Kinetics and Dynamics of Oxidation Reactions Involving an Adsorbed CO Species. Second Year Annual Report, January 1, 1992--December 31, 1992

Kinetics and Dynamics of Oxidation Reactions Involving an Adsorbed CO Species. Second Year Annual Report, January 1, 1992--December 31, 1992 PDF Author:
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Languages : en
Pages : 8

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Book Description
Objectives were to formulate kinetic models/mechanistic sequences, and to develop bifunctional catalysts for selective oxidation of hdyrocarbons. Efforts are reported this year on 3 items: development of Fourier transform infrared emission spectroscopy to monitor near infrared (ir) under reaction conditions (ethylene oxidation on V2O5); kinetics study of methanol oxidation on supported Pt catalysts (methanol-rich feed the CO2 yield exhibits a maximum at an intermediate temperature); and comparative kinetics study of CO oxidation on Pt, Pd, and Rh. The ir spectra of V2O5 show a correlation between the ir features and the degree of surface oxidation. 4 figs. (DLC).