Influence de la stéréochimie et de la fonctionnalité de molécules organiques sur l'hydratation de composés cimentaires

Influence de la stéréochimie et de la fonctionnalité de molécules organiques sur l'hydratation de composés cimentaires PDF Author: Camille Nalet
Publisher:
ISBN:
Category :
Languages : fr
Pages : 183

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Book Description
Le manque de connaissance sur les interactions existantes entre les adjuvants organiques et les phases minérales ainsi que leur influence sur les mécanismes d’hydratation du Ciment Portland Ordinaire (CPO) limite le développement de nouvelles molécules organiques avec des propriétés améliorées et contrôlées. Ici, le but de ces travaux était de comprendre pourquoi et comment des adjuvants organiques modifient le temps de prise du CPO en faisant varier progressivement les caractéristiques de molécules organiques simples comme leur charge, leurs groupes fonctionnels (hydroxyle, hydroxy-carboxylate, carboxylate, sulfonate et phosphonate) et la stéréochimie de leurs groupes hydroxyles.Les différents retards induits par les molécules organiques étudiées sur l’hydratation du composé minéral responsable des propriétés finales du CPO, le silicate tricalcique, ont été reliés aux caractéristiques des composés organiques. Les interactions de ces derniers dont leur adsorption sur du silicate de calcium hydraté (C-S-H) ainsi que leur complexation avec les ions calcium, hydroxyde et/ou silicates en solution ont été identifiées dans des systèmes à l’équilibre et corrélées au retard généré par les molécules organiques sur l’hydratation du silicate tricalcique.L’impact des hexitols qui varient uniquement en fonction de la stéréochimie de leurs groupes hydroxyles sur le processus de dissolution-précipitation de l’hydratation du silicate tricalcique a été étudié. L’influence de ces polyols sur l’hydratation d’un mélange luminatesulfate de calcium a été expliquée par leur adsorption sur l’ettringite, les AFm et par leur complexation ionique en solution. Pour finir, cette étude s’est focalisée sur les conséquences des interactions des hexitols avec l’ettringite et les ions aluminate en solution sur l’hydratation des phases silicates présentes dans le CPO.

Influence de la stéréochimie et de la fonctionnalité de molécules organiques sur l'hydratation de composés cimentaires

Influence de la stéréochimie et de la fonctionnalité de molécules organiques sur l'hydratation de composés cimentaires PDF Author: Camille Nalet
Publisher:
ISBN:
Category :
Languages : fr
Pages : 183

Get Book Here

Book Description
Le manque de connaissance sur les interactions existantes entre les adjuvants organiques et les phases minérales ainsi que leur influence sur les mécanismes d’hydratation du Ciment Portland Ordinaire (CPO) limite le développement de nouvelles molécules organiques avec des propriétés améliorées et contrôlées. Ici, le but de ces travaux était de comprendre pourquoi et comment des adjuvants organiques modifient le temps de prise du CPO en faisant varier progressivement les caractéristiques de molécules organiques simples comme leur charge, leurs groupes fonctionnels (hydroxyle, hydroxy-carboxylate, carboxylate, sulfonate et phosphonate) et la stéréochimie de leurs groupes hydroxyles.Les différents retards induits par les molécules organiques étudiées sur l’hydratation du composé minéral responsable des propriétés finales du CPO, le silicate tricalcique, ont été reliés aux caractéristiques des composés organiques. Les interactions de ces derniers dont leur adsorption sur du silicate de calcium hydraté (C-S-H) ainsi que leur complexation avec les ions calcium, hydroxyde et/ou silicates en solution ont été identifiées dans des systèmes à l’équilibre et corrélées au retard généré par les molécules organiques sur l’hydratation du silicate tricalcique.L’impact des hexitols qui varient uniquement en fonction de la stéréochimie de leurs groupes hydroxyles sur le processus de dissolution-précipitation de l’hydratation du silicate tricalcique a été étudié. L’influence de ces polyols sur l’hydratation d’un mélange luminatesulfate de calcium a été expliquée par leur adsorption sur l’ettringite, les AFm et par leur complexation ionique en solution. Pour finir, cette étude s’est focalisée sur les conséquences des interactions des hexitols avec l’ettringite et les ions aluminate en solution sur l’hydratation des phases silicates présentes dans le CPO.

Nanotechnology in Construction

Nanotechnology in Construction PDF Author: Zdenek Bittnar
Publisher: Springer Science & Business Media
ISBN: 3642009808
Category : Technology & Engineering
Languages : en
Pages : 432

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Book Description
The 3rd International Symposium on Nanotechnology in Construction (NICOM 3) follows the highly successful NICOM 1 (Paisley, UK 2003) and NICOM 2 (Bilbao, Spain 2005) Symposia. The NICOM3 symposium was held in Prague, Czech Republic from May 31 to June 2, 2009 under the auspices of the Czech Technical University in Prague. It was a cross-disciplinary event, bringing together R&D experts and users from different fields all with interest in nanotechnology and construction. The conference was aimed at: Understanding of internal structures of existing construction materials at nano-scale Modification at nano-scale of existing construction materials. Production and properties of nanoparticulate materials, nanotubes and novel polymers. Modeling and simulation of nanostructures. Instrumentation, techniques and metrology at nano-scale. Health and safety issues and environmental impacts related to nanotechnology during research, manufacture and product use. Review of current legislation. Societal and commercial impacts of nanotechnology in construction, their predictions and analysis.

