Laser Flash Photolysis Studies of Some Halogen Monoxide Reactions of Atmospheric Interest PDF Download
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Author: Jeffrey M. Cronkhite
Publisher:
ISBN:
Category : Oxides
Languages : en
Pages : 242
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Author: Jeffrey M. Cronkhite
Publisher:
ISBN:
Category : Oxides
Languages : en
Pages : 242
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Author: Patrick L. Laine
Publisher:
ISBN:
Category : Atmosphere
Languages : en
Pages :
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Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 616
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Author: Zhijun Zhao
Publisher:
ISBN:
Category : Dynamics
Languages : en
Pages :
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Radical reactions play central roles in regulating regional air quality and global climate. Some potentially important gas phase radical reactions are being investigated in this research project, including Cl reactions with acetone, butanone, 3-pentanone, pyridine, and dimethyl selenide (DMSe), HO2 complex formation and dissociation with formic and acetic acids, and reactive and non-reactive quenching of O(1D) by the potent greenhouse gases SO2F2, NF3, and SF5CF3. The involved radicals are generated by laser flash photolysis (LFP). Temporal profiles of either the radical reactant or a product are monitored in "real time" using atomic resonance fluorescence spectroscopy (RF), time-resolved UV-visible absorption spectroscopy (TRUVVAS), or tunable diode laser absorption spectroscopy (TDLAS), allowing kinetic and mechanistic information of these reactions to be obtained. These studies provide new knowledge of the investigated radical reactions and facilitate a better understanding of their significance in atmospheric chemistry.
Author: Rafal Strekowski
Publisher:
ISBN:
Category : Hydrocyanic acid
Languages : en
Pages : 380
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Author:
Publisher:
ISBN:
Category : Atmospheric chemistry
Languages : en
Pages : 576
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Author: National Research Council of Canada. Reprints
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Category :
Languages : en
Pages : 35
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Author: N. Basco
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ISBN:
Category :
Languages : en
Pages : 14
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The rate constants for the production of vibrationally excited oxygen in the reactions O + ClO2 to O2 + C10 and O + ClO to O2 + Cl are approximately equal. The oxygen initially receives 45 plus or minus 10% of the heat of reaction in the form of vibrational energy. Extinction coefficients have been measured for several bands of the C-X, D-X and E-X systems of ClO2 in the vacuum ultraviolet. Five new systems are reported between 141 and 128 nm. Two of these, F-X and J-X, and the C-X system form a Rydberg series for an ionization potential of 10.36 eV. (Modified author abstract).
Author: William James Bloss
Publisher:
ISBN:
Category :
Languages : en
Pages :
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Author:
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ISBN:
Category : Dissertations, Academic
Languages : en
Pages : 680
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