Electronic Structure and Properties of Transition Metal Compounds PDF Download
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Author: Isaac B. Bersuker
Publisher: John Wiley & Sons
ISBN: 0470920858
Category : Science
Languages : en
Pages : 658
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Book Description
With more than 40% new and revised materials, this second edition offers researchers and students in the field a comprehensive understanding of fundamental molecular properties amidst cutting-edge applications. Including ~70 Example-Boxes and summary notes, questions, exercises, problem sets, and illustrations in each chapter, this publication is also suitable for use as a textbook for advanced undergraduate and graduate students. Novel material is introduced in description of multi-orbital chemical bonding, spectroscopic and magnetic properties, methods of electronic structure calculation, and quantum-classical modeling for organometallic and metallobiochemical systems. This is an excellent reference for chemists, researchers and teachers, and advanced undergraduate and graduate students in inorganic, coordination, and organometallic chemistry.
Author: Isaac B. Bersuker
Publisher: John Wiley & Sons
ISBN: 0470920858
Category : Science
Languages : en
Pages : 658
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Book Description
With more than 40% new and revised materials, this second edition offers researchers and students in the field a comprehensive understanding of fundamental molecular properties amidst cutting-edge applications. Including ~70 Example-Boxes and summary notes, questions, exercises, problem sets, and illustrations in each chapter, this publication is also suitable for use as a textbook for advanced undergraduate and graduate students. Novel material is introduced in description of multi-orbital chemical bonding, spectroscopic and magnetic properties, methods of electronic structure calculation, and quantum-classical modeling for organometallic and metallobiochemical systems. This is an excellent reference for chemists, researchers and teachers, and advanced undergraduate and graduate students in inorganic, coordination, and organometallic chemistry.
Author: E. König
Publisher: Springer
ISBN: 9783540130185
Category : Science
Languages : en
Pages : 352
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Book Description
Author: Kenneth Kam-Wing Lo
Publisher: Academic Press
ISBN: 012803887X
Category : Science
Languages : en
Pages : 408
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Book Description
Inorganic and Organometallic Transition Metal Complexes with Biological Molecules and Living Cells provides a complete overview of this important research area that is perfect for both newcomers and expert researchers in the field. Through concise chapters written and edited by esteemed experts, this book brings together a comprehensive treatment of the area previously only available through scattered, lengthy review articles in the literature. Advanced topics of research are covered, with particular focus on recent advances in the biological applications of transition metal complexes, including inorganic medicine, enzyme inhibitors, antiparasital agents, and biological imaging reagents. - Geared toward researchers and students who seek an introductory overview of the field, as well as researchers working in advanced areas - Focuses on the interactions of inorganic and organometallic transition metal complexes with biological molecules and live cells - Foscuses on the fundamentals and their potential therapeutic and diagnostic applications - Covers recent biological applications of transition metal complexes, such as anticancer drugs, enzyme inhibitors, bioconjugation agents, chemical biology tools, and bioimaging reagents
Author: E. König
Publisher: Springer
ISBN: 9783540122708
Category : Science
Languages : en
Pages : 677
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Book Description
Author: Mandeep Dalal
Publisher: Dalal Institute
ISBN: 8193872002
Category : Science
Languages : en
Pages : 482
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Book Description
An advanced-level textbook of inorganic chemistry for the graduate (B.Sc) and postgraduate (M.Sc) students of Indian and foreign universities. This book is a part of four volume series, entitled "A Textbook of Inorganic Chemistry – Volume I, II, III, IV". CONTENTS: Chapter 1. Stereochemistry and Bonding in Main Group Compounds: VSEPR theory; dπ -pπ bonds; Bent rule and energetic of hybridization. Chapter 2. Metal-Ligand Equilibria in Solution: Stepwise and overall formation constants and their interactions; Trends in stepwise constants; Factors affecting stability of metal complexes with reference to the nature of metal ion and ligand; Chelate effect and its thermodynamic origin; Determination of binary formation constants by pH-metry and spectrophotometry. Chapter 3. Reaction Mechanism of Transition Metal Complexes – I: Inert and labile complexes; Mechanisms for ligand replacement reactions; Formation of complexes from aquo ions; Ligand displacement reactions in octahedral complexes- acid hydrolysis, base hydrolysis; Racemization of tris chelate complexes; Electrophilic attack on ligands. Chapter 4. Reaction Mechanism of Transition Metal Complexes – II: Mechanism of ligand displacement reactions in square planar complexes; The trans effect; Theories of trans