Infrared Matrix Isolation Studies PDF Download
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Author: Shelle J. David
Publisher:
ISBN:
Category : Matrix isolation spectroscopy
Languages : en
Pages : 200
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Author: Shelle J. David
Publisher:
ISBN:
Category : Matrix isolation spectroscopy
Languages : en
Pages : 200
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Author: John David Guerin
Publisher:
ISBN:
Category :
Languages : en
Pages : 270
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Author: John D. R. Howells
Publisher:
ISBN:
Category : Matrix isolation spectroscopy
Languages : en
Pages :
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Thesis (M. Sc.)
Author: A. Barnes
Publisher: Springer Science & Business Media
ISBN: 9400985401
Category : Science
Languages : en
Pages : 602
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Book Description
The matrix isolation (MI) method has now been used for nearly thirty years. During this period it has been actively developed and the range of problems tackled greatly extended. Originally it was used for studies of transient species involv ing vibrational, electronic and ESR spectroscopy. Nowadays the study of transient species forms a comparatively small part of HI work since it has been amply demonstrated that very fruitful information can be obtained of the structure and interactions of stable molecules and their aggregates. In addition to the s~ectroscopic methods mentioned above the MI technique is nowadays a standard method in research based on vibrational relaxation, luminescence, Mossbauer, magnetic circular dichroism, pulsed NMR and photoelectron spectroscopy. The matrix isolation technique affords considerable advantages over more conventional methods in most applications of spectroscopy. Areas where the technique has been widely applied, or shows great potential, include: metal atom chemistry, and its relation to surface chemistry, high temperature inorganic species, transition metal complexes, interstellar species, free radicals and unstable molecules, conformational studies, molecular com plexes, and intermolecular forces.
Author: Mei-Lee Hwang Jeng
Publisher:
ISBN:
Category :
Languages : en
Pages : 410
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Author: Stephen Cradock
Publisher: CUP Archive
ISBN: 9780521207591
Category : Science
Languages : en
Pages : 160
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Book Description
This 1975 book shows how and why matrix isolation developed and describes the necessary apparatus.
Author: Markku Räsänen
Publisher:
ISBN: 9789519946061
Category :
Languages : en
Pages : 21
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Author: Dolphus E. Milligan
Publisher:
ISBN:
Category : Diazomethane
Languages : en
Pages : 38
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Author:
Publisher:
ISBN:
Category :
Languages : en
Pages :
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The combination of Fourier transform infrared (FT-IR) spectroscopy with the matrix-isolation techniques has advantages compared with the use of more conventional grating spectroscopy. Furthermore, the recent commercial availability of Fourier transform spectrometers has made FT-IR a practical alternative. Some advantages of the FT-IR spectrometer over the grating spectrometer are the result of the computerized data system that is a necessary part of the FT-IR spectrometer; other advantages are a consequence of the difference in optical arrangements and these represent the inherent advantages of the FT-IR method. In most applications with the matrix-isolation technique, the use of FT-IR spectroscopy results in either an improved signal-to-noise ratio or a shorter time for data collection compared with grating infrared spectroscopy. Fourier transform infrared spectroscopy has been used in the laboratory to study several molecular species in low-temperature matrices. Some species have been produced by high-temperature vaporization from Knudsen cells and others by sputtering. By sputtering, Ar and Kr matrices have been prepared which contain U atoms, UO, UO/sub 2/, UO/sub 3/, PuO, PuO/sub 2/, UN, or UN/sub 2/, depending upon the composition of the gas used to sputter as well as the identity of the metallic cathode. Infrared spectra of matrices containing these compounds are presented and discussed. (JRD).
Author: S. Dickinson
Publisher:
ISBN:
Category :
Languages : en
Pages :
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