Metal Ion-Promoted Syntheses of Boranes and Carboranes PDF Download
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Author: Russell N. Grimes
Publisher:
ISBN:
Category :
Languages : en
Pages : 10
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Book Description
Controlled synthetic routes to new boron hydrides, carboranes, and metal-carborane complexes have been developed and a number of structurally novel species have been prepared and characterized. The oxidative fusion method for synthesis of boranes and carboranes has been further extended and its mechanism explored. The chemistry of small (7-vertex) metallacarboranes having reactive metal centers has been examined. Practical routes to metalarene-carborane sandwich complexes have been developed. Keywords: Boron; Arene-metal complex; Iron-carborane complex; Cobalt-carborane complex; Nickel-carborane complex; Oxidative fusion.
Author: Russell N. Grimes
Publisher:
ISBN:
Category :
Languages : en
Pages : 10
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Book Description
Controlled synthetic routes to new boron hydrides, carboranes, and metal-carborane complexes have been developed and a number of structurally novel species have been prepared and characterized. The oxidative fusion method for synthesis of boranes and carboranes has been further extended and its mechanism explored. The chemistry of small (7-vertex) metallacarboranes having reactive metal centers has been examined. Practical routes to metalarene-carborane sandwich complexes have been developed. Keywords: Boron; Arene-metal complex; Iron-carborane complex; Cobalt-carborane complex; Nickel-carborane complex; Oxidative fusion.
Author: United States. Army Research Office
Publisher:
ISBN:
Category : Military research
Languages : en
Pages : 284
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Book Description
Vols. for 1977- consist of two parts: Chemistry, biological sciences, engineering sciences, metallurgy and materials science (issued in the spring); and Physics, electronics, mathematics, geosciences (issued in the fall).
Author:
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ISBN:
Category : Aeronautics
Languages : en
Pages : 244
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Author:
Publisher:
ISBN:
Category : Military research
Languages : en
Pages : 248
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Author: Robert Wilczynski
Publisher:
ISBN:
Category :
Languages : en
Pages : 9
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Author: Russell N. Grimes
Publisher: Academic Press
ISBN: 0128019050
Category : Science
Languages : en
Pages : 1060
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Book Description
Carboranes, Third Edition, by Russell Grimes, is the definitive resource on the subject. Completely updated with a wealth of research and review articles published in this active field since the previous volume was released in 2011, the book provides a readable and concise introduction to the basic principles underlying the synthesis, structures, and reactions of carboranes, heterocarboranes, and metallacarboranes. Following the valuable foundational information, the book explores the advances in practical applications for the many areas in which experts have discovered that carboranes afford new possibilities for solving problems and advancing the science. These disciplines include polymer science, catalysis, biomedicine, nanomaterials, and others. Winner of a 2017 Textbook Excellence Award (Texty) from the Textbook and Academic Authors Association Includes over 2,000 molecular structure drawings throughout the text Features expanded coverage on applications of carboranes, particularly in biomedicine and nanomaterials, given the growth of research in these areas Presents extended and updated tables, listing thousands of compounds with key literature references, provided online via the book’s website Explores the advances in practical applications for the many areas in which experts have discovered that carboranes afford new possibilities for solving problems and advancing the science
Author: E. W Corcoran (Jr)
Publisher:
ISBN:
Category :
Languages : en
Pages : 9
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Platinum dibromide has been found to be a general dehydrodimerization catalyst for boron-boron linked polyhedral cage compounds. The reactions of a variety of small cage systems were explored, and all coupling reactions were found to proceed at moderate temperatures, were highly selective, and gave excellent yields of linked-cage products. These techniques have been used to prepare a number of new coupled cage boron hydrides and carboranes, including 1:1'-B4H92, 1:2'-B4H9B5H8, 1:2'-B4H91'-CH3B5H7, 1:2'-2-CH3B5H73'-CH3B5H7, and 2:2'-1,6-C2B4H52, as well as to provide synthetic routes to the previously known compounds, 1:2'-B5H82 and 2:2'-1,5-C2B3H42.
Author: Mario G. L. Mirabelli
Publisher:
ISBN:
Category :
Languages : en
Pages : 332
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Author:
Publisher:
ISBN:
Category : Science
Languages : en
Pages : 306
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Author: David Emin
Publisher:
ISBN:
Category : Science
Languages : en
Pages : 408
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