Ion Solvation

Ion Solvation PDF Author: Y. Marcus
Publisher: John Wiley & Sons
ISBN:
Category : Science
Languages : en
Pages : 328

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Book Description
Chemical reactions generally take place in solution and often involve ions. The behaviour of ions in solution, manifested through ion solvation, is therefore of prime interest in chemistry. This book considers in depth the phenomenology of ion solvation and the models and interpretations that have been proposed as the physical causes for the observed phenomena. It contains a thorough discussion of the statistical thermodynamic background of the solvation process from which a discussion of the actual thermodynamics is developed. This, in turn, serves as a background to the structural and kinetic features of ion solvation.

Ion Solvation

Ion Solvation PDF Author: Y. Marcus
Publisher: John Wiley & Sons
ISBN:
Category : Science
Languages : en
Pages : 328

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Book Description
Chemical reactions generally take place in solution and often involve ions. The behaviour of ions in solution, manifested through ion solvation, is therefore of prime interest in chemistry. This book considers in depth the phenomenology of ion solvation and the models and interpretations that have been proposed as the physical causes for the observed phenomena. It contains a thorough discussion of the statistical thermodynamic background of the solvation process from which a discussion of the actual thermodynamics is developed. This, in turn, serves as a background to the structural and kinetic features of ion solvation.

Ions in Solution and their Solvation

Ions in Solution and their Solvation PDF Author: Yizhak Marcus
Publisher: John Wiley & Sons
ISBN: 1118889142
Category : Science
Languages : en
Pages : 308

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Book Description
The book starts with an exposition of the relevant properties of ions and continues with a description of their solvation in the gas phase. The book contains a large amount of factual information in the form of extensive tables of critically examined data and illustrations of the points made throughout. It covers: the relevant properties of prospective liquid solvents for the ions the process of the transfer of ions from the gas phase into a liquid where they are solvated various aspects of the solutions of the ions, such as structural and transport ones and the effects of the ions on the solvent dynamics and structure what happens in cases where the solvent is a mixture selective solvation takes place applications of the concepts expounded previously in fields such as electrochemistry, hydrometallurgy, separation chemistry, biophysics, and synthetic methods

Single-Ion Solvation

Single-Ion Solvation PDF Author: Philippe Hunenberger
Publisher: Royal Society of Chemistry
ISBN: 1782624961
Category : Science
Languages : en
Pages : 685

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Book Description
Ions are ubiquitous in chemical, technological, ecological and biological processes. Characterizing their role in these processes in the first place requires the evaluation of the thermodynamic parameters associated with the solvation of a given ion. However, due to the constraint of electroneutrality, the involvement of surface effects and the ambiguous connection between microscopic and macroscopic descriptions, the determination of single-ion solvation properties via both experimental and theoretical approaches has turned out to be a very difficult and highly controversial problem. This unique book provides an up-to-date, compact and consistent account of the research field of single-ion solvation thermodynamics that has over one hundred years of history and still remains largely unsolved. By reviewing the various approaches employed to date, establishing the relevant connections between single-ion thermodynamics and electrochemistry, resolving conceptual ambiguities, and giving an exhaustive data compilation (in the context of alkali and halide hydration), this book provides a consistent synthesis, in depth understanding and clarification of a large and sometimes very confusing research field. The book is primarily aimed at researchers (professors, postgraduates, graduates, and industrial researchers) concerned with processes involving ionic solvation properties (these are ubiquitous, eg. in physical/organic/analytical chemistry, electrochemistry, biochemistry, pharmacology, geology, and ecology). Because of the concept definitions and data compilations it contains, it is also a useful reference book to have in a university library. Finally, it may be of general interest to anyone wanting to learn more about ions and solvation. Key features: - discusses both experimental and theoretical approaches, and establishes the connection between them - provides both an account of the past research (covering over one hundred years) and a discussion of current directions (in particular on the theoretical side) - involves a comprehensive reference list of over 2000 citations - employs a very consistent notation (including table of symbols and unambiguous definitions of all introduced quantities) - provides a discussion and clarification of ambiguous concepts (ie. concepts that have not been defined clearly, or have been defined differently by different authors, leading to confusion in past literature) - encompasses an exhaustive data compilation (in the restricted context of alkali and halide hydration), along with recommended values (after critical analysis of this literature data) - is illustrated by a number of synoptic colour figures, that will help the reader to grasp the connections between different concepts in one single picture

