Hydrophile - Lipophile Balance of Surfactants and Solid Particles

Hydrophile - Lipophile Balance of Surfactants and Solid Particles PDF Author: Pyotr M Kruglyakov
Publisher: Elsevier
ISBN: 0080534333
Category : Science
Languages : en
Pages : 405

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Book Description
This book considers the different concepts of hydrophile-lipophile balance (HLB) of surfactants and solid particles and the main physicochemical properties of surfactant and solid interfaces which are used to definite the hydrophile-lipophile balance. The book comprehensively analyses all interfacial and bulk properties of surfactants used for the determination of HLB (such as interfacial tension, distribution coefficient, adsorption, surface pressure, surfactants solubility, structure characteristics, distribution between heteropolar phases, micellar formation, chromatographic characteristics, phase separation in emulsions, phase inversion temperature, formation of three phase systems).The central point of the book is the energetic interpretation of the balance, i.e. the hydrophile-lipophile ratio. At the same time the HLB-number systems of Griffin and Davies and other independant methods of the hydrophile-lipophile balance definitions are discussed: PIT, polarity indexes, surfactant affinity difference etc. The possibility of application of the different characteristics of the hydrophile-lipophile balance as a criterion of phase inversion in emulsions and microemulsion systems water-oil-surfactant are considered.For the first time the different methods of the hydrophile-lilophile balance definition for solid particles in compact and dispersed form are suggested by the author. The use of hydrophile-lipophile characteristics of solid particles as a criterion of phase inversion in emulsion stabilisation and for other applications is discussed.

Surfactants

Surfactants PDF Author: Bob Aveyard
Publisher: Oxford University Press
ISBN: 0192563750
Category : Science
Languages : en
Pages : 568

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Book Description
Surfactants... today you have probably eaten some, or rubbed others on your body. Plants, animals (including you) and microorganisms make them, and many everyday products (e.g. detergents, cosmetics, foodstuffs) contain them. Surfactant molecules have one part which is soluble in water and another which is not. This gives surfactant molecules two valuable properties: 1) they adsorb at surfaces (e.g. of an oil droplet in water), and 2) they stick together (aggregate) in water. The aggregates (micelles) are able to dissolve materials not soluble in water alone, and adsorbed surfactant layers, at the surfaces of particles or (say) oil droplets in water, stop the particles or drops sticking together. This is why stable emulsions such as milk do not separate into layers. This book treats the basic physical chemistry and physics underlying the behaviour of surfactant systems. In this book, you will first learn about some background material including hydrophobic hydration, interfacial tension and capillarity (Section I). Discussion of surfactant adsorption at liquid/fluid and solid/liquid interfaces is given in Section II, and includes thermodynamics of adsorption, dynamic and rheological aspects of liquid interfaces and the direct characterisation of surfactant monolayers. In Section III, a description is given of surfactant aggregation to give micelles, lyotropic liquid crystals, microemulsions and Winsor systems. There follows a discussion of surface forces and the way they confer stability on lyophobic colloids and thin liquid films (Section IV). Various dispersions stabilised by adsorbed surfactant or polymer (including solid in liquid dispersions, emulsions and foams) are considered in Section V. The wetting of solids and liquids is explored in Section VI. Like surfactants, small solid particles can adsorb at liquid/fluid interfaces, form monolayers and stabilise emulsions and foams. Such behaviour is covered in Section VII. It is assumed the reader has a knowledge of undergraduate physical chemistry, particularly chemical thermodynamics, and of simple physics. Mathematics (elementary algebra and calculus) is kept at a level consistent with the straightforward derivation of many of the equations presented.