Agroecology and Strategies for Climate Change

Agroecology and Strategies for Climate Change PDF Author: Eric Lichtfouse
Publisher: Springer Science & Business Media
ISBN: 9400719051
Category : Technology & Engineering
Languages : en
Pages : 334

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Book Description
Sustainable agriculture is a rapidly growing field aiming at producing food and energy in a sustainable way for our children. This discipline addresses current issues such as climate change, increasing food and fuel prices, starvation, obesity, water pollution, soil erosion, fertility loss, pest control and biodiversity depletion. Novel solutions are proposed based on integrated knowledge from agronomy, soil science, molecular biology, chemistry, toxicology, ecology, economy, philosophy and social sciences. As actual society issues are now intertwined, sustainable agriculture will bring solutions to build a safer world. This book series analyzes current agricultural issues and proposes alternative solutions, consequently helping all scientists, decision-makers, professors, farmers and politicians wishing to build safe agriculture, energy and food systems for future generations.

Sociology, Organic Farming, Climate Change and Soil Science

Sociology, Organic Farming, Climate Change and Soil Science PDF Author: Eric Lichtfouse
Publisher: Springer Science & Business Media
ISBN: 9048133335
Category : Technology & Engineering
Languages : en
Pages : 478

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Book Description
Sustainable agriculture is a rapidly growing field aiming at producing food and energy in a sustainable way for humans and their children. Sustainable agriculture is a discipline that addresses current issues such as climate change, increasing food and fuel prices, poor-nation starvation, rich-nation obesity, water pollution, soil erosion, fertility loss, pest control, and biodiversity depletion. Novel, environmentally-friendly solutions are proposed based on integrated knowledge from sciences as diverse as agronomy, soil science, molecular biology, chemistry, toxicology, ecology, economy, and social sciences. Indeed, sustainable agriculture decipher mechanisms of processes that occur from the molecular level to the farming system to the global level at time scales ranging from seconds to centuries. For that, scientists use the system approach that involves studying components and interactions of a whole system to address scientific, economic and social issues. In that respect, sustainable agriculture is not a classical, narrow science. Instead of solving problems using the classical painkiller approach that treats only negative impacts, sustainable agriculture treats problem sources. Because most actual society issues are now intertwined, global, and fast-developing, sustainable agriculture will bring solutions to build a safer world. This book series gathers review articles that analyze current agricultural issues and knowledge, then propose alternative solutions. It will therefore help all scientists, decision-makers, professors, farmers and politicians who wish to build a safe agriculture, energy and food system for future generations.

Concrete Repair, Rehabilitation and Retrofitting

Concrete Repair, Rehabilitation and Retrofitting PDF Author: M. Alexander
Publisher: CRC PressI Llc
ISBN: 9780415396561
Category : Science
Languages : en
Pages : 544

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Book Description
The First International Conference on Concrete Repair, Rehabilitation and Retrofitting (ICCRRR 2005) was held in Cape Town, South Africa, in November 2005. The conference was a collaborative venture by researchers from the South African Research Programme in Concrete Materials (based at the Universities of Cape Town and The Witwatersrand) and The Construction Materials Section at Leipzig University in Germany. The conference focused on appropriate repairing, maintaining, rehabilitating, and, if necessary, retrofitting existing infrastructure with a view to extending its life and maximising its economic return.

Organic Farming, Prototype for Sustainable Agricultures

Organic Farming, Prototype for Sustainable Agricultures PDF Author: Stéphane Bellon
Publisher: Springer Science & Business
ISBN: 9400779275
Category : Technology & Engineering
Languages : en
Pages : 492

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Book Description
Stakeholders show a growing interest for organic food and farming (OF&F), which becomes a societal component. Rather than questioning whether OF&F outperforms conventional agriculture or not, the main question addressed in this book is how, and in what conditions, OF&F may be considered as a prototype towards sustainable agricultures. The book gathers 25 papers introduced in a first chapter. The first section investigates OF&F production processes and its capacity to benefit from the systems functioning to achieve higher self-sufficiency. The second one proposes an overview of organic performances providing commodities and public goods. The third one focuses on organics development pathways within agri-food systems and territories. As well as a strong theoretical component, this book provides an overview of the new challenges for research and development. It questions the benefits as well as knowledge gaps with a particular emphasis on bottlenecks and lock-in effects at various levels.