Ions in Solution and their Solvation

Ions in Solution and their Solvation PDF Author: Yizhak Marcus
Publisher: John Wiley & Sons
ISBN: 1118892275
Category : Science
Languages : en
Pages : 312

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Book Description
The book starts with an exposition of the relevant properties of ions and continues with a description of their solvation in the gas phase. The book contains a large amount of factual information in the form of extensive tables of critically examined data and illustrations of the points made throughout. It covers: the relevant properties of prospective liquid solvents for the ions the process of the transfer of ions from the gas phase into a liquid where they are solvated various aspects of the solutions of the ions, such as structural and transport ones and the effects of the ions on the solvent dynamics and structure what happens in cases where the solvent is a mixture selective solvation takes place applications of the concepts expounded previously in fields such as electrochemistry, hydrometallurgy, separation chemistry, biophysics, and synthetic methods

Molecular Theory of Solvation

Molecular Theory of Solvation PDF Author: F. Hirata
Publisher: Springer Science & Business Media
ISBN: 1402025904
Category : Science
Languages : en
Pages : 366

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Book Description
Molecular Theory of Solvation presents the recent progress in the statistical mechanics of molecular liquids applied to the most intriguing problems in chemistry today, including chemical reactions, conformational stability of biomolecules, ion hydration, and electrode-solution interface. The continuum model of "solvation" has played a dominant role in describing chemical processes in solution during the last century. This book discards and replaces it completely with molecular theory taking proper account of chemical specificity of solvent. The main machinery employed here is the reference-interaction-site-model (RISM) theory, which is combined with other tools in theoretical chemistry and physics: the ab initio and density functional theories in quantum chemistry, the generalized Langevin theory, and the molecular simulation techniques. This book will be of benefit to graduate students and industrial scientists who are struggling to find a better way of accounting and/or predicting "solvation" properties.

Ion Solvation

Ion Solvation PDF Author: Yizhak Marcus
Publisher:
ISBN: 9780783743929
Category :
Languages : en
Pages : 314

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Book Description


Spectroscopic Studies of Alkali and Ammonium Ion Solvation in Non-aqueous Solvents

Spectroscopic Studies of Alkali and Ammonium Ion Solvation in Non-aqueous Solvents PDF Author: John Lynn Wuepper
Publisher:
ISBN:
Category : Ammonium salts
Languages : en
Pages : 280

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Book Description


Spectroscopic Studies of Lithium Ion Solvation in Non-aqueous Solvents

Spectroscopic Studies of Lithium Ion Solvation in Non-aqueous Solvents PDF Author: Paul Russell Handy
Publisher:
ISBN:
Category : Lithium ions
Languages : en
Pages : 302

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Book Description


Ionic Solvation

Ionic Solvation PDF Author: Gennadiĭ Alekseevich Krestov
Publisher: Prentice Hall
ISBN:
Category : Science
Languages : en
Pages : 368

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Book Description
This comprehensive, widely-read anthology presents cogent and provocativearticles from differing political perspectives on major issues in post-World WarII America. The fourth edition is considerably expanded to include newselections on the AIDS epidemic, gay rights, the women's movement, and theClinton-Gore administration. In addition to articles by leading historians theeditors have chosen first-person accounts by participants in each of the issuesunder discussion, from Martin Luther King, Jr.'s "Letter from the BirminghamJail" to Al Gore's speech on environmentalism. With lively introductions to eachsection providing a context for the articles, this book helps students makesense of the tumultuous world of our time.

Spectroscopic and Electrochemical Studies of Ion Solvation and Complexation in Various Solvents

Spectroscopic and Electrochemical Studies of Ion Solvation and Complexation in Various Solvents PDF Author: Richard M. Farmer
Publisher:
ISBN:
Category : Calcium ions
Languages : en
Pages : 578

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Book Description