Aulton's Pharmaceutics E-Book

Aulton's Pharmaceutics E-Book PDF Author: Kevin M.G. Taylor
Publisher: Elsevier Health Sciences
ISBN: 0702053937
Category : Medical
Languages : en
Pages : 909

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Book Description
Pharmaceutics is one of the most diverse subject areas in all of pharmaceutical science. In brief, it is concerned with the scientific and technological aspects of the design and manufacture of dosage forms or medicines. An understanding of pharmaceutics is therefore vital for all pharmacists and those pharmaceutical scientists who are involved with converting a drug or a potential drug into a medicine that can be delivered safely, effectively and conveniently to the patient. Now in its fourth edition, this best-selling textbook in pharmaceutics has been brought completely up to date to reflect the rapid advances in delivery methodologies by eye and injection, advances in drug formulations and delivery methods for special groups (such as children and the elderly), nanomedicine, and pharmacognosy. At the same time the editors have striven to maintain the accessibility of the text for students of pharmacy, preserving the balance between being a suitably pitched introductory text and a clear reflection of the state of the art. New to this edition New editor: Kevin Taylor, Professor of Clinical Pharmaceutics, School of Pharmacy, University of London. Twenty-two new contributors. Six new chapters covering parenteral and ocular delivery; design and administration of medicines for the children and elderly; the latest in plant medicines; nanotechnology and nanomedicines, and the delivery of biopharmaceuticals. Thoroughly revised and updated throughout. provides a logical, comprehensive account of drug design and manufacture includes the science of formulation and drug delivery designed and written for newcomers to the design of dosage forms New to this edition New editor: Kevin Taylor, Professor of Clinical Pharmaceutics, School of Pharmacy, University of London. Twenty-two new contributors. Six new chapters covering parenteral and ocular delivery; design and administration of medicines for the children and elderly; the latest in plant medicines; nanotechnology and nanomedicines, and the delivery of biopharmaceuticals. Thoroughly revised and updated throughout.

Surfactants in Tribology

Surfactants in Tribology PDF Author: Girma Biresaw
Publisher: CRC Press
ISBN: 1439889589
Category : Science
Languages : en
Pages : 601

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Book Description
The manufacture and use of almost every consumer and industrial product rely on application of advanced knowledge in surface science and tribology. These two disciplines are of critical importance in major economic sectors, such as mining, agriculture, manufacturing (including metals, plastics, wood, computers, MEMS, NEMS, appliances), construction, transportation, and medical instruments, transplants, and diagnostic devices. An up-to-date reference with contributions by experts in surface science and tribology, Surfactants in Tribology, Volume 3 discusses some of the underlying tribological and surface science issues relevant to many situations in diverse industries. The tradition of presenting new developments and research that began with the first volume in this groundbreaking series continues in the third volume. Comprising 19 chapters on various aspects of surfactants in tribology—including subjects not covered in previous volumes—this book is presented in four parts: Nanotribology and Polymeric Systems, Biobased and Environmentally Friendly Lubricants and Additives, Tribological Properties of Aqueous and Nonaqueous Systems, and Advanced Tribological Concepts. Topics include tribological properties of nanoparticles, biopolymer friction, environmentally friendly surface-active agents, biolubricants, aqueous mixed surfactant systems, and surfactants in motor oil, drilling fluids, and in electrowetting for MEMS and NEMS. The information in this volume provides a cutting-edge reference connecting the fields of surfactants and tribology as a way forward to novel, enhanced methods of controlling lubrication, friction, and wear. Written by a global team of established authorities, this book reflects the latest developments, highlighting the relevance of surfactants in tribological phenomena in a broad range of industries. It provides a valuable resource for readers working in or entering the fields of tribology and surface science.

Adsorption and Aggregation of Surfactants in Solution

Adsorption and Aggregation of Surfactants in Solution PDF Author: K.L. Mittal
Publisher: CRC Press
ISBN: 0824745744
Category : Science
Languages : en
Pages : 656

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Book Description
Offering the latest research and developments in the understanding of surfactant behavior in solutions, this reference investigates the role and dynamics of surfactants and their solution properties in the formulation of paints, printing inks, paper coatings, pharmaceuticals, personal care products, cosmetics, liquid detergents, and lubricants. Exploring the science behind techniques from oil recovery to drug delivery, the book covers surfactant stabilized particles; solid particles at liquid interfaces; nanocapsules; aggregation behavior of surfactants; micellar catalysis; vesicles and liposomes; the clouding phenomena; viscoelasticity of micellar solutions; and more.