Organic Farming, Pest Control and Remediation of Soil Pollutants

Organic Farming, Pest Control and Remediation of Soil Pollutants PDF Author: Eric Lichtfouse
Publisher: Springer Science & Business Media
ISBN: 1402096542
Category : Technology & Engineering
Languages : en
Pages : 417

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Book Description
Sustainable agriculture is a rapidly growing field aiming at producing food and energy in a sustainable way for humans and their children. Sustainable agriculture is a discipline that addresses current issues such as climate change, increasing food and fuel prices, poor-nation starvation, rich-nation obesity, water pollution, soil erosion, fertility loss, pest control, and biodiversity depletion. Novel, environmentally-friendly solutions are proposed based on integrated knowledge from sciences as diverse as agronomy, soil science, molecular biology, chemistry, toxicology, ecology, economy, and social sciences. Indeed, sustainable agriculture decipher mechanisms of processes that occur from the molecular level to the farming system to the global level at time scales ranging from seconds to centuries. For that, scientists use the system approach that involves studying components and interactions of a whole system to address scientific, economic and social issues. In that respect, sustainable agriculture is not a classical, narrow science. Instead of solving problems using the classical painkiller approach that treats only negative impacts, sustainable agriculture treats problem sources. Because most actual society issues are now intertwined, global, and fast-developing, sustainable agriculture will bring solutions to build a safer world. This book series gathers review articles that analyze current agricultural issues and knowledge, then propose alternative solutions. It will therefore help all scientists, decision-makers, professors, farmers and politicians who wish to build a safe agriculture, energy and food system for future generations.

Genetic Engineering, Biofertilisation, Soil Quality and Organic Farming

Genetic Engineering, Biofertilisation, Soil Quality and Organic Farming PDF Author: Eric Lichtfouse
Publisher: Springer Science & Business Media
ISBN: 9048187419
Category : Technology & Engineering
Languages : en
Pages : 414

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Book Description
Sustainable agriculture is a rapidly growing field aiming at producing food and energy in a sustainable way for humans and their children. Sustainable agriculture is a discipline that addresses current issues such as climate change, increasing food and fuel prices, poor-nation starvation, rich-nation obesity, water pollution, soil erosion, fertility loss, pest control, and biodiversity depletion. Novel, environmentally-friendly solutions are proposed based on integrated knowledge from sciences as diverse as agronomy, soil science, molecular biology, chemistry, toxicology, ecology, economy, and social sciences. Indeed, sustainable agriculture decipher mechanisms of processes that occur from the molecular level to the farming system to the global level at time scales ranging from seconds to centuries. For that, scientists use the system approach that involves studying components and interactions of a whole system to address scientific, economic and social issues. In that respect, sustainable agriculture is not a classical, narrow science. Instead of solving problems using the classical painkiller approach that treats only negative impacts, sustainable agriculture treats problem sources. Because most actual society issues are now intertwined, global, and fast-developing, sustainable agriculture will bring solutions to build a safer world. This book series gathers review articles that analyze current agricultural issues and knowledge, then propose alternative solutions. It will therefore help all scientists, decision-makers, professors, farmers and politicians who wish to build a safe agriculture, energy and food system for future generations.

Organic Farming

Organic Farming PDF Author: Sarath Chandran
Publisher: Woodhead Publishing
ISBN: 0128132736
Category : Technology & Engineering
Languages : en
Pages : 438

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Book Description
Organic Farming: Global Perspectives and Methods explores the core definition and concepts of organic farming in sustainability, its influence on the ecosystem, the significance of seed, soil management, water management, weed management, the significance of microorganisms in organic farming, livestock management, and waste management. The book provides readers with a basic idea of organic farming that presents advancements in the field and insights on the future. Written by a team of global experts, and with the aim of providing a current understanding of organic farming, this resource is valuable for researchers, graduate students, and post-doctoral fellows from academia and research institutions. - Presents the basic principles of organic farming and sustainable development - Discusses the role of soil in organic agriculture - Addresses various strategies in seed processing and seed storing, seed bed preparation, watering of seeds and seed quality improvement - Includes updated information on organic fertilizers and their preparation techniques

Organic Crop Breeding

Organic Crop Breeding PDF Author: Edith T. Lammerts van Bueren
Publisher: John Wiley & Sons
ISBN: 0470958588
Category : Technology & Engineering
Languages : en
Pages : 312

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Book Description
Organic Crop Breeding provides readers with a thorough review of the latest efforts by crop breeders and geneticists to develop improved varieties for organic production. The book opens with chapters looking at breeding efforts that focus on specific valuable traits such as quality, pest and disease resistance as well as the impacts improved breeding efforts can have on organic production. The second part of the book is a series of crop specific case studies that look at breeding efforts currently underway from around the world in crops ranging from carrots to corn. Organic Crop Breeding includes chapters from leading researchers in the field and is carefully edited by two pioneers in the field. Organic Crop Breeding provides valuable insight for crop breeders, geneticist, crop science professionals, researchers, and advanced students in this quickly emerging field.