Metallocenes in Regio- and Stereoselective Synthesis PDF Download
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Author: Tamotsu Takahashi
Publisher: Springer Science & Business Media
ISBN: 9783540016069
Category : Science
Languages : en
Pages : 260
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Book Description
Metallocene is a well known sandwich complex with two cyclopentadienyl ligands such as ferrocene. Recently, such metallocene compounds have been found to be very characteristic and they have become very important, not only in the area of organic synthesis, but also in polymerization in industry. Metal complexes with one cyclopentadienyl ligand have also become popular as half sandwich complexes. The number of researchers in the field of metallocenes has increased rapidly. However, the origin of the characteristic reactivity of metallocenes is not fully understood. In this volume, the chemistry of metal complexes with at least one cyclopentadienyl ligand is comprehensively covered by leading experts. Reactions discussed here are (i) natural product synthesis, (ii) catalytic asymmetric synthesis, (iii) cyclization reactions, (iv)catalytic reactions, (iv) polymerization reactions and (v) carbon-carbon bond cleavage reactions. The reader will have access to useful information about the current state of metallocene chemistry.
Author: Tamotsu Takahashi
Publisher: Springer Science & Business Media
ISBN: 9783540016069
Category : Science
Languages : en
Pages : 260
Get Book Here
Book Description
Metallocene is a well known sandwich complex with two cyclopentadienyl ligands such as ferrocene. Recently, such metallocene compounds have been found to be very characteristic and they have become very important, not only in the area of organic synthesis, but also in polymerization in industry. Metal complexes with one cyclopentadienyl ligand have also become popular as half sandwich complexes. The number of researchers in the field of metallocenes has increased rapidly. However, the origin of the characteristic reactivity of metallocenes is not fully understood. In this volume, the chemistry of metal complexes with at least one cyclopentadienyl ligand is comprehensively covered by leading experts. Reactions discussed here are (i) natural product synthesis, (ii) catalytic asymmetric synthesis, (iii) cyclization reactions, (iv)catalytic reactions, (iv) polymerization reactions and (v) carbon-carbon bond cleavage reactions. The reader will have access to useful information about the current state of metallocene chemistry.
Author: George M. Benedikt
Publisher: Cambridge University Press
ISBN: 0080950426
Category : Science
Languages : en
Pages : 398
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Book Description
It has been estimated that within just ten years, over half of all polyolefins will be made by using metallocene catalysts. This ground-breaking volume from PDL brings togetherùfor the first timeùwork from dozens of world-renowned experts on the subject. Fifty chapters of peer-reviewed content offer insights into applications in automotive components, food packaging, insulating films, non-woven fabrics and medical markets, among others.
Author: Marko Hapke
Publisher: Springer Nature
ISBN: 3031573811
Category :
Languages : en
Pages : 208
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Book Description
Author: Antonio Togni
Publisher: Wiley-VCH
ISBN:
Category : Science
Languages : en
Pages : 576
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Book Description
That terms like sandwich complexes or the concept of compounds without direct chemical bonds between the central metal atom and the ligating atoms are nowadays common knowledge can be attributed to the sensational discovery of ferrocene in the early 1950s. Although ferrocene is still at the forefront of research, this two-volume book highlights the development of metallocene chemistry, and emphasizes the similarities and differences between ferrocene and other metallocenes. Do you require a transition metal to build metallocenes? Must the planes of the cyclopentadienyl ligands be parallel to allow the compound to behave like a typical metallocene? Do zirconocenes react by the same mechanism as molybdenocenes? What are the (potential) applications of these substances? Let yourself be guided by the leading experts in this field, and learn all about the synthesis, reactivity, and unique properties of these sandwich complexes. If you are more interested in applications, there is a wealth of polymeric and dendritic materials with metallocene building blocks described herein. This book also focusses on metallocenes as catalysts in polymerization or asymmetric reactions. If you are graduate student or researcher in organic, inorganic, organometallic, polymer chemistry, and materials science you will find this book an inspiring source of ideas for your own research.
Author: Didier Astruc
Publisher: Springer Science & Business Media
ISBN: 3540461299
Category : Science
Languages : en
Pages : 598
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Book Description
This volume covers both basic and advanced aspects of organometallic chemistry of all metals and catalysis. In order to present a comprehensive view of the subject, it provides broad coverage of organometallic chemistry itself. The catalysis section includes the challenging activation and fictionalization of the main classes of hydrocarbons and the industrially crucial heterogeneous catalysis. Summaries and exercises are provides at the end of each chapter, and the answers to these exercises can be found at the back of the book. Beginners in inorganic, organic and organometallic chemistry, as well as advanced scholars and chemists from academia and industry will find much value in this title.
Author: Héctor González
Publisher:
ISBN:
Category :
Languages : en
Pages : 278
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Book Description
Author: Lisa S. Baugh
Publisher: CRC Press
ISBN: 142001708X
Category : Science
Languages : en
Pages : 698
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Book Description
New synthetic techniques allow chemists to modify polymer microstructures more precisely than ever, making it possible to design materials that meet increasingly demanding performance requirements. Written and edited by experts in the field, Stereoselective Polymerization with Single-Site Catalysts reviews how the relative stereochemistry of
Author: Ray Hoff
Publisher: John Wiley & Sons
ISBN: 1119242134
Category : Technology & Engineering
Languages : en
Pages : 696
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Book Description
Including recent advances and historically important catalysts, this book overviews methods for developing and applying polymerization catalysts – dealing with polymerization catalysts that afford commercially acceptable high yields of polymer with respect to catalyst mass or productivity. • Contains the valuable data needed to reproduce syntheses or use the catalyst for new applications • Offers a guide to the design and synthesis of catalysts, and their applications in synthesis of polymers • Includes the information essential for choosing the appropriate reactions to maximize yield of polymer synthesized • Presents new chapters on vanadium catalysts, Ziegler catalysts, laboratory homopolymerization, and copolymerization
Author: Wiley-VCH
Publisher: John Wiley & Sons
ISBN: 3527685952
Category : Science
Languages : en
Pages : 1934
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Book Description
Your personal Ullmann's: Chemical and physical characteristics, production processes and production figures, main applications, toxicology and safety information are all to be found here in one single resource - bringing the vast knowledge of the Ullmann's Encyclopedia to the desks of industrial chemists and chemical engineers. The ULLMANN’S perspective on polymers and plastics brings reliable information on more than 1500 compounds and products straight to your desktop Carefully selected “best of” compilation of 61 topical articles from the Encyclopedia of Industrial Chemistry on economically important polymers provide a wealth of chemical, physical and economic data on more than 1000 different polymers and hundreds of modifications Contains a wealth of information on the production and use of all industrially relevant polymers and plastics, including organic and inorganic polymers, fibers, foams and resins Extensively updated: more than 30% of the content has been added or updated since the launch of the 7th edition of the Ullmann’s encyclopedia in 2011 and is now available in print for the first time 4 Volumes
Author: Thomas R. Cundari
Publisher: CRC Press
ISBN: 9780824704780
Category : Science
Languages : en
Pages : 450
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Book Description
This work provides a how-to approach to the fundamentals, methodologies and dynamics of computational organometallic chemistry, including classical and molecular mechanics (MM), quantum mechanics (QM), and hybrid MM/QM techniques. It demonstrates applications in actinide chemistry, catalysis, main group chemistry, medicine, and organic synthesis.