Surfactants

Surfactants PDF Author: Laurier Lincoln Schramm
Publisher: Cambridge University Press
ISBN: 0521640679
Category : Science
Languages : en
Pages : 633

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Book Description
This 2000 book provides an introduction to the nature, occurrence, physical properties, propagation, and uses of surfactants in the petroleum industry.

Molecular Organisation on Interfaces

Molecular Organisation on Interfaces PDF Author: Gerhard Lagaly
Publisher: Springer
ISBN: 3540478221
Category : Science
Languages : en
Pages : 118

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Book Description
This volume contains studies on the molecular organisation on interfaces and nanoparticles. The contributions were presented during the 40. General Meeting (Hauptversammlung) of the Kolloid-Gesellschaft in Potsdam in September 2001 and are related to the subject "Colloids and Life Science". Therefore, a diversity of papers were collected covering a large field: synthesis of polymer colloids, biominerals and nanoparticles, investigations on monolayers, lyotropic mesophases, polymeric surfactants, micellar transitions, supramolecular compounds for modifying polymers, solid particles for emulsion stabilisers, and adsorbents for odour control.

Particle-Stabilized Emulsions and Colloids

Particle-Stabilized Emulsions and Colloids PDF Author: To Ngai
Publisher: Royal Society of Chemistry
ISBN: 1782620141
Category : Science
Languages : en
Pages : 337

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Book Description
There has been much scientific interest in the behaviour of colloidal particles at liquid interfaces. From a research aspect they provide model systems for fundamental studies of condensed matter physics. From a commercial aspect they provide applications for making new materials in the cosmetics, food and paint industries. In many cases of colloidal particles at interfaces, the mechanism of particle interactions is still unknown. Particle-Stabilized Emulsions and Colloids looks at recent studies on the behaviour of particles at liquid interfaces. The book first introduces the basic concepts and principles of colloidal particles at liquid-liquid interfaces including the interactions and conformations. The book then discusses the latest advances in emulsions and bicontinuous emulsions stabilized by both solid and soft particles and finally the book covers applications in food science and oil extraction. With contributions from leading experts in these fields, this book will provide a background to academic researchers, engineers, and graduate students in chemistry, physics and materials science. The commercial aspects will also be of interest to those working in the cosmetics, food and oil industry.

Characterization of Liquids, Nano- and Microparticulates, and Porous Bodies using Ultrasound

Characterization of Liquids, Nano- and Microparticulates, and Porous Bodies using Ultrasound PDF Author: Andrei S. Dukhin
Publisher: Elsevier
ISBN: 0080543367
Category : Science
Languages : en
Pages : 383

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Book Description
Two key words define the scope of this book: 'ultrasound' and 'colloids'. Historically, there has been little real communication between disciples of these two fields. Although there is a large body of literature devoted to ultrasound phenomenon in colloids, there is little recognition that such phenomena may be of real importance for both the development, and application, of Colloid Science. From the other side, colloid scientists have not embraced acoustics as an important tool for characterizing colloids. The lack of any serious dialogue between these scientific fields is the biggest motivation behind this book. For colloidal systems, ultrasound provides information on three important areas of particle characterization: Particle sizing, Rheology, and Electrokinetics. This book primarily targets scientists who consider colloids as their major object of interest. As such we emphasize those aspects of acoustics that are important for colloids, and thereby neglect many others. On the other hand, scientists working with ultrasound who are already familiar with the subject will find several important new developments.

Food Engineering Handbook

Food Engineering Handbook PDF Author: Theodoros Varzakas
Publisher: CRC Press
ISBN: 1482261685
Category : Technology & Engineering
Languages : en
Pages : 654

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Book Description
Food Engineering Handbook: Food Process Engineering addresses the basic and applied principles of food engineering methods used in food processing operations around the world. Combining theory with a practical, hands-on approach, this book examines the thermophysical properties and modeling of selected processes such as chilling, freezing, and dehy