effect; Mechanism of electron transfer reactions – types; outer sphere electron transfer mechanism and inner sphere electron transfer mechanism; Electron exchange. Chapter 5. Isopoly and Heteropoly Acids and Salts: Isopoly and Heteropoly acids and salts of Mo and W: structures of isopoly and heteropoly anions. Chapter 6. Crystal Structures: Structures of some binary and ternary compounds such as fluorite, antifluorite, rutile, antirutile, crystobalite, layer lattices- CdI2, BiI3; ReO3, Mn2O3, corundum, pervoskite, Ilmenite and Calcite. Chapter 7. Metal-Ligand Bonding: Limitation of crystal field theory; Molecular orbital theory: octahedral, tetrahedral or square planar complexes; π-bonding and molecular orbital theory. Chapter 8. Electronic Spectra of Transition Metal Complexes: Spectroscopic ground states, Correlation and spin-orbit coupling in free ions for Ist series of transition metals; Orgel and Tanabe-Sugano diagrams for transition metal complexes (d1 – d9 states); Calculation of Dq, B and β parameters; Effect of distortion on the d-orbital energy levels; Structural evidence from electronic spectrum; John-Tellar effect; Spectrochemical and nephalauxetic series; Charge transfer spectra; Electronic spectra of molecular addition compounds. Chapter 9. Magantic Properties of Transition Metal Complexes: Elementary theory of magneto - chemistry; Guoy’s method for determination of magnetic susceptibility; Calculation of magnetic moments; Magnetic properties of free ions; Orbital contribution, effect of ligand-field; Application of magneto-chemistry in structure determination; Magnetic exchange coupling and spin state cross over. Chapter 10. Metal Clusters: Structure and bonding in higher boranes; Wade’s rules; Carboranes; Metal carbonyl clusters - low nuclearity carbonyl clusters; Total electron count (TEC). Chapter 11. Metal-π Complexes: Metal carbonyls: structure and bonding; Vibrational spectra of metal carbonyls for bonding and structure elucidation; Important reactions of metal carbonyls; Preparation, bonding, structure and important reactions of transition metal nitrosyl, dinitrogen and dioxygen complexes; Tertiary phosphine as ligand.
Author: P.D. Day
Publisher: Royal Society of Chemistry
ISBN: 0851863019
Category :
Languages : en
Pages : 220
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Book Description
Reflecting the growing volume of published work in this field, researchers will find this book an invaluable source of information on current methods and applications.
Author: P Day
Publisher: Royal Society of Chemistry
ISBN: 1847555977
Category : Science
Languages : en
Pages : 220
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Book Description
Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued. The current list of Specialist Periodical Reports can be seen on the inside flap of this volume.
Author: R.T. Pardasani
Publisher: Springer Nature
ISBN: 3662624702
Category : Science
Languages : en
Pages : 1087
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Book Description
With the objective to collate the enormous amount of information on magnetic susceptibility parameters of a very large number of a variety of skeletons and present it in a form that can readily be retrieved and used, a new pattern is being introduced with the present volume keeping in view that now a majority of research groups look at the scientific data electronically. In this volume, magnetic properties of Ni, Pd, Pt, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Th, and U complexes are described. All the magnetic properties of each individual substance are listed as a single document which is self-explainable and allowing search in respect of substance name, synonyms, common vocabulary, and even structure.
Author: R.T. Pardasani
Publisher: Springer Nature
ISBN: 3662624745
Category : Science
Languages : en
Pages : 1483
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Book Description
With the objective to collate the enormous amount of information on magnetic susceptibility parameters of a very large number of a variety of skeletons and present it in a form that can readily be retrieved and used, a new pattern is being introduced with the present volume keeping in view that now a majority of research groups look at the scientific data electronically. In this volume, magnetic properties of complexes of Cu are described. All the magnetic properties of each individual substance are listed as a single document which is self-explainable and allowing search in respect of substance name, synonyms, common vocabulary, and even structure.
Author: R.T. Pardasani
Publisher: Springer Nature
ISBN: 3662624664
Category : Science
Languages : en
Pages : 1047
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Book Description
With the objective to collate the enormous amount of information on magnetic susceptibility parameters of a very large number of a variety of skeletons and present it in a form that can readily be retrieved and used, a new pattern is being introduced with the present volume keeping in view that now a majority of research groups look at the scientific data electronically. This volume describes magnetic properties of complexes of Fe, Ru, Co, and Rh. All the magnetic properties of each individual substance are listed as a single document which is self-explainable and allowing search in respect of substance name, synonyms, common vocabulary, and even structure.
