. Proton exchange membrane fuel cells are currently considered the most promising clean energy-converting devices for stationary, transportation, and micro-power applications due to their high energy density, high efficiency, and environmental friendliness. To advance research and development of this emerging technology, testing and diagnosis are an essential combined step. This book aids those efforts, addressing effects of humidity, temperature and pressure on fuel cells, degradation and failure analysis, and design and assembly of MEAs, single cells and stacks. Provides fundamental and theoretical principles for PEM fuel cell testing and diagnosis. Comprehensive source for selecting techniques, experimental designs and data analysis Analyzes PEM fuel cell degradation and failure mechanisms, and suggests failure mitigation strategies Provides principles for selecting PEM fuel cell key materials to improve durability
Author: Korneel Rabaey
Publisher: IWA Publishing
ISBN: 184339233X
Category : Science
Languages : en
Pages : 525
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Book Description
In the context of wastewater treatment, Bioelectrochemical Systems (BESs) have gained considerable interest in the past few years, and several BES processes are on the brink of application to this area. This book, written by a large number of world experts in the different sub-topics, describes the different aspects and processes relevant to their development. Bioelectrochemical Systems (BESs) use micro-organisms to catalyze an oxidation and/or reduction reaction at an anodic and cathodic electrode respectively. Briefly, at an anode oxidation of organic and inorganic electron donors can occur. Prime examples of such electron donors are waste organics and sulfides. At the cathode, an electron acceptor such as oxygen or nitrate can be reduced. The anode and the cathode are connected through an electrical circuit. If electrical power is harvested from this circuit, the system is called a Microbial Fuel Cell; if electrical power is invested, the system is called a Microbial Electrolysis Cell. The overall framework of bio-energy and bio-fuels is discussed. A number of chapters discuss the basics – microbiology, microbial ecology, electrochemistry, technology and materials development. The book continues by highlighting the plurality of processes based on BES technology already in existence, going from wastewater based reactors to sediment based bio-batteries. The integration of BESs into existing water or process lines is discussed. Finally, an outlook is provided of how BES will fit within the emerging biorefinery area.
Author: Timothy E. Lipman
Publisher: Springer
ISBN: 9781493977888
Category : Technology & Engineering
Languages : en
Pages : 0
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Book Description
The expected end of the “oil age” will lead to increasing focus and reliance on alternative energy conversion devices, among which fuel cells have the potential to play an important role. Not only can phosphoric acid and solid oxide fuel cells already efficiently convert today’s fossil fuels, including methane, into electricity, but other types of fuel cells, such as polymer electrolyte membrane fuel cells, have the potential to become the cornerstones of a possible future hydrogen economy. This handbook offers concise yet comprehensive coverage of the current state of fuel cell research and identifies key areas for future investigation. Internationally renowned specialists provide authoritative introductions to a wide variety of fuel cell types and hydrogen production technologies, and discuss materials and components for these systems. Sustainability and marketing considerations are also covered, including comparisons of fuel cells with alternative technologies.
Author: Felix N. Büchi
Publisher: Springer Science & Business Media
ISBN: 038785536X
Category : Science
Languages : en
Pages : 489
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Book Description
This book covers a significant number of R&D projects, performed mostly after 2000, devoted to the understanding and prevention of performance degradation processes in polymer electrolyte fuel cells (PEFCs). The extent and severity of performance degradation processes in PEFCs were recognized rather gradually. Indeed, the recognition overlapped with a significant number of industrial dem- strations of fuel cell powered vehicles, which would suggest a degree of technology maturity beyond the resaolution of fundamental failure mechanisms. An intriguing question, therefore, is why has there been this apparent delay in addressing fun- mental performance stability requirements. The apparent answer is that testing of the power system under fully realistic operation conditions was one prerequisite for revealing the nature and extent of some key modes of PEFC stack failure. Such modes of failure were not exposed to a similar degree, or not at all, in earlier tests of PEFC stacks which were not performed under fully relevant conditions, parti- larly such tests which did not include multiple on–off and/or high power–low power cycles typical for transportation and mobile power applications of PEFCs. Long-term testing of PEFCs reported in the early 1990s by both Los Alamos National Laboratory and Ballard Power was performed under conditions of c- stant cell voltage, typically near the maximum power point of the PEFC